• 분석과학
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• 제19권4호
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• pp.309-315
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• 2006

Two piperazine-templated metal sulfate complexes, $(C_4N_2H_{12})[Ni(H_2O)_6](SO_4)_2$, I and ($C_4N_2H_{12}$) $[Co(H_2O)_6](SO_4)_2$, II, have been synthesized by hydro/solvothermal reactions and their crystal structures analyzed by single crystal X-ray diffraction methods. Complex I crystallizes in the monoclinic system, $P2_1/n$ space group, a=12.920(3), b=10.616(2), $c=13.303(2){\AA}$, ${\beta}=114.09(1)^{\circ}$, Z=4, $R_1=0.030$ for 3683 reflections; II: monoclinic $P2_1/n$, a=12.906(3), b=10.711(2), $c=13.303(2){\AA}$, ${\beta}=114.10(2)^{\circ}$, Z=4, $R_1=0.032$ for 4010 reflections. The crystal structures of the piperazine-templated metal(II) sulfates demonstrate zero-dimensional compound constituted by diprotonated piperazine cations, metal(II) cations and sulfate anions. The structures of complex I and II are substantially isostructural to that of the previously reported our piperazine-templated copper(II) sulfate complex $(C_4N_2H_{12})[Cu(H_2O)_6](SO_4)_2$. The central metal(II) atoms are coordinated by six water molecules in the octahedral geometry. The crystal structures are stabilized by three-dimensional networks of the $O_{water}-H{\cdots}O_{sulfate}$ and $N_{pip}-H{\cdots}O_{sulfate}$ hydrogen bonds between the water molecules and sulfate anions and protonated piperazine cations. Based on the results of thermal analysis, the thermal decomposition reactions of the complex I was analyzed to have three distinctive stages whereas the complex II proceed through several stages.

• 정보처리학회논문지B
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• 제11B권4호
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• pp.527-536
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• 2004

리바이저 시스템은 프로젝션 화면 상에서 종이 문서의 수정시 사용되는 교정 제스처와 동일한 제스처를 이용한 온라인 문서 교정 시스템이다. 이를 위해, 프로젝션 화면 상에서 손이나 문서와 같은 전경물체추출 기술과 연속 동작으로 부터의 제스처 인식 기술이 필요하다. 많은 조명 변화와 복잡한 배경 상에서 전경물체를 검출하기 위해서 기하보정과 색상보정을 수행하고, HMM 기반 제스처 인식기를 구현하였다. 실험 결과로부터 연속 제스처에서 93.22%의 인식률을 나타남을 볼 수 있다.

• 대한기계학회논문집A
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• 제28권9호
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• pp.1320-1327
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• 2004

An efficient boundary-based technique is developed for addressing shape design sensitivity analysis in supercavitating flow problem. An analytical sensitivity formula in the form of a boundary integral is derived based on the continuum formulation for a general functional defined in potential flow problems. The formula, which is expressed in terms of the boundary solutions and shape variation vectors, can be conveniently used for gradient computation in a variety of shape design in potential flow problems. While the sensitivity can be calculated independent of the analysis means, such as the finite element method (FEM) or the boundary element method (BEM), the FEM is used for the analysis in this study because of its popularity and easy-to-use features. The advantage of using a boundary-based method is that the shape variation vectors are needed only on the boundary, not over the whole domain. The boundary shape variation vectors are conveniently computed by using finite perturbations of the shape geometry instead of complex analytical differentiation of the geometry functions. The supercavitating flow problem is chosen to illustrate the efficiency of the proposed methodology. Implementation issues for the sensitivity analysis and optimization procedure are also addressed in this flow problem.

• 비파괴검사학회지
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• 제30권6호
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• pp.569-577
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• 2010

Nonplanar surface geometries of components are frequently encountered in real ultrasonic inspection situations. Use of rigid array transducers can lead to beam defocusing and reduction of defect image quality due to the mismatch between the planar array and the changing surface. When a flexible array is used to fit the complex surface profile, the locations of array elements should be known to compute the delay time necessary for adaptive heam focusing. An alternative method is to employ the time reversal focusing technique that does not require a prior knowledge about the properties and structures of the specimen and the transducer. In this paper, a time reversal method is applied to simulate beam focusing of flexible arrays and imaging of point-like defects contained in specimens with nonplanar surface geometry. Quantitative comparisons are made for the performance of a number of array techniques in terms of the ability to focus and image three point-like reflectors positioned at regular intervals. The sinusoidal profile array studied here exhibits almost the same image quality as the flat, reference case.

