• Title/Summary/Keyword: Complete removal

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Recovery of Ammonium Salt from Nitrate-Containing Water by Iron Nanoparticles and Membrane Contactor

  • Hwang, Yu-Hoon;Kim, Do-Gun;Ahn, Yong-Tae;Moon, Chung-Man;Shin, Hang-Sik
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.111-116
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    • 2012
  • This study investigates the complete removal of nitrate and the recovery of valuable ammonium salt by the combination of nanoscale zero-valent iron (NZVI) and a membrane contactor system. The NZVI used for the experiments was prepared by chemical reduction without a stabilizing agent. The main end-product of nitrate reduction by NZVI was ammonia, and the solution pH was stably maintained around 10.5. Effective removal of ammonia was possible with the polytetrafluoroethylene membrane contactor system in all tested conditions. Among the various operation parameters including influent pH, concentration, temperature, and contact time, contact time and solution pH showed significant effects on the ammonia removal mechanism. Also, the osmotic distillation phenomena that deteriorate the mass transfer efficiency could be minimized by pre-heating the influent wastewater. The ammonia removal rate could be maximized by optimizing operation conditions and changing the membrane configuration. The combination of NZVI and the membrane contactor system could be a solution for nitrate removal and the recovery of valuable products.

Is the Complete Resection of Craniopharyngiomas in Adults Feasible Considering Both the Oncologic and Functional Outcomes?

  • Lee, Eun Jung;Cho, Young Hyun;Hong, Seok Ho;Kim, Jeong Hoon;Kim, Chang Jin
    • Journal of Korean Neurosurgical Society
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    • v.58 no.5
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    • pp.432-441
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    • 2015
  • Objective : To assess the impact of the complete resection of craniopharyngioma (CP) in adults on oncologic and functional outcomes. Methods : We retrospectively analyzed 82 patients with CP who were surgically treated by the same neurosurgeon at our institution between January 1994 and December 2012. Results : Gross total resection (GTR) was achieved in 71 patients (86.6%), near total resection (NTR) in 7 patients (8.5%), and subtotal resection (STR) in 3 patients (3.7%). The disease-specific overall survival rate was 100% with the exclusion of 2 surgery-related mortalities. The overall recurrence rate was 12.2% (10 of 82 patients), however the recurrence rate according to extent of resection (EOR) was 9.9% (7 of 71 patients) after GTR, 14.3% (1 of 7 patients) after NTR, and 66.7% (2 of 3 patients) after STR. The overall recurrence-free survival (RFS) rates at 5 and 10 years were 87.0% and 76.8%, respectively. Postoperatively, most patients (86.3%) needed hormone replacement for at least 1 hypothalamic-pituitary axis. Vision improved in 56.4% of the patients with preoperative abnormal vision, but deteriorated in 27.4% of patients. Hypothalamic dysfunction developed in 32.9% of patients. There were no significant differences in the risks of pituitary dysfunction, visual deterioration, or hypothalamic dysfunction between the groups with complete vs. incomplete removal. The overall rate of postoperative complications was 22.0%, which did not differ between groups (p=0.053). Conclusion : The complete removal of a CP at first surgery can provide a chance for a cure with acceptable morbidity and mortality risks.

The Kinetic Analysis on Organic Substrate Removal and Nitrification in Anoxic-Anaerobic-Aerobic Process (무산소-혐기-호기법에서 유기기질제거와 질산화의 동역학적 해석)

  • Chae, Soo Kwon
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.689-696
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    • 2007
  • Kinetic analysis was important to develope the biological nutrient removal process effectively. In this research, anoxic-anaerobic-aerobic system was operated to investigate kinetic behavior on the nutrient removal reaction. Nitrification and denitrification were important microbiological reactions of nitrogen. The kinetics of organic removal and nitrification reaction have been investigated based on a Monod-type expression involving two growth limiting substrates : TKN for nitrification and COD for organic removal reaction. The kinetic constans and yield coefficients were evaluated for both these reactions. Experiments were conducted to determine the biological kinetic coefficients and the removal efficiencies of COD and TKN at five different MLSS concentrations of 5000, 4200, 3300, 2600, and 1900 mg/L for synthetic wastewater. Mathematical equations were presented to permit complete evaluation of the this system. Kinetic behaviors for the organic removal and nitrification reaction were examined by the determined kinetic coefficient and the assumed operation condition and the predicted model formulae using kinetic approach. The conclusions derived from this experimental research were as follows : 1. Biological kinetic coefficients were Y=0.563, $k_d=0.054(day^{-1})$, $K_S=49.16(mg/L)$, $k=2.045(day^{-1})$ for the removal of COD and $Y_N=0.024$, $k_{dN}=0.0063(day^{-1})$, $K_{SN}=3.21(mg/L)$, $k_N=31.4(day^{-1})$ for the removal of TKN respectively. 2. The predicted kinetic model formulae could determine the predicted concentration of the activated sludge and nitrifier, investigate the distribution rate of input carbon and nitrogen in relation to the solid retention time (SRT).

