• Title/Summary/Keyword: Compact

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Remarkable Structure Relaxation of Zeolite Windows in Rb₃- and K₃-A Crystal Structures of $M_3nA_{9-x}H_xSi_{12}Al_{12}O_{48}$ where M-Rb or K and x=1 or 0

  • 박종삼;윤명숙;임우택;김명철;서숭혁;허남호
    • Bulletin of the Korean Chemical Society
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    • v.16 no.10
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    • pp.923-929
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    • 1995
  • Four crystal structures of M3-A (M3Na9-xHx-A, M=Rb or K and x=1 or 0), Rb3Na8H-A(a=12.228(1) Å and R1=0.046), Rb3Na9-A (a=12.258(3) Å and R1=0.058), K3Na8H-A (a=12.257(3) Å and R1=0.048) and K3Na9-A (a=12.257(3) Å and R1=0.052), have been determined by single crystal x-ray diffraction technique in the cubic space group Pm3^m at 21 ℃. In all structures, each unit cell contained three M+ ions all located at one crystallographically distinct position on 8-rings. Rb+ ions are 3.12 and 3.21 Å away respectively from O(1) and O(2) oxygens, about 0.40 Å away from the centers of the 8-rings, and K+ ions are 2.87 and 2.81 Å apart from the corresponding oxygens. These distances are the shortest ones among those previously found for the corresoponding ones. Eight 6-rings per unit cell are occupied by eight Na+ ions, each with a distance of 2.31 Å to three O(3) oxygens. The twelfth cation per unit cell is found as Na+ opposite 4-ring in the large cavities of M3Na9-A and assumed to be H+ for M3Na8H-A. With these noble non-framework cationic arrangements, larger M+ ions preferably on all larger 8-rings and the compact Na+ ions on all 6-rings, the bond angles in the 8-rings of M3-A, 145.1 and 161.0 respectively for (Si,Al)-O(1)-(Si,Al) and (Si,Al)-O(2)-(Si,Al), turned out to be remarkably stable and smaller, by more than 12 to 17°, than the corresponding angles found in the crystal structures of zeolites A with high concentration of M+ ions. It is to achieve these remarkably relaxed 8-rings, the main windows for the passage of gas molecules, with simultaneously maximized cavity volumes that M3-A have been selected as one of the efficient zeolite A systems for gas encapsulation.

On The Development of The Stern Form with Low Resistance and High Propulsive Efficiency for Full Ships (저저항(低抵抗) 고추진(高推進) 효율(效率)의 비대선(肥大船) 선미선형(船尾船型)의 개발(開發)에 관하여)

  • Ho-Chung,Kim;Chun-Ju,Lee;Young-Bok,Choi
    • Bulletin of the Society of Naval Architects of Korea
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    • v.27 no.3
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    • pp.89-99
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    • 1990
  • It is required to develop a hull form with low resistance and high propulsive efficiency for the improvement of the ship-board operational economy. Since the hull forms with low resistance frequently have lower propulsive efficiency and on the other hand the hull forms with higher propulsive efficiency don't show good resistance characteristics, it is always very difficult to obtain economical hull forms which require less propulsive power accordingly. Efforts have been made to pursue a stern form with excellent resistance and propulsion characteristics together by shaping the run of the so-called buttock-flow type stern, which is known to have good viscous resistance performance, like that of conventional aftbody(U-type or Hogner type) featured by high propulsive efficiency. First model tests confirmed that the above concept can be one of the alternative approaches to the design of the good stern form and by the continuing efforts thereafter for the refining of the concept, propelled by the first promising results, stern form of good resistance performance together with good propulsive efficiency has been realized to some extent. In addition, it is confirmed that the new new stern can have better cavitation and vibration characteristics due to uniform wake-fields and the compact engine room arrangement can be possible due to it's larger floor area in way of engine room double bottom as compared with usual barge stern.

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Structures of OH Emulsion Prepared with Saccharide Surfactants (당류계 계면활성제로 제조된 O/W 에멀젼의 구조)

  • 홍세흠;한창규;조춘구
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.261-274
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    • 2000
  • The o/w emulsions were prepared with saccharide surfactants which were sucrose monostearate(S160), sucrose distearate(S110), and POE(20) methyl glucose stearate(SSE20). And for emulsion the oils used were n-hydocarbon, squalane(SQ), liquid paraffin(LP), octylpalmitate(OP), octylstearate(OS), alkyl benzoate(AB), isostearyl benzoate(ISB). The structures of o/w emulsion droplet were investigated by laser light scattering and the fractal dimensions were calculated from light intensity curves. Increasing of concentration, chain length, and nonpolarity of oils, fractal dimensions of emulsion droplets were found greater. In general fiactal dimensions were varied from 1.7 to 2.8 and its structures were fractal But the fractal dimensions of octadecane( $C_{18}$), 50, and LP emulsified with S110 and S160 were varied from 3.0 to 3.2 and its structures were more dense. The overall fractal dimensions of S110 and S160 were varied from 2.1 to 2.6, that of SSE20 were varied from 1.5 to 2.1. So it was found that the structures of SSE20 system were less compact than that of S110 and S 160 system, because the hindrance effect of polyoxyehtylene group of SSE20 was stronger than that of sucrose of S160. The strucures of emulsion droplets changed according to the nature of emulsifiers and to compositions of oil substances which they contained, and the structures were found similar when the hydophilic moiety of emulsifiers was same.

