• Bulletin of the Korean Chemical Society
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• 제16권12호
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• pp.1163-1167
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• 1995

The structures of dehydrated Ca4Na4-A (a=12.243(1) Å) and of its bromine sorption complex (a=12.214(1) Å) have been determined by single crystal x-ray diffraction techniques in the cubic space groupPm&bar{3}m at 21(1) ℃. Both crystals were dehydrated at 360 ℃ and 2 X 10-3 Torr for 2 days and one crystal was treated with 180 Torr of bromine vapor at 24 ℃ for 1 h. The structures were refined to final error indices, R1=0.066 and R2=0.078 with 192 reflections and R1=0.109 and R2=0.093 with 100 reflections, respectively, for which I>3σ(I). In these structures, four Ca2+ and four Na+ ions are located on two different threefold axes associated with 6-ring oxygens, respectively. In Ca4Na4-A·6Br2, four Ca2+ ions are recessed 0.28(1) Å into the large cavity and four Na+ ions extend 0.63(1) Å into the sodalite unit. A total of six dibromine molecules are sorbed per unit cell. Each Br2 molecule approaches a framework oxide ion axially with O(1)-Br(1)=3.27(2) Å Br(1)-Br(2)=2.66(6) Å and O(1)-Br(1)-Br(2)=172(1)°, indicating a charge-transfer interaction.

• Current Optics and Photonics
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• 제3권1호
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• pp.16-21
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• 2019

We present a broad-bandwidth comb-spacing-swept source (CSWS) based on a differential polarization delay line (DPDL) for interferometric three-dimensional (3D) imaging. The comb spacing of the CSWS is repeatedly swept by the tunable DPDL in the multiwavelength source to provide depth-scanning optical coherence tomography (OCT). As the polarization differential delay of the DPDL is tuned from 5 to 15 ps, the comb spacing along the wavelength continuously varies from 1.6 to 0.53 nm, respectively. The wavelength range of various semiconductor optical amplifiers and the cavity feedback ratio of the tunable fiber coupler are experimentally selected to obtain optimal conditions for a broader 3-dB bandwidth of the multiwavelength spectrum and thus provide a higher axial resolution of $35{\mu}m$ in interferometric OCT imaging. The proposed CSWS-OCT has a simple imaging interferometer configuration without reference-path scanning and a simple imaging process without the complex Fourier transform. 3D surface images of a via-hole structure on a printed circuit board and the top surface of a coin were acquired.

• 한국치위생학회지
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• 제22권2호
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• pp.125-132
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• 2022

Objectives: The purpose of this study was to examine the relationship between stress and halitosis in a representative sample of Korean adolescents. Methods: This study was based on the 15th Korea Youth Risk Behavior Survey (2019). The final participation rate in the survey was 95.3%; 57,303 out of 60,100 (95.3%) adolescents aged 13-18 years were selected. Multiple logistic regression with complex samples was performed to identify the correlation between stress and halitosis. Stress level was classified as 'very much', 'a little', and 'not much' and halitosis was defined as the presence of an unpleasant odor in the oral cavity. Results: The prevalence of halitosis among students was 21.3%. As a result of multiple regression analysis, the 'a little' [odds ratio (OR); 1.39, 95% confidence interval (CI); 1.29-1.49] and 'very much' stress group (OR; 1.78, 95% CI; 1.66-1.90) exhibited significantly higher risk of halitosis than the 'not much' stress group. Conclusions: A significant correlation between stress and halitosis exists among Korean adolescents. Therefore, psychological factors such as stress should be considered in managing halitosis in adolescents.

• 한국치위생학회지
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• 제24권2호
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• pp.131-139
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• 2024

Objectives: Oral bacterial samples included subgingival, supragingival, and saliva plaques. As the diversity and number of microorganisms deffer depending on the area of the oral cavity and the method used, an appropriate and reliable collection method is important. The present study investigated oral bacterial sampling methods. Methods: Supragingival dental plaque was collected from the buccal and lingual tooth surfaces of study participants using sterilized cotton swabs. Plaques were collected from the subgingival area using a sterilized curette. Bacterial genomic DNA was extracted using MagNA Pure 96 DNA and Viral NA low-volume kits. Real-time polymerase chain reaction (PCR) was performed using the PowerCheck^TM Periodontitis Pathogens Multiplex Real-time PCR kit. Results: Aggregatibacter actinomycetemcomitans, Prevotella intermedia, and Fusobacterium nucleatum of the orange complex were not observed in the subgingival biofilms of all study participants. For Porphyromonas. gingivalis, a significant correlation was observed between supragingival, subgingival, and total tooth surface biofilms. Compared to the supragingival and subgingival biofilmss, total tooth surface biofilm exhibited the highest bacterial count when the inswabbing method was used. Conclusions: Based on these findings, the supragingival swab method is recommended for oral bacterial research.

