• 제목/요약/키워드: Competitive through rate

검색결과 138건 처리시간 0.029초

이온교환 능력을 가진 지지체에 부착된 나노 영가철을 이용한 질산성 질소의 환원과 부산물 제거 (Reduction of Nitrate using Nanoscale Zero-Valent Iron Supported on the Ion-Exchange Resin)

  • 박희수;박용민;조윤성;오수경;강상윤;유경민;이성재;최용수;이상협
    • 상하수도학회지
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    • 제21권6호
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    • pp.679-687
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    • 2007
  • Nanoscale zero valent ion (nZVI) technology is emerging as an innovative method to treat contaminated groundwater. The activity of nZVI is very high due to their high specific surface area, and supporting this material can help to preserve its chemical nature by inhibiting oxidation. In this study, nZVI particles were attached to granular ion-exchange resin through borohydride reduction of ferrous ions, and chemical reduction of nitrate by this material was investigated as a potential technology to remove nitrate from groundwater. The pore structure and physical characteristics were measured and the change by the adsorption of nZVI was discussed. Batch tests were conducted to characterize the activity of the supported nZVI and the results indicated that the degradation of nitrate appeared to be a pseudo first-order reaction with the observed reaction rate constant of $0.425h^{-1}$ without pH control. The reduction process continued but at a much lower rate with a rate constant of $0.044h^{-1}$, which is likely limited by mass transfer. To assess the effects of other ions commonly found in groundwater, the same experiments were conducted in simulated groundwater with the same level of nitrate. In simulated groundwater, the rate constant was $0.078h^{-1}$ and it also reduced to $0.0021h^{-1}$ in later phase. The major limitation in application of ZVI for nitrate reduction is ammonium production. By using a support material with ion exchange capacity, the problem of ammonium release can be solved. The ammonium was not detected in the batch test, even when other competitive ions such as calcium and potassium existed.

$\alpha$-(n-Butyl)-N-Phenylnitrone 유도체에 대한 Sodium Thiophenoxide의 친핵성 첨가반응 메카니즘과 그의 반응 속도론적 연구 (Kinetics and Mechanism of Nucleophilic Addition of Sodium Thiophenoxide to $\alpha$-(n-Butyl)-N-Phenylnitrone Derivatives)

  • 이광일;이석우;곽천근;김영주;노승일;이기창
    • 대한화학회지
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    • 제38권6호
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    • pp.442-448
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    • 1994
  • ${\alpha}$-(n-Butyl)-N-Phenylnitrone 유도체의 첨가 반응속도상수를 25^{\circ}C$의 수용액에서 자외선 분광광도법으로 측정하여 넓은 pH범위에서 잘 맞는 반응속도식을 유도하였다. 첨가반응생성물은 ${\alpha}$-phenylthiobutylidene-aniline이었으며, 첨가반응속도상수 측정과 반응속도식의 유도, 일반기염 효과, 치환기 효과 및 최종생성물의 결과로부터 반응 메카니즘을 제안하였다. 즉, pH 3.0 이하에서는 티오페놀의 첨가로 반응이 시작되며, pH 3.0∼10.0에서는 티오페놀과 티오페녹시드 음이온이 경쟁적으로 첨가되어 진행되며, pH10.0이상에서는 티오페녹시드 음이온의 첨가에 의해서 반응이 진행된다.

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유기물 농도가 낮은 고품질 정수 생산을 위한 고압막여과 공정 설계 시 고려사항 (Considerations to design high-pressure membrane system to produce high quality potable water with lower organic matter concentration)

  • 전종민;김성수;서인석;김수한
    • 상하수도학회지
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    • 제34권6호
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    • pp.473-480
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    • 2020
  • High-pressure membrane system like nanofiltration(NF) and reverse osmosis(RO) was investigated as a part of water treatment processes to produce high quality potable water with low organic matter concentration through membrane module tests and design simulation. River water and sand filtration permeate in Busan D water treatment plant were selected as feed water, and NE4040-90 and RE4040-Fen(Toray Chemical Korea) were used as NF and RO membranes, respectively. Total organic carbon(TOC) concentrations of NF and RO permeates were mostly below 0.5 mg/l and the average TOC removal rates of NF and RO membranes were 93.99% and 94.28%, respectively, which means NF used in this study is competitive with RO in terms of organic matter removal ability. Different from ions rejection tendency, the TOC removal rate increases at higher recovery rates, which is because the portion of higher molecular weight materials in the concentrated raw water with increasing recovery rate increases. Discharge of NF/RO concentrates to rivers may not be acceptable because the increased TDS concentration of the concentrates can harm the river eco-system. Thus, the idea of using NF/RO concentrate as the raw water for industrial water production was introduced. The design simulation results with feed water and membranes used in this work reveal that the raw water guideline can be satisfied if the recovery rate of NF/RO system is designed below 80%.

