• 한국전기전자재료학회논문지
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• 제24권12호
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• pp.955-961
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• 2011

We investigated the physical properties of stoichiometric and non-stoichiometric oxide doped complex perovskite, $Ba(Zn_{1/3}Ta_{2/3})O_3$ ceramics and their impacts on the microwave dielectric performances using various characterization techniques such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and network analyzer. According to the measurement of lattice constant changes, anomalous lattice volume contraction of $ZrO_2$ doped $Ba(Zn_{1/3}Ta_{2/3})O_3$ sample only showed the dielectric quality factor enhancements, which was due to the lattice volume contraction as well as the 1:2 B-site cation ordering. In addition, NiO doping was useful to the stabilization of temperature coefficient of resonance frequency.

• 한국안광학회지
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• 제9권1호
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• pp.35-41
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• 2004

IV-VI족 화합물인 PbSnSe는 흥미 있는 물리적 특성을 가지고 있는 화합물 반도체로써 본 실험에서는 HWE 방법으로 성장시킨 PbSnSe 박막에 대한 특성을 조사하였다. 원료부와 열벽부 그리고 기판의 온도를 변화시키며 단결정 박막을 성장시켰다. Rutherford back scattering (RBS)을 측정하여 Pb:Sn:Se의 조성비를 확인하였다. 특히 좁은 에너지 대역을 측정하기에 매우 용이한 Fourier transform infra red (FT-IR)측정 장치를 이용하여 에너지 갭을 측정하였다. 박막의 표면 상태는 atomic force microscopy (AFM) 사진과 주사 전자 현미경 (SEM) 사진으로 관찰하여 결정구조와 성장 용도와의 연관성을 조사하였다. 광학 상수는 Spectroscopic ellipsometry (SE) 방법을 이용하여 박막의 광학 상수를 측정했다. PbSnSe 화합물 에피층 시료의 굴절률(n), 유전상수(${\varepsilon}$), 반사율(R) 그리고 흡수 계수(${\alpha}$)등 광학상수를 측정하였다.

• 한국산학기술학회논문지
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• 제14권11호
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• pp.6000-6007
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• 2013

유기합성 과정에서 응용범위가 넓고 안정한 알코올류의 산화제에 대해 많은 연구가 진행 되고 있으며, 그중에서도 Cr(VI)-계열의 시약들이 산화제로 널리 이용되어 왔다. 그러므로 유기 용매에 잘 용해되고, 일차 알코올을 알데히드까지만 산화시키는 산화제의 합성과 그에 따르는 메카니즘 규명이 필요하게 되었다. Cr(VI)-헤테로고리 착물인 Cr(VI)-isoquinoline를 합성하여, 적외선 분광광도법(IR), 유도결합 플라즈마(ICP) 등으로 구조를 확인하였다. 또한 여러가지 용매 하에서 Cr(VI)-isoquinoline를 이용하여 벤질 알코올의 산화반응을 측정한 결과 유전상수(${\varepsilon}$) 값이 큰 용매 순서인 시클로헥센<클로로포름<아세톤$CH_3$, m-Br, m-$NO_2$)을 효과적으로 산화시켰다. 여기서 전자받개 그룹들은 반응 속도가 감소한 반면에 전자주개 치환체들은 반응속도를 증가시켰고, Hammett 반응상수(${\rho}$) 값은 -0.69(308K) 이였다. 그러므로 본 실험에서 알코올의 산화반응 과정은 먼저 크로메이트 에스테르 형성과정을 거친 후, 속도결정단계에서 수소화 전이가 일어나는 메카니즘임을 알 수 있었다.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2002년도 학술대회논문집
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• pp.329-334
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• 2002

This study evaporates TiO$_2$ layer thickness differently with RF sputtering method on Si Wafer(n-100). Thin film is made with the structure of Si+TiO$_2$ and Si+TiO$_2$+Al by evaporating TiN which is used as Antireflection of superintegrated semiconductor integrated circuit with Photo Catalyst. The research is performed to increase the characteristics of photon energy according to TiO$_2$ thickness and the reliability and reproducibility of TiO$_2$ thin film. Reversal of electric Permittivity values is induced by dipole polarization shown in the dielectric of thin film. Complex electric constant ($\varepsilon$$_1$, $\varepsilon$$_2$) has larger peak values as it's thickness is thinner and then it is larger according to the increase of frequency. Electric Permittivity by photon energy has large value in imaginary number and is reduced exponentially by the increase of carrier density according to that of photon energy.

• Structural Engineering and Mechanics
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• 제62권3호
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• pp.325-344
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• 2017

The present paper investigates the propagation of Love-type wave in a composite structure comprised of imperfectly bonded piezoelectric layer with lower fiber-reinforced half-space with rectangular shaped irregularity at the common interface. Closed-form expression of phase velocity of Love-type wave propagating in the composite structure has been deduced analytically for electrically open and short conditions. Some special cases of the problem have also been studied. It has been found that the obtained results are in well-agreement to the Classical Love wave equation. Significant effects of various parameters viz. irregularity parameter, flexibility imperfectness parameter and viscoelastic imperfectness parameter associated with complex common interface, dielectric constant and piezoelectric coefficient on phase velocity of Love-type wave has been reported. Numerical computations and graphical illustrations have been carried out to demonstrate the deduced results for various cases. Moreover, comparative study has been performed to unravel the effects of the presence of reinforcement and piezoelectricity in the composite structure and also to analyze the existence of irregularity and imperfectness at the common interface of composite structure in context of the present problem which serves as a salient feature of the present study.