• Industrial Engineering and Management Systems
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• 제6권2호
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• pp.94-105
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• 2007

Measurement technology plays an important role in discrete manufacturing industry. Probe-type coordinate measuring machines (CMMs) are normally used to capture the geometry of part features. The measured points are then fit to verify a specified geometry by using the least squares method (LSQ). However, it occasionally overestimates the tolerance zone, which leads to the rejection of some good parts. To overcome this drawback, minimum zone approaches defined by the ANSI Y14.5M-1994 standard have been extensively pursued for zone fitting in coordinate form literature for such basic features as plane, circle, cylinder and sphere. Meanwhile, complex features such as torus have been left to be dealt-with by the use of profile tolerance definition. This may be impractical when accuracy of the whole profile is desired. Hence, the true deviation model of torus is developed and then formulated as a minimax problem. Next, a relatively new and simple population based evolutionary approach, particle swarm optimization (PSO), is applied by imitating the social behavior of animals to find the minimum tolerance zone torusity. Simulated data with specified torusity zones are used to validate the deviation model. The torusity results are in close agreement with the actual torusity zones and also confirm the effectiveness of the proposed PSO when compared to those of the LSQ.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.761-763
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• 2001

Dendrimers represent a new class of synthetic macromolecules characterized by a regularly branched treelike structure. Dendrimer can be made with high regularity and controlled molecular weight. Peculiar features of the dendritic geometry are the large number of end groups as well as the shape persistence in higher generations, approaching spherical geometry. One of the most peculiar characteristics of dendritic macromolecules is their controlled molecular structure and orientation, which means that they have a practical application in achieving a highly organized molecular arrangement. We attempted to fabricate a G4-48PyA dendrimer LB films containing 48 pyridinealdoxime functional end group that could form a complex structure with metal ions. Also, we investigated the surface activity of dendrimer films at air-water interface. And we have studied the electrical properties of the ultra-thin dendrimer LB films. The electrical properties of the ultra-thin dendrimer LB films were investigated by studying the current-voltage(I-V) characteristics of metal/dendrimer LB films/metal (MIM) structure. And rectifying behavior of the devices was occurred in applied field.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2004년도 가을 학술발표회 논문집
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• pp.355-362
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• 2004

An efficient boundary-based technique is developed for addressing shape design sensitivity analysis in various problems. An analytical sensitivity formula in the form of a boundary integral is derived based on the continuum formulation for a general functional defined in problems. The formula, which is expressed in terms of the boundary solutions and shape variation vectors, can be conveniently used for gradient computation in a variety of shape design problems. While the sensitivity can be calculated independent of the analysis means, such as the finite element method (FEM) or the boundary element method (BEM), the FEM is used for the analysis in this study because of its popularity and easy-to-use features. The advantage of using a boundary-based method is that the shape variation vectors are needed only on the boundary, not over the whole domain. The boundary shape variation vectors are conveniently computed by using finite perturbations of the shape geometry instead of complex analytical differentiation of the geometry functions. The supercavitating flow problem and fillet problem are chosen to illustrate the efficiency of the proposed methodology. Implementation issues for the sensitivity analysis and optimization procedure are also addressed in these problems.

• Journal of Communications and Networks
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• 제7권4호
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• pp.438-449
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• 2005

In this paper, we describes the information-theoretic approaches to sensor selection and sensor placement in sensor net­works for target localization and tracking. We have developed a sensor selection heuristic to activate the most informative candidate sensor for collaborative target localization and tracking. The fusion of the observation by the selected sensor with the prior target location distribution yields nearly the greatest reduction of the entropy of the expected posterior target location distribution. Our sensor selection heuristic is computationally less complex and thus more suitable to sensor networks with moderate computing power than the mutual information sensor selection criteria. We have also developed a method to compute the posterior target location distribution with the minimum entropy that could be achieved by the fusion of observations of the sensor network with a given deployment geometry. We have found that the covariance matrix of the posterior target location distribution with the minimum entropy is consistent with the Cramer-Rao lower bound (CRB) of the target location estimate. Using the minimum entropy of the posterior target location distribution, we have characterized the effect of the sensor placement geometry on the localization accuracy.

• 대한기계학회논문집A
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• 제33권11호
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• pp.1187-1194
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• 2009

During the last decade, possibility of flaw occurrences has been rapidly increased world-widely as the increase of operating times of petro-chemical facilities. For instance, from a recent in-service inspection, three different sized surface cracks were detected in welding parts of a spherical oxygen holder in Korea. While API579 code provides corresponding engineering assessment procedures to determine crack driving forces, in the present work, numerical analyses are carried out for the cracked oxygen holder to investigate effects of complex geometry, analysis model and residual stress. With regard to the detailed finite element analysis, stress intensity factors are determined from both the full three-dimensional model and equivalent plate model. Also, as an alternative, stress intensity factors are calculated for equivalent plate model by employing the noted influence stress function technique. Finally, parametric structural integrity evaluation of the cracked oxygen holder is conducted in use of failure assessment diagram method, J/T method and DPFAD method. Effects of the geometry and so forth are examined and key findings from the simulations are fully discussed, which enables to determine practical safety margins of spherical components containing a defect.

• 산업공학
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• 제12권1호
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• pp.68-78
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• 1999

A noncircular cutting such as a piston cutting has depended on the copy-machining because of its complex shape. But the copy-machining needs a master model and brings about a low quality of the piston caused by being worn out of the master model. And the lower cutting speed reduces the productivity. In this paper, for solving these problems, a specialized software system and its subsequent procedure are presented. The shape of a piston consists of an oval, an offset, recesses, and eccentricities. The paper describes these shapes as a consistent equation that is a function of the rotational angle and the position of longitudinal direction(Z-axis). It is simple to define the characteristic geometry of a piston and to generate a tool path for CNC machining. This paper proposes the a proper structure of a 4-axes CNC(Computerized Numerical Control) lathe for machining the piston. As well as X-axis and Z-axis, are attached to the machine a C-axis for rotation and a Y-axis for higher speedy prismatic motion parallel to X-axis.