전략적 인적자원관리 측면의 육군 ROTC 제도 개선방안 연구 - 조직편성 및 운영체계를 중심으로 - (A Study on the Improvement Plan of ROK Army's ROTC System in the Aspect of Strategic Human Resource Management -Focusing on the Organizational Structure and Operation System-)

  • 김명렬;김충관
    • 융합보안논문지
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    • 제22권1호
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    • pp.141-148
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    • 2022
  • 한국의 ROTC 제도는 유능한 초급장교 충원과 평시부터 예비전력 확보를 위해 1961년에 미국으로부터 도입되었다. 하지만 2000년대 접어들어 저출산에 따른 학령인구 및 병역자원의 감소, 병 복무기간까지 단축되는 획득환경의 변화로 지원율이 점점 하락하는 심각한 위기에 직면하게 되었다. 따라서 본 연구는 이러한 획득환경의 변화와 그에 따른 지원율 감소의 원인을 분석하여 조직편성 및 운영체계를 중심으로 ROTC 제도 개선방안을 제시하고자 하였다. 연구방법은 국내‧외 문헌연구를 통해 미국과 한국의 ROTC 제도에 관한 사례 간 비교기법을 적용하였다. 이론적 측면에서는 지식기반사회에서 조직의 성과달성과 비교경쟁우위 확보를 위해 기업경영에 적용하고 있는 전략적 인적자원관리를 이론적 준거로 삼았다.

활성탄에 의한 작용기가 다른 염료의 흡착: 파라미터 및 경쟁 흡착 (Adsorption of Dyes with Different Functional Group by Activated Carbon: Parameters and Competitive Adsorption)

  • 이종집
    • 공업화학
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    • 제33권2호
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    • pp.151-158
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    • 2022
  • 본 논문은 활성탄에 의해 작용기가 다른 말라카이트 그린(MG), 다이렉트 레드 81 (DR 81) 및 티오플라빈 S (TS)의 흡착에 대한 파라미터 특성(PH 효과, 등온선, 동역학 및 열역학 파라미터) 및 염료의 경쟁 흡착에 대해 조사하였다. Langmuir, Freundlich 및 Temkin 등온선 모델을 사용하여 염료의 흡착 메커니즘 및 활성탄에 의한 흡착 처리의 적합성을 평가했다. Langmuir 무차원 분리 계수 값은 활성탄에 의한 세 가지 염료의 흡착 처리가 효과적인 방법임을 나타내었다. 활성탄에 대한 세 가지 염료의 흡착 메커니즘은 Temkin 식에서 계산된 흡착열로부터 물리 흡착임을 확인하였다. 세 가지 염료의 흡착 동역학은 유사 2차 모델에 가까웠으며 잘 일치함을 보여주었다. 활성탄에 의한 세 가지 염료의 흡착 과정의 속도 지배 단계는 입자내 확산이었다. 양의 엔탈피와 엔트로피 변화는 각각 흡열 반응과 고액계면에서 흡착에 의한 무질서도가 증가함을 나타내었다. 세 가지 염료의 음의 Gibbs 자유 에너지 값은 온도가 증가함에 따라 자발성이 높아지는 것을 나타냈다. 삼성분 경쟁흡착에서 흡착능력이 높은 MG는 혼합용액에서 DR 81과 TS에 의해 약간의 방해를 받았으나, 흡착능력이 낮은 DR 81과 TS는 흡착력이 좋은 MG의 영향을 받아 흡착률이 크게 증가하였다.

인트라넷이 의사소통에 미치는 영향에 관한 연구 (A Study on the Impact of the Intranet on Communication)

  • 노경호
    • 경영과정보연구
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    • 제12권
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    • pp.53-75
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    • 2003
  • The Internet is flourishing and the World Wide Web is growing at an exponential rate. A fundamental concept of Intranet, the so-called second wave, was introduced only a few years ago. Intranets have been embraced by corporate users of information services and made substantial inroads in strategic vision documents and procurement practices. Business organizations have come to the conclusion that they require an extensive data repository in order to acquire a competitive advantage in a dynamically change market. This rich assortment of data must further be delivered and deliverable enterprise-wide in a secure and cost-efficient manner. Information technology(IT) has created the Intranet as a vitally important mechanism for the storage, dissemination, and even the analysis data. The present study is an attempt to develop a more through understanding of the potential and actual impact of the Intranet on organizational functions and activities. Expecially, it also consists of an effort to assess the impact of the Intranet on communication. The research also addresses the issue of how the Intranet affects communication and shapes or modifies business activities. The results of literature review and study revealed that middle managers believe that the extent of the Intranet use is significantly related to improvements in overall organizational functions and activities. While communication, decision-making, productivity, work collaboration, and business activities are all enhanced by Intranet use, communication appears to be most dramatically improved by Intranet use.