Continuous removal of heavy metals by coupling a microbial fuel cell and a microbial electrolytic cell

  • Xie, Guo R.;Choi, Chan S.;Lim, Bong S.;Chu, Shao X.
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.283-294
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    • 2020
  • This work aims at studying the feasibility of continuous removal of mixed heavy metal ions from simulated zinc plating wastewaters by coupling a microbial fuel cell and a microbial electrolysis cell in batch and continuous modes. The discharging voltage of MFC increased initially from 0.4621 ± 0.0005 V to 0.4864 ± 0.0006 V as the initial concentration of Cr6+ increased from 10 ppm to 60 ppm. Almost complete removal of Cr6+ and low removal of Cu2+ occurred in MFC of the MFC-MEC-coupled system after 8 hours under the batch mode; removal efficiencies (REs) of Cr6+ and Cu2+ were 99.76% and 30.49%. After the same reaction time, REs of nickel and zinc ions were 55.15% and 76.21% in its MEC. Cu2+, Ni2+, and Zn2+ removal efficiencies of 54.98%, 30.63%, 55.04%, and 75.35% were achieved in the effluent within optimum HRT of 2 hours under the continuous mode. The incomplete removal of Cu2+, Ni2+ and Zn2+ ions in the effluent was due to the fact that the Cr6+ was almost completely consumed at the end of MFC reaction. After HRT of 12 hours, at the different sampling locations, Cr6+ and Cu2+ removal efficiencies in the cathodic chamber of MFC were 89.95% and 34.69%, respectively. 94.58%, 33.95%, 56.57%, and 75.76% were achieved for Cr6+, Cu2+, Ni2+ and Zn2+ in the cathodic chamber of MEC. It can be concluded that those metal ions can be removed completely by repeatedly passing high concentration of Cr6+ through the cathode chamber of MFC of the MFC-MEC-coupled system.

Enhanced nitrogen removal from high-strength ammonia containing wastewater using a membrane aerated bioreactor (MABR)

  • Arindam Sinharoy;Ji-Hong Min;Chong-Min Chung
    • Membrane and Water Treatment
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    • v.15 no.2
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    • pp.59-66
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    • 2024
  • This study evaluated the performance of a membrane aerated biofilm reactor (MABR) for nitrogen removal from a high-strength ammonia nitrogen-containing wastewater. The experimental setup consisted of four compartments that are sequentially anaerobic and aerobic to achieve complete nitrogen removal. The last compartment of the reactor setup contained a membrane bioreactor (MBR) to reduce sludge production in the system and to obtain a better-quality effluent. Continuous experiment over a period of 47 days showed that MABR exhibited excellent NH4+-N removal efficiency (99.5%) compared to the control setup without MABR (56.5%). The final effluent NH4+-N concentration obtained in the MABR was 2.99±1.56 mg/L. In contrast to NH4+-N removal, comparable TOC removal values in the MABR and the control reactor (99.2% and 99.3%, respectively) showed that air supply through MABR is much more critical for denitrification than for organic removal. Further study to understand the effect of air supply rate and holding pressure on NH4+-N removal in MABR revealed that an increase in both these parameters positively impacted reactor performance. These parameters are related to oxygen supply to the biofilm formed over the membrane surface, which in turn influenced NH4+-N removal in MABR. Among the two different strategies to control biofilm over the membrane surface, results showed that scouring for a duration of 10 min on a weekly basis, along with mixing air supply, could be an effective method.

Removal of a High Load of Ammonia by a Marine Bacterium, Vibrio alginolyticus in Biofilter

  • Kim, Nam-Jin;Shoda, Makoto
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.5
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    • pp.316-322
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    • 2002
  • A newly isolated heterotrophic marine bacterium, Vibrio alginolyticus, was used to remove a high load of ammonia gas under non-sterile condition. The cells were inoculated onto an inorganic packing material in a fixed-bed reactor (biofilter), and a high load of ammonia, in the range of ammonia gas concentration of 170 ppm to 880 ppm, was introduced continuously. Sucrose solution and 3% NaCl was supplied intermittently to supplement the carbon source and water to the biofilter. The average percentage of gas removed exceeded 85% for 107-day operation. The maximum removal capacity and the complete removal capacity were$19\;g-N\;kg^{-1}$ dry packing material $day^{-1}$ and $16\;g-N\;kg^{-1}$ dry packing material $day^{-1}$, respectively, which were about three times greater than those obtained in nitrifying sludge inoculated onto the same packing material. On day 82, the enhanced pressure drop was restored to the normal one by NaOH treatment, and efficient removal characteristics were later observed. During this operation, the non-sterile condition had no significantly adverse effect on the removability of ammonia by V. alginolyticus.

