• 한국추진공학회지
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• 제21권5호
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• pp.1-9
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• 2017

초임계 환경에서 와류형 분사기의 극저온 질소 분무 동적 특성 분석을 위하여 3차원 LES 난류 모델을 적용하였다. 초임계 상태에서 질소의 상태량들을 정확하게 예측하기 위해 SRK 실기체 상태방정식을 사용하였고, 점성계수와 열전도도는 Chung의 고압 상태 혼합물에 대한 방정식, 그리고 확산 계수는 Fuller의 이론에 Takahashi의 보정식을 적용하였다. 질소 분무 결과, 분사기 내, 외부에서 유동장과 음향장 사이의 상호작용으로 복잡한 유동구조가 형성된다. 복잡한 유동 현상을 분석하기 위해 FFT, POD 그리고 DMD 기법을 적용하여 해석을 수행하였다. FFT 해석을 수행하여 분사기 내, 외부에서 나타나는 특정 주파수를 파악하였으며, POD와 DMD를 통해 각 주파수가 어떠한 유동 구조를 갖는지에 대한 연구를 수행하였다. 또한, DMD를 통해 각 주파수의 감쇠 계수를 파악하여 이를 실험 결과와 비교하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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• pp.119-122
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• 1998

Chemical analysis, measurement of pumping rates of 60 production wells and depth to water tables of 57 monitoring wells were carried to protect depletion of water resources and deterioration of water quality for the commercial portable ground-water. Borehole depth of production well averages 149m(31 boreholes), casing depth is 28m(29 boreholes), production rate is 70 $m^3$/day and depth to water table of monitoring well is 23.26m, respectively. The geology of 60 wells can be divided into Daebo granite(20), Okchun metarmorphic complex(18), Precambrian granitic gneiss(15), Bulguksa granite(4), Cheju volcanics(2), Cretaceous sedimentary rock(1). Average electrical conductivity and pH are 152$\mu$S/cm, and 7.35, respectively. The contents of major cation and anion predominantly $Ca^{2+}$>N $a^{+}$>M $g^{2+}$> $K^{+}$ and HC $O_{3}$$^{－}$ >S $O_{4}$$^{2-}$>Cl￣>F￣. Water type is predominantly $Ca^{2+}$-HC $O_{3}$$^{－}$(81.7%). It's possible that water chemistry of some wells were affected not only by the geology of boreholes penetrated but by inflows of surface water or shallow ground-water. Therefore, it is strongly necessary to steadily monitor the water quality and hydrogeologic conditins of production wells.ells.ls.ells.

• 한국항행학회논문지
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• 제22권3호
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• pp.205-212
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• 2018

자연발화의 문제는 심각한 경제적 손해뿐만 아니라 화재 시 발생하는 유해가스로 인해 환경오염을 발생시키는 대표적인 발전소 피해이다. 저탄장 자연발화 예방 및 조치하기 위해 드론을 이용하는 방법이 제시되었으나 외부의 측풍과 외란으로 인한 2차 사고의 발생위험이 존재하는 상황이다. 자연발화의 원인과 영향 인자는 매우 복잡하기 때문에 사전에 예방하기가 쉽지 않으며 일단 발생하면 소화하기도 어렵다. 따라서 저탄장 내부에서 직접적으로 온도 및 상태를 측정하고 자연발화 지점에 직접적으로 냉각 가스를 분출하여 소화하는 장치가 필요하다. 본 연구는 저탄장의 자연발화를 예방하기 위한 냉각볼 장치의 내부 압력과 외부 압력에 대하여 구조해석을 실시하고 구조적 안전성에 대하여 연구한다.

• 한국표면공학회지
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• 제4권1호
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• pp.5-15
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• 1971

"Rapid Determination of Boric Acid in Nickel Plating Solution" by the addition of Na$_2$C$_2$O$_4$ and thus preventing the precipitation of i(OH)$_2$ during titiration , has previously been reported. In this paper, the exact amount of glycerine and the complexing possibility of oxalate with nickel has been determined by measn of conductivity titrations. This experimental work has been supported by the mathematical application of the Debye-Huckel and mass action equitions as well as statistical analysis. The results were ; (1) Fro determining boric acid in nickel plating solution, 20 ml of 400ml/ι glycerine was sufficient, since 97% of the H$_3$BO$_3$ was dissoicated by this addition. (2) In the absence of Na$_2$C$_2$O$_4$ the continious precipitation of Ni(OH)$_2$ during titration with NaOH even past end -point for boric acid determination resulted in considerable anlaytical error. (3) In the presence of Na$_2$C$_2$O$_4$ during titration , Ni++ combined with C$_2$O$_4$-to form NiC$_2$O$_4$. The solution with this precititate of very fine, colloidal , trantsparent particles, remained quite clear for approximately 2 hours. Therefore it was shown that the presence of Na$_2$C$_2$O$_4$ prevents the formation of gross Ni(OH)$_2$ precititation by forming NiC$_2$O$_4$ instead of a complex salt with Ni++ , which did not interfere with the visible determination of the end point for boric acid with NaOH titation. This observous may be interpreted in the light of the previously published solubility ratio for NiC$_2$O$_4$ and Ni(OH)$_2$, 0.3mg/100g H$_2$O(25$^{\circ}C$), respectively. Precipitation of the less soluble , albeit transparent salt, NiC$_2$O$_4$ precluded therefore the precipitation of the Ni(OH)$_2$ salt.