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회귀변수선택절차를 이용한 인터넷통신 네트워크 품질특성과 고객만족도와의 관계 실증분석 (Empirical analysis of relationship between Internet communication network quality characteristics and customer satisfaction using regression variable selection procedures)

  • 박성민;박영준
    • 한국경영과학회:학술대회논문집
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    • 한국경영과학회/대한산업공학회 2005년도 춘계공동학술대회 발표논문
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    • pp.822-828
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    • 2005
  • Customer satisfaction becomes one of the important managerial concerns associated with corporate competency in current competitive environment for Internet communication service companies. Hence, it is demanding to improve a company's customer satisfaction through the total quality management perspective. In practice, engineers as well as the management hope to find major quality characteristics with Internet communication network that is closely related to customer satisfaction, consequently aiming to the raise of their company's customer satisfaction. This paper presents an empirical relationship analysis between network quality characteristics and customer satisfaction on Internet communication. Methodologically, the relationship analysis framework is based on the regression variable selection procedures. In this framework, it is implemented that; 1) iterative model building; and 2) consistent criteria application to statistical tests for selecting significant variables. A case study shows that; 1) the customer satisfaction on the network connection seems to be more closely related to the network quality characteristics compared with the customer satisfaction on the network speed; and 2) the download disconnection rate has relatively evident relationship with the customer satisfaction on the network connection.

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Characteristics of Peptide Assimilation by Helicobacter pylori: Evidence for Involvement of Cell Surface Peptidase

  • YUN SOON-KYU;CHOI KYUNG-MIN;UHM CHANG-SUB;PARK JEONG-KYU;HWANG SE-YOUNG
    • Journal of Microbiology and Biotechnology
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    • 제15권4호
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    • pp.899-902
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    • 2005
  • Peptide assimilation by Helicobacter pylori was investigated using L-phenylalanyl-3-thia-phenylalanine (PSP) as a detector peptide; the release of thiophenol upon enzymatic hydrolysis of PSP was spectrophotometrically detected with the aid of 5,5'-dithiobis[2-nitrobenzoic acid] (DTNB). By adding PSP to whole-cell suspension, thiophenol was produced progressively, resembling that found in Esherichia coli or Staphylococcus aureus. Interestingly, the rate of thiophenol production by H pylori in particular was markedly reduced when cells were pretreated with trypsin, indicating surface exhibition of peptidase. According to the competitive spectrophotometry using alanyl-peptides, H pylori did not appear to assimilate PSP through the peptide transport system. No discernible PSP assimilation could be ascertained in H pylori cells, unless provided with some additives necessary for peptidase activity, such as $Ni^{2+}\;or\;Mg^{2+}$ and an appropriate concentration of potassium or ammonium salts. These observations strongly suggest that, regardless of a presumptive peptide transport system, peptide assimilation of H. plori appears to be highly dependent upon milieu conditions, due to unique peptidase exhibition on the cell surface.

공급기업의 관점에서 본 B2B e-marketplace의 성공요인 (An Empirical Study to Identify Success Factors of B2B e-marketplaces: Focused on the Supply Companies)

  • 황하진;김정아
    • 한국정보시스템학회지:정보시스템연구
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    • 제13권2호
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    • pp.65-88
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    • 2004
  • This study is intended to identify success factors which influence the performance of the B2B e-marketplaces.Thestudyisfocused on the supply companies and conducted to provide local small businesses with guidelines to improve their competitiveness and to develop appropriate business strategies in the digital economy age. Based on the literature review, four characteristics which influence the performance of B2B e-marketplaces are identified. Such characteristics as strategic, operational, organizational, and product/service properties are then utilized to develop the survey questionaire. The data collection is first performed through e-mail and, after finding out the response rate was too poor to analyze the results, followed by visits to the companies which participate in e-marketplaces. SAS 8.1 is used for the data analysis. Demographic analysis is conducted to generate the general information of the companies responded, and factor analysis is performed for the validity test. Finally, multiple regression is used for the hypothesis testing. This study is expected to contribute to find out critical factors for the success of B2B e-marketplaces and suggest guidelines for local small businesses to develop an appropriate e-business strategy to improve their competitive position.

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중소기업의 e-비즈니스가 생산성에 미치는 영향에 관한 연구 (A Study on the Impact of the e-business of SMEs on Productivity)

  • 노경호
    • 통상정보연구
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    • 제7권2호
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    • pp.49-74
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    • 2005
  • E-business has received much attention from entrepreneurs, executives, investors, and industry observers recently. The Internet is flourishing and the World Wide Web is growing at an exponential rate In recent years, information has become the critical commodity needed for success in the changing global economic order. Accordingly, business organizations have come to the conclusion that they require an extensive data repository in order to acquire a competitive advantage in a dynamically change market. This rich assortment of data must further be delivered and deliverable enterprise-wide in a secure and cost-efficient manner. Information technology(IT) has created the E-business as a vitally important mechanism for the storage, dissemination, and even the analysis data. The E-business has become increasingly important to a growing number of organizations in Korea in relatively short order. The present study is an attempt to develop a more through understanding of the potential and actual impact of the E-business on organizational functions and activities. Expecially, it also consists of an effort to assess the impact of the E-business on productivity. The research also addresses the issue of how the E-business affects productivity and shapes or modifies business activities. The results of literature review and study revealed that middle managers believe that the extent of the E-business use is significantly related to improvements in overall organizational functions and activities. While communication, decision-making, productivity, work collaboration, and business activities are all enhanced by E-business use, productivity appears to be most dramatically improved by Intranet use.

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