• 한국분말재료학회지
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• 제15권4호
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• pp.292-296
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• 2008

The electromagnetic (EM) wave absorption properties of the $Fe_{73}Si_{16}B_7Nb_3Cu_1$ nanocrystalline powder mixed with 5 to 20 vol% of Ni-Zn ferrites has been investigated in a frequency range from 100MHz to 10GHz. Amorphous ribbons prepared by a planar flow casting process were pulverized and milled after annealing at 425 for 1 hour. The powder was mixed with a ferrite powder at various volume ratios to tape-cast into a 1.0mm thick sheet. Results showed that the EM wave absorption sheet with Ni-Zn ferrite powder reduced complex permittivity due to low dielectric constant of ferrite compared with nanocrystalline powder, while that with 5 vol% of ferrite showed relatively higher imaginary part of permeability. The sheet mixed with 5 vol% ferrite powder showed the best electromagnetic wave absorption properties at high frequency ranges, which resulted from the increased imaginary part of permeability due to reduced eddy current.

• 한국세라믹학회지
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• 제31권7호
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• pp.804-812
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• 1994

Stable PZT coating sol was prepared using chelating agent, ethylacetoacetate(EAcAc) by sol-gel processing under ambient atmosphere. Through FT-IR spectrum analysis on solution of each reaction step, formation of metal complex was confirmed and prepared PZT sol was stable over several months. Through TG-DTA, XRD, FT-IR spetrum analysis of PZT gel powder, it was understood that the addition of EAcAc could reduce the transition temperature to ferroelectric phase, due to the increased homogeneity by matching the hydrolysis and condensation rates by chelation. Single perovskite phase was obtained by the heat-treatment at 54$0^{\circ}C$ for 30 min. The film was coated on ITO-coated glass substrate by dip coating method. After heat-treatment, PZT thin film had thickness in the range of 20~130 nm. The maximum dielectric constant of its thin film at room temperature and 1 kHz was 128.

• 한국전기전자재료학회논문지
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• 제17권9호
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• pp.960-966
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• 2004

On the bases of the results from "Additive Coating of BaTiO$_3$ Powder using Sol Coating Method I", experimental condition was defined. Representative additives for BaTiO$_3$, that is to say, Mg, Ca and Mn were experimented. The sources of the metal ion were used by organometal complex. As added it, the stability of BaTiO$_3$ sol was evaluated. Mg and Ca were stable, however, The solubility limit of Mn-ATH was 0.05 mol ratio in Mn-ATH/sol. The solubility limit of Mg ion in BaTiO$_3$ was lower than 2 mol%. From the x Ray diffraction patterns, lattice parameters were different with temperature and additives, because the solubility of metal ion was varied in BaTiO$_3$. The dielectric constant of BaTiO$_3$ powders which coated with the 1.5 mol% Mg and calcined at 1200$^{\circ}C$ was increased with 20%.

• 한국정보통신학회논문지
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• 제12권5호
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• pp.821-827
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• 2008

본 논문은 $1{\sim}20Ghz$의 대역별 위성통신 신호에 미치는 영향에 대해 예측 모델을 제안하고 기존 황사시 측정한 데이터와 비교 분석하였다. 황사의 감쇠 특성을 분석하기 위해 황사 물질에 대한 이론적 분석을 하였으며 이를 통해 예측 감쇠량을 제시하였다. 예측 감쇠량을 실제 우리나라 황사 강도와 가시거리와 높이 등의 파라미터를 적용한 이론치를 구하여 4년간 측정한 실측치와 비교하였고 이를 토대로 황사로 인한 감쇠를 미리 예측 가능할 것으로 확인되었다.

• 대한화학회지
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• 제34권2호
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• pp.123-129
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• 1990

메탄올-, 에탄올-, 아세토니트릴-, 아세톤-물 등의 혼합용매에서 $trans-[Cr(en)_2Br_2]^+$착이온의 반응속도상수를 20, 25, 30 및 35$^{\circ}C$에서 분광광도법으로 구하였다. 반응속도상수는 온도가 증가함에 따라 증가하고 공용매의 조성이 증가함에 따라 감소하였다. 속도상수는 공용매의 유전상수의 역수값과 아무런 관계도 보이지 않았다. Grunwald-Winstein식의 m값은 메탄올-, 에탄올-, 아세토니트릴- 및 아세톤-물 혼합용매에서 각각 0.109, 0.103, 0.101 및 0.095이었다. 물과 공용매에서 착이온이 초기상태에서 전이상태로 진행되는 자유에너지사이클로부터 전이상태의 용매화가 속도에 지배적인 영향을 미친다는 것을 알 수 있었다. 위의 결과로부터 이 착이온의 수화반응메카니즘은 Id메카니즘으로 진행된다고 추정하였다.