Reuse of the sewage from sea area using the Submerged Moving Media Complete Mixing Activated Sludge (SMMCMAS) (회전매체를 가진 완전혼합활성슬러지 공법을 이용한 온천지구 하수의 재이용)

  • 김홍태;김학석
    • Journal of Environmental Science International
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    • v.11 no.1
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    • pp.69-74
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    • 2002
  • This study was performed to evaluate an applicability of the SMMCMAS system for reuse of the sewage from spa area and was operated to HLR(Hydraulic loading rate) of 211.3 to 126.8 $\ell$/㎥/d. The operating HRT(Hydraulic retention time) ranges were 2.5 to 1.5 hours. Conclusions are as follows; At the optimum HLR of 158.5 $\ell/\m^2$/d (HRT of 2.0 hours), the maximum BOD removal efficiency was 94% and the effluent BOD concentration was 1.1mg/$\ell$ in result. As the HLR was increased to 211.3 $\ell/\m^2$/d, BOD removal efficiency was decreased to 75% and BOD removal efficiency was also reduced to 74% at lower HLR of 126.8 $\ell/\m^2$/d. It shows that the maximum BOD removal efficiency occurs at an optimum HLR value and that the removal efficiency decreases when the HLR is either higher or lower than the optimum value. Sludge production rates were ranged 0.01 to 0.24gVSS/gBODrem/d and accomplished to 0.01gVSS/gBODrem/d at the optimum HLR of 158.5 $\ell/\m^2$/d.

Removal of Odor and THM from the Raw Water of Daecheong Dam (대청호 원수내 냄새 및 THM 제거방안 연구)

  • Jeon, Hang-Bae;Yun, Gi-Sik
    • Journal of Korea Water Resources Association
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    • v.30 no.3
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    • pp.235-245
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    • 1997
  • A pilot scale study for removing odor and trihalomethane formation potential (THMFP) was investigated in the standard water treatment plant equipped with ozone oxidation and granular activated carbon (GAC) adsorption processes. The removal efficiency of dissolved organic carbon (DOC) in the pilot scale standard water treatment process (PSWTP) was about 25%, however, no more removal in the ozone oxidation process. On a GAC after 30 days operation, DOC removal efficiency was about 75%. Odor removal efficiency was about 30% in PSWTP, 60% in ozone oxidation, and almost complete in well as DOC. Mid-1 and 2 that showed breakthrough in odor inducing material as well as DOC. Mid-1 and 2 chlorination was able to reduce trihalomethanes (THM) by 25% compared to prechloringation, while postchlorination alone could reduce them by 30%.

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Development of LED Traffic Light Lens with snow removing function (제설 기능을 갖는 LED 신호등 렌즈 개발)

  • Lee, Dongeun;Seol, Dongyoul
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.13 no.4
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    • pp.41-48
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    • 2017
  • It is necessary to develop an LED traffic light lens having a snow removal function capable of clearly providing a traffic signal to the driver even when a traffic light is blurred due to heavy snow and wind in the winter season. This study is focused on the research and development of the traffic light lens in the process of developing the LED traffic light with the snow removal function. In the developed traffic light lens, instead of attaching the film heater, the coated nichrome wire was wound into a coil shape and inserted directly into the groove in the lens. The developed heater system facilitates the insertion of the heating wire with high elasticity into a curved lens and can provide a sufficient heat without deformation of the PC lens. The proposed traffic lights were tested in various external environments and the test results showed that complete snow removal is possible without tunnel effect.

Fire Behavior of Steel Columns Encased by Damaged Spray-applied Fire Resistive Material

  • Kwak, Yoon Keun;Pessiki, Stephen;Kwon, Kihyon
    • Architectural research
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    • v.10 no.1
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    • pp.1-11
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    • 2008
  • A Steel column with damaged spray-applied fire resistive material (SFRM) may exhibit reduced structural performance due to the effects of elevated temperature during fire events. Thus, the fire load behavior of steel columns with removed or reduced SFRM needs to be examined to predict the structural damage by fire. FEM analyses were performed for the flange thinning removal models in which the SFRM was reduced as a constant strip in thickness at the top flange of the column. The temperature results for all models obtained from the heat transfer analyses were included as an initial condition in the FEM structural analyses. In this study, the results of analysis show that even small remnants of SFRM led to an effective reduction of temperature at any given fire duration, and improved significantly the axial load capacity of a column as compared to the complete removal cases of SFRM.