• 한국전산구조공학회논문집
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• 제24권2호
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• pp.193-200
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• 2011

본 연구를 통해 superlite라 불리는 단열 파우더를 채용한 NO96 멤브레인 타입 LNG선 단열 화물창의 만선항해 시 LNG의 BOR(Boil-Off Rate) 예측모델을 제시하였다. LNGCC(LNG Cargo Containment)의 비정상상태 열전달 FEM모델은 만선항해 시 대기 및 해수 조건을 반영하고 복잡한 화물창 단열구조에 균질화 기법을 적용하여 구축하였다. BOR은 만선항해중 LNGCC 내부로 침입하는 총 열량을 이용하여 평가되었으며, 주요 변수에 따른 BOR의 변화는 파라메트릭 열전달해석을 통하여 분석하였다. 그리고 파라메트릭 BOR 특성해석 결과를 토대로 LNG선의 탱크 크기, 단열층의 두께 그리고 superlite의 열전도율을 함수로 하는 BOR 예측모델을 유도하였다. 비선형 과도 열전달해석을 통해 직접 구한 BOR과의 비교를 통해 유도한 예측모델은 최대 1% 이내의 상대오차를 나타내었다.

• Corrosion Science and Technology
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• 제14권5호
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• pp.213-217
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• 2015

Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

• 대한화학회지
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• 제37권1호
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• pp.3-9
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• 1993

메탄올 및 에탄올 수용액내에서 1-adamantyl fluoroformate의 가용매분해반응속도를 여러 압력하에서 전도도방법을 이용하여 측정하였다. 이들 속도상수로부터 활성화부피(${\Delta}V^{\neq}{_o}$), 활성화압축율계수(${\Delta}{\beta}^{\neq}$), 활성화엔탈피(${Delta}H^{\neq}$), 활성화엔트로피(${Delta}S^{\neq}$), 그리고 활성화 착물에서의 charge development(△P)를 구하였다. 또한 에탄올 수용액내에서 가용매분해반응으로 인한 생성물에 대한 selectivity를 GC를 이용하여 측정하였다. 그 결과 ${\Delta}V^{\neq}{_o}$와 ${\Delta}{\beta}^{\neq}$의 값은 모두 음의 값을 ${Delta}H^{\neq}$는 양의 값을 ${Delta}S^{\neq}$은 큰 음의 값을 얻었다. 이 현상을 용매구조변화에 대하여 논의하였다. 이들 결과로부터 본 반응은 acyl carbon을 공격하는 이분자성반응과 가용매분해과정(S-D)인 용매-분리이온쌍반응으로 추정할 수가 있었다.

• 한국조경학회지
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• 제27권5호
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• pp.161-169
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• 2000

In this study, the temporal changes in the chemical characteristics of soil in a reclaimed coastal area, the Shihwa Industrial Complex in the West Coast in Kyung-Gi Province, and the correlations between chemical components were investigated to provide useful information needed for introducing vegetation in the area. The sites were filled with mountain forest soils from 1987 to 1996, and developed into various landuses such as neighbourhood parks, children's parks, buffer greens, pedestrian roads and others. The correlation analyses shoed that pH, organic matter(OM) and available P205 had not been closely related to other chemical parameters such as various cations electro-conductivity(EC) and cation exchange capacity(CEC): especially, pH showed a very low correlation with other factors. The EC turned out to have positive relationships with cations, especially with Na+ ions. There seemed to be fairly good correlations between cations except Ca++ ion. The relation between cations and OM was inconclusive possible because the OM contents in the soils were too low for the analysis. The OM seemed to increase slowly with time and the EC decreased slowly. The salinity and CEC in the original soils decreased rapidly possibly because of leaching. It is believed that there were some external disturbances such as rainfall which had affected the soil properties. The soils sampled in dry season showed a very high salinity. From this it is possible to assume that the rainfall would affect the sol properties significantly. So it is necessary to continue further studies to investigate the impacts of external disturbances such as rainfall on vertical soil profile and temporal variations as well as to delineate correlations between parameters with external disturbances controlled.

• 대한안전경영과학회지
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• 제16권2호
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• pp.237-246
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• 2014

Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.

• KIEAE Journal
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• 제12권3호
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• pp.33-40
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• 2012

Since 2000 country region developmental policy has been to integrate not only the improvement of physical living environment but also various subjects on ecology, environment, scenery, local culture, and green tourism. This study has recently established a decentralized Rainwater Management plan in order to provide an hydrology cycle system to the eco-village being planned by Seocheon-gun as a part of the garden village development business promoted by the ministry of agriculture and forestry. Hydraulic conductivity of the subject area is measured at $10^{-7}{\sim}10^{-10}m/sec$, and a flowerbed-type rainwater Infiltration system capable of controlling a non-point pollution source that stems from the development-caused impermeable surface has been applied. In the case of rainwater flowing out from the main entrance way and parking lot within the complex being treated in the flowerbed-type rainwater infiltration system, natural purification effects via soil and plants as well as natural water cycling effects through evaportranspiration and infiltration are expected. The significance of this study, compared to conventional decentralized rainwater management being applied limited to the urban areas, is that it offers appropriate rainwater management planning based on the analysis of the current situation of the subject area. Decentralized Rainwater Management is a valuable measure both economically and ecologically that reduces the burdens on local underground water cultivation as well as rain water pipe lines or purification systems, and sewage pipes.