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Optical pulse parameter analysis of gain switched InGaAIP FP LD at 650 nm wavelegth and its characteristic in comparison with CW operation (이득스위칭을 이용한 650nm InGaAIP FP LD의 광펄스 파라메터 분석 및 CW 발진과의 특성비교)

  • 오광환;채정혜;이용탁;백운출;김덕영
    • Korean Journal of Optics and Photonics
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    • v.12 no.2
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    • pp.135-142
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    • 2001
  • Recently, plastic optical fiber draws a lot of attention as a new transmission medium for local area network (LAN) and home network applications. As PMMA based GI-POF (Graded Index Plastic Optical Fiber) has very low loss at about 500 nm and 650 nm wavelengths, it is very important to have a compact ultra short optical pulse source at these wavelength windows. In this paper, we have investigated detailed characteristics of gain switched laser system by using a commercially available low cost RF devices and an InGaAlP Fabry Perot semiconductor laser operating at 650 nm wavelength. The shortest optical 'pulse obtained was 33 psec with 1 GHz repetition rate. Depending on the DC bias current and the modulation frequency, the FWHM and the pulse energy of the gain switched pulses show 33.3-82.8 psec and 0.97-9.69 pI respectively. Also, the spectral bandwidths for CW and gain switched operations are 0.44 nm and 1.50 nm. We believe that these results are quite useful for high bit rate optical transmission applications with PMMA based plastic optical fibers in addition to estimate properties of ultra fast optical components and electro-optic devices. vices.

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The Generalized Characteristics of Extinction Ratio for a Directional Coupler and Design of Compact 1310/1550 nm Demultiplexer (방향성 결합기 소멸비 특성의 일반화 경향과 파장분리기의 소형화 설계)

  • Choi, Chul-Hyun;O, Beom-Hoan;Lee, Seung-Gol;Park, Se-Geun;Lee, El-Hang
    • Korean Journal of Optics and Photonics
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    • v.16 no.5
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    • pp.446-449
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    • 2005
  • In a directional coupler, the design process requires repeated calculation of the characteristics of every changed structure, because it is generally difficult to expect the extinction ratio to be optimized over the entire variation of design parameters. In this paper, we systematically simulated the extinction ratio as a function of the design parameters, and analyzed the general tendency of that characteristic. In other words, we could find the generalized extinction ratio curve if the separation distance is normalized by the waveguide width. Here, the extinction ratio is shown to be increased as the normalized frequency (v) and the ratio (d) of the separation distance over the waveguide width were increased. For various structures with same ratio d, all corresponding extinction ratio curves as a function of v coincide with each other. We showed the usefulness of the generalized extinction ratio curve by applying it to the design and the fabrication of 1310/l550 nm demultiplexer, as it was convenient to design a shorter directional coupler with targeted extinction ratio from this curve.

Integrated Photonic Microwave Bandpass Filter Incorporating a Polymer Microring Resonator (폴리머 마이크로링 공진기를 이용한 광학적 마이크로웨이브 대역통과 필터)

  • Chin, Won-Jun;Kim, Do-Hwan;Song, Ju-Han;Lee, Sang-Shin
    • Korean Journal of Optics and Photonics
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    • v.16 no.5
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    • pp.469-475
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    • 2005
  • An integrated photonic microwave bandpass filter has been proposed and demonstrated incorporating a coherently coupled microring resonator in low-loss polymers. The proposed device may feature compact site, simple structure, tuning via the thermooptic and electrooptic effect, and flexible integration with other electrical and optical devices. The resonator was designed to have an extremely small bandwidth so that it could be used to selectively pass the optical signal carrying the microwave signal to attain efficient bandpass filtering. We made and tested two resonators with a single ring and double rings, and performed a theoretical fitting of their measured transfer curves to predict the performance of the microwave filters based on them precisely. It was found that as the number of the rings used for the resonator increases, the bandwidth gets smaller, the rolloff sharper, and the band rejection higher. Finally our filter exhibited the center frequency of 10GHz, the 3-dB bandwidth of 1.0GHz, the corresponding quality (Q) factor of 10, and the rejection outside of the passband of more than 25dB.