• Geomechanics and Engineering
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• 제37권6호
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• pp.629-641
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• 2024

The presence of excavations or cavities beneath the foundations of a building can have a significant impact on their stability and cause extensive damage. Traditional methods for calculating the bearing capacity and subsidence of foundations over cavities can be complex and time-consuming, particularly when dealing with conditions that vary. In such situations, machine learning (ML) and deep learning (DL) techniques provide effective alternatives. This study concentrates on constructing a prediction model based on the performance of ML and DL algorithms that can be applied in real-world settings. The efficacy of eight algorithms, including Regression Analysis, k-Nearest Neighbor, Decision Tree, Random Forest, Multivariate Regression Spline, Artificial Neural Network, and Deep Neural Network, was evaluated. Using a Python-assisted automation technique integrated with the PLAXIS 2D platform, a dataset containing 272 cases with eight input parameters and one target variable was generated. In general, the DL model performed better than the ML models, and all models, except the regression models, attained outstanding results with an R² greater than 0.90. These models can also be used as surrogate models in reliability analysis to evaluate failure risks and probabilities.

• 대한화학회지
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• 제38권6호
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• pp.435-441
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• 1994

3차원 금속 착제, Cd(pn)Ni(CN)4를 host로 하는 포접 화합물을 합성하고, X-선 회절 데이타를 이용한 단결정의 구조해석을 하였다. 결정학적 데이타는 다음과 같다. $[Cd(pn)Ni(CN)_4]{\cdot}0.5(CH_3COCH_3{\cdot}H_2O)$, Fw = 387.35, Orthorhombic, $Pn2_1a$, a = 13.950(3) $\AA$, b = 26.713(7) $\AA$, c = 7.628(1) $\AA$, V = 2843(1) $\AA^3$, Z = 4, $D_x=1.81 gcm^{-3}$, $\mu(MoK{\alpha})$ = $28.153cm^{-1}$, T = 297K, 3521개($F_0>3{\sigma}(F_0)$)의 회절 강도에 대한 최종 신뢰도 인자 R = 0.0418이 얻어졌다. 이 포접 화합물은 thiourea 포접 화합물과 유사한 턴넬형의 포접 공간(T-type)을 형성하며, 이런 포접공간 내에 분자당 0.5개의 아세톤과 물분자를 guest로서 받아 들인다. 표제의 포접 화합물은 이미 보고된 바와 같이, 가지달린 유기 guest분자가 host의 기하구조를 T-type으로 이끈다고 하는 host 선택성에 대한 또 하나의 증거가 된다.

• Bulletin of the Korean Chemical Society
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• 제14권6호
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• pp.687-691
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• 1993

Complexation of $Cd^{2+},\;Pb^{2+}\;and\;Hg^{2+}$ ions with four cryptands were studied by potentiometry and solution calorimetry in various weight percent methanol-aqueous solvent at 25${\circ}$C under $CO_2$free nitrogen atmosphere. The stabilities of the complexes were dependent on the cavity size of macrocycles. The $Hg^{2+}$ ion stability constants are higher than those of $Cd^{2+}\;and\;Pb^{2+}$ ion. All the cryptands formed complexes having 1 : 1 (metal to ligand) mole-ratio except for $Hg^{2+}-L_1$ (cryptand 1,2b: 3,5-benzo-9,14,17-trioxa-1,7-diazabicyclo-(8,5,5) heptadecane) and $Cd^{2+}-L_2$ (cryptand 2,2b: 3,5-benzo-10,13,18,21-tetraoxa-1,7-diazabicyclo (8,5,5) eicosane) complexes. $Hg^{2+}-L_1$ complex was a sandwitch type, and the $Cd^{2+}-L_2$ complex showed two stepwise reactions. Thermodynamic parameters of the $Cd^{2+}-L_2$ complex were $6.08(log\;K_1)$, -7.28 Kcal/mol $({\Delta}H_1)$, and $4.78\;(log\;K_2)$, -4.62 Kcal/mol $({\Delta}H_2)$, respectively, for 1 : 1 and 2: 1 mole-ratio. The sequences of the selectivity were increased in the order of $Hg^{2+}\;>Pb^{2+}\;>Cd^{2+}$ ion for $L_3\;and\;L_4$ macrocycles, and the $L_2$-macrocycle has a selectivity for $Cd^{2+}$ ion relative to $Zn^{2+},\;Ni^{2+},\;Pb^{2+}\;and\;Hg^{2+}$ ions. Thus, it is expected that the $L_2$ can be used as carrier for seperation of the post transition metals by macrocycles-mediated liquid membrane because $L_2$ is not soluble in water, and the difference of stability constants of the metal complexes with $L_2$ are large as compared with the other transition metal complexes. The $^1H\;and\;^{13}C-NMR studies indicated that the nitrogen atoms of cryptands have greater affinity to the post transition metal ions than the oxygen atoms, and that the planarities of the macrocycles were lost by complexation with the metal ions because of the perturbation of ring current of benzene molecule attached to macrocycles and counter-anions.