Catadioptric Omnidirectional Optical System Using a Spherical Mirror with a Central Hole and a Plane Mirror for Visible Light (중심 구멍이 있는 구면거울과 평면거울을 이용한 가시광용 반사굴절식 전방위 광학계)

  • Seo, Hyeon Jin;Jo, Jae Heung
    • Korean Journal of Optics and Photonics
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    • v.26 no.2
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    • pp.88-97
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    • 2015
  • An omnidirectional optical system can be described as a special optical system that images in real time a panoramic image with an azimuthal angle of $360^{\circ}$ and the altitude angle corresponding to the upper and lower fields of view from the horizon line. In this paper, for easy fabrication and compact size, we designed and fabricated a catadioptric omnidirectional optical system consisting of the mirror part of a spherical mirror with a central hole (that is, obscuration), a plane mirror, the imaging lens part of 3 single spherical lenses, and a spherical doublet in the visible light spectrum. We evaluated its image performance by measuring the cut-off spatial frequency using automobile license plates, and the vertical field of view using an ISO 12233 chart. We achieved a catadioptric omnidirectional optical system with vertical field of view from $+53^{\circ}$ to $-17^{\circ}$ and an azimuthal angle of $360^{\circ}$. This optical system cleaniy imaged letters on a car's front license plate at the object distance of 3 meters, which corresponds to a cut-off spatial frequency of 135 lp/mm.

Microbial Contamination in a Fresh-Cut Onion Processing Facility (신선편이 양파 가공작업장 내의 시설 및 공정별 미생물 오염 실태)

  • Lee, Hye-Ok;Kim, Ji-Young;Yoon, Doo-Hyun;Cha, Hwan-Soo;Kim, Gun-Hee;Kim, Byeong-Sam
    • Food Science and Preservation
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    • v.16 no.4
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    • pp.567-572
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    • 2009
  • We evaluated the microbiological quality of a facility in which freshly cut onions were prepared. The total plate counts on walls, equipment, and raw materials were ND (not detected) to $10^1$ CFU/100 $cm^2$, $10^0{\sim}10^3$ CFU/100 $cm^2$, and $10^3{\sim}10^4$ CFU/g, respectively. No coliforms were detected on walls however, coliforms were detected at concentrations of ND to $10^3$ CFU/100 $cm^2$ and $10^3{\sim}10^4$ CFU/g on equipment and raw materials, respectively. The total plate counts for falling and floating bacteria in the processing plant were ND to $10^0$CFU/plate and $10^1{\sim}10^2$ $CFU/m^3$, respectively. Pathogenic microorganisms such as Escherichia coli, Salmonella spp, Staphylococcus aureus, and Listeria monocytogenes were not detected on walls, equipment, or raw materials. Overall, the results of the study indicate that hygiene control at the fresh-cut processing plant should be improved.

Fabrication and Evaluation of Diameter 1 m Off-axis Parabolic mirror (직경 1 m 비축포물면의 가공 및 평가)

  • Yang, Ho-Soon;Lee, Jae-Hyeob;Jeon, Byung-Hyug;Lee, Yun-Woo;Lee, Kyoung-Muk;Choi, Se-Chol;Kim, Jong-Min
    • Korean Journal of Optics and Photonics
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    • v.19 no.4
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    • pp.287-293
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    • 2008
  • The collimator which makes a collimated beam, is an essential instrument for assembly and evaluation of telescopes. Recently, the Cassegrain type collimator has been widely used for its compact size as the focal length of high resolution cameras becomes longer. However, this kind of collimator has a disadvantage in that the secondary mirror is a heat source which can degrade the evaluation accuracy for an IR camera system. In this paper, we present the fabrication and measurement process for an off-axis parabolic mirror with the physical diameter pf 1 m, effective diameter 930 mm, and the focal length 6 m. After four months of works we obtained the final surface wave-front error of 30.4 nm rms ($\lambda$/138, ${\lambda}=4.2\;{\mu}m$), which is capable of evaluation of an IR camera as well as a visible camera.

Effect of Diflubenzuron on Silkgland Development of Silkworm, Bombyx mori (Lepidoptera: Bombycidae) (Diflubenzuron이 누에의 실샘 발달에 미치는 영향)

  • 김영섭;손해룡
    • Journal of Sericultural and Entomological Science
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    • v.43 no.2
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    • pp.77-82
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    • 2001
  • This study was investigated to know the effects of diflubenzuron(DFB) on the larval silkgland development of the silk-worm, Bombyx mori (L.). It has been known as a prohibitor of chitin synthesis mostly on the species of the Order Lepidoptera. In this work, the effects of the DFB concentrations (2.5$\times$10$\^$-1/,2.5$\times$10$\^$-2/, and 2.5$\times$10$\^$-3/$\mu\textrm{g}$/$\mu$l on the various larval stages, were investigated in terms on the silkgland. The macro- and microstructure of cell membrane of silkgland, and the differences of silkgland weight and water contents treated by DFB are also surveyed. As the tesults, the silkgland weight depended sensitively on not the DFB concentration but the DFB treatment period. The longer DFB treatment period, the lighter dried silkgland weight and the heavier water content of the silkgland. White opaque(WO) emerged in the middle silkgland of DFB treated larva. From the scanning election microscope observation, the cell membrane of silkgland of DFB treated larva was distinctly more compact compared to that of control. The WO was evidently resulted from the obstacles of normal transformation of silk protein through the cell membrane of middle silkgland.

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