• 한국융합학회논문지
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• 제6권4호
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• pp.1-7
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• 2015

본 연구는 이과계통의 고교생들과 함께 연구한 연구(RESEARCH) 및 교육(EDUCATION)의 사례연구이다. 최근 발달한 사물인터넷(IoT)[9-15] 기반의 여러 가지 연구주제가 존재한다. 본 연구는 이들 중 이동형 통신기기중 가장 초보단계이면서도 학생들이 쉽게 접하고 제작방법을 따라 갈 수 있는 무선 호출기의 성형과정을 연구 주제로 정하였다. 우리는 이것을 페이저라고 한다. 오늘날 복잡하고 빅 데이터를 사용할 수 있는 대용량 스마트 이동형 통신기기[9-15]가 나와 있다. 그 이전 무선 호출기는 우리 삶에 이동 통신 수단의 첫 의미를 가르쳐 준 기기였다. 내부 구조도 비교적 간단하고 기능도 비교적 단순하여 이제 막 대학의 이공계에 관심을 가진 고교생들의 교육 사례로 적합하다고 생각된다. 본 연구는 사출성형 해석의 ONE CAVITY해석이라는 비교적 간단한 내용으로 무선호출기의 기구, 전자적인 내용을 모두 살펴볼 수 있다. 나아가 학생들에게 대량생산 및 공정자동화에 대한 융합교육의 의미도 일깨워 줄 수 있는 좋은 교육 사례로 평가된다.

• 한국산학기술학회논문지
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• 제16권1호
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• pp.877-887
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• 2015

본 연구진은 사출성형 공정에서 적용되는 미지 시료 및 고점도의 복합소재 점도를 추정하기 위한 새로운 방법을 제시한 바 있다. 본 논문에서는 사출성형 금형 캐비티 내압을 측정하는 장치를 개발하였다. 이는 사출성형 공정 중의 금형 내를 흐르는 용융체의 압력을 실시간으로 측정하고, 이를 CAE 해석 결과로부터 모사된 압력과 비교함으로써 CAE D/B내의 점도 데이터의 정확성을 검증할 수 있게 한다. 본 연구에서 사용한 재료는 PP(Polypropylene), PP/LGF30%(Polypropylene과 long glass fiber 50% composite), PA66/LGF50%(Polyamide 6,6와 long glass fiber 50% composite) 이다. 여기서 PP와 PP장섬유복합재료는 이미 점도 데이터가 구축되어 있으나, PA66장섬유복합재료는 새롭게 개발한 재료로써 기존의 점도 데이터가 없기에 본 시스템을 이용해서 새로운 점도 곡선을 추정하였다. 그리고, 일반 점도 측정장치로 구한 점도 곡선과도 비교하였다. 한편, 이미 점도 데이터를 갖고 있는 경우인 PP는 신뢰성을 확인할 수 있었으나, PP/LGF50%의 경우는 높은 점도와 구조의 복잡성으로 인해 기존 점도 데이터의 개선이 필요하였다.

• 유변학
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• 제10권4호
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• pp.217-226
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• 1998

단섬유 강화 고분자의 사출성형시 고분자 수지의 유동에 의하여 섬유배향이 필연적으로 일어나며, 섬유배향에 의한 이방성 (anisotropy)은 최종성형물의 품질과 기계적인 특성 등에 많은 영향을 미친다. 사출공정 중에서 충전과정(filling stage)은 섬유배향에 지배적인 역할을 하므로, 충전과정의 유동장을 정확하게 해석하는 것은 매우 중요하다. 형상이 복잡한 캐비티(cavity)와 다중 캐비티에서는 먼저 충전이 완료되어 현탁액(suspension)이 압축을 받고 있는 영역들이 존재하게 된다. 기존의 방법처럼 사출성형의 충전과정을 비압축성 유동으로 가정하면 정확한 유동장을 계산할 수 없다. 본 연구에서는 충전과정에서 압축성을 고려한 혼합 유한요소법/유한차분법을 이용하여 유동장을 계산하였다. 충전이 완료되는 순간에서, 이차배향텐서에 대한 배향변화방정식을 4차 Runge-Kutta 방법을 이용하여 해석함으로써 3차원 섬유배향장을 예측하였다. 충전시간이 다른 4개의 캐비티를 갖는 금형을 제작하여 충전과정에서 압축성 효과를 고려한 수치해석 결과가 실험과 잘 일치함을 보였다. 또한, 압축성과 비압축성 유동장에서 이론적으로 계산된 섬유배향의 차이를 정성적 및 정량적으로 비교하였다.