• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
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• pp.61-64
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• 2002

A novel ceramic synthesis technique, combustion synthesis, is explored to produce a orange-emitting $SnO_{2}:Eu^{3+}$ phosphors. This technique involves a reaction of metal salts with a citric acid as an organic fuel. The variation of the ratio of citric acid to metal introduces change in reaction temperature and atmosphere of the combustion reaction, which in turn influences crystallinity and luminescence properties of the final products seriously. And, the heat treatment of the as-synthesized product increases its luminescence intensity. Especially, the samples treated at above $1100^{\circ}C$ show a orange-emission peak, which is attributed to the formation of single phase and well-crystallized $SnO_{2}:Eu$ oxides in the rutile structure

• Korean Chemical Engineering Research
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• 제49권6호
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• pp.857-864
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• 2011

순산소연소는 높은 연소 효율과 적은 배가스량, 낮은 질소산화물 농도를 장점으로 하고 있으며 연소온도 조절을 위한 배가스 재순환에 의해 배출되는 연소가스중의 $CO_2$ 농도를 95%까지 농축이 가능하므로 석탄 연소설비에 대한 유망한 CCS 기술로 부각되고 있다. 본 연구는 순산소연소 조건에서 배가스의 재순환을 통한 $CO_2$ 농도 증가에 기인하는 직접 황화반응이 탈황효율에 미치는 영향을 평가하고 반응온도, $CO_2$ 농도, $SO_2$ 농도상승이 $SO_2$ 제거효율에 미치는 영향과 배가스 중 수분 등이 $SO_2$ 제거효율에 미치는 영향을 실험적으로 고찰하였다. 반응온도 $1,200^{\circ}C$까지 온도 상승에 따라 $SO_2$의 제거효율은 증가하였고 Ca/S비, $CO_2$ 농도와 수분이 증가할수록 $SO_2$ 제거효율이 증가하였다. 이러한 운전변수는 영향인자 평가를 통하여 Ca/S 비>체류시간>$O_2$농도>반응온도>$SO_2$농도>$CO_2$농도>수분농도의 순으로 탈황반응에 영향을 미치는 것으로 나타났다. 또한 운전변수별 실험결과를 이용하여 로내 건식탈황에 있어서 각 운전변수별 성능 영향인자를 평가할 수 있는 반경험적 모델식을 도출하였다.

• 한국산업융합학회 논문집
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• 제1권2호
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• pp.49-54
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• 1998

In the catalytic combustor, combustion characteristic and deterioration of catalysts were affected by non-uniformity of pre-mixed gas, Therefore, formation of uniform pre-mixed gas is one of important subjects. In this study, the effect of uniformity and non-uniformity of pre-mixed gas supplied to the catalyst was examined to clarify reaction acceleration and combustion characteristic of the catalytic combustion. It was clarified that static mixer or vaporizer tube length of about 150mm and weak swirl to a combustion air were effictive expedient to make uniform pre-mixed gas. And catalystic inlet temperature needs more than $600^{\circ}C$ with rich pre-mixed gas to active reaction.

• 한국연소학회지
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• 제22권4호
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• pp.9-18
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• 2017

This paper is to suggest a simple flame model for the analysis of an internal flame of rotary kilns and to present the application cases. Reaction rates in the multi combustion stages of the selected solid fuel were calculated considering the reaction rates with the Arrhenius type equations. In addition, primary and secondary air flow arrangement were considered. As a simple application case, the combustion trends according to the different solid fuels were described. Improved operating conditions as related with the fuel characteristics were shown to be important for the stable combustion characteristics and the performance of the reactors as defined by the exit temperature of the solid materials.

• 한국연소학회지
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• 제16권2호
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• pp.40-46
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• 2011

The diesel pre-heater has being used in cabin heating and coolant heating of engine to reduce the engine warm up time for commercial vehicle. The pre-heaters are classified as diesel spray combustor and it forms diffusion flame. By using swirler, a recirculation flow of hot product gases is established near the fuel nozzle and it helps the maintaining of diffusion flame. The design difference of swirler can affect on reaction characteristics and temperature distribution inside pre-heater. The purpose of this study is the investigation of the effect of swirler configuration on combustion characteristics. To solve spray combustion problem, the Euler-Lagrange approach discrete model is used to track droplet trajectory and evaporation history. The PDF equilibrium model is used for chemical reaction model. These models are implemented into the FLUENT code.

• 한국재료학회지
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• 제9권7호
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• pp.680-687
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• 1999

Fe-Al계 금속간화합물이 FACS (Field-Activated Combustion Synthesis) 법에 의해 제조되었다. 이 계의 반응에 있어서 조성 (Fe:Al=3 : 1,2 : 1, 1 : 1.1 : 2, 1 : 3) , 성형압력 (150, 250, 350MPa), 저항 등이 조사되었는데. Al의 몰비, 성형압력, 전기장의 세가가 증가함에 따라서 연소온도와 연소속도는 증가하였다. 또한 이 계에 있어서 전류적용방식에 따른 반응에 대한 영향이 조사되었다. 전기장이 적용되지 않는 경우, 반응이 일어나기 위해서는 예열이 필요하였고, 예열을 하였을 경우라도 그 반응은 불안정연소파를 나타내어 완전한 반응이 이루어지지 않았다. 생성물은 X-ray, SEM, EDXS를 사용하여 그 구조와 조성을 관찰하였다

• 한국연소학회지
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• 제2권1호
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• pp.29-38
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• 1997

In this study, the experimental and numerical investigations of the ignition of methane-air mixtures by a electrically heated wire have been carried out. In order to define the initial condition and make the analysis simple, the following control unit was developed; which heats the wire to the setting temperature in a very short time, and maintains the wire temperature constant until ignition. Experiments with the feedback control have been performed using nickel and platinum wires in normal gravity and microgravity. From experimental results, ignition temperatures in normal gravity are higher than those in microgravity, however, the dependences of ignition temperature on equivalence ratio are not affected by natural convection. Numerical calculations, including catalytic reaction for platinum, have been performed to analyze the experimental results in microgravity. Numerical results show that reactants near platinum wire are consumed by catalytic reaction, therefore, the higher temperature is needed to ignite the mixture with platinum wire.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.444-449
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• 2001

A numerical parametric study is conducted to simulate shock-induced combustion with a variation in freestream conditions. A steady combustion front is established if the freestream Mach number is above the Chapman-Jouguet speed of the mixture. On the other, an unsteady reaction front is established if the the freestream Mach number is below or at the Chapman-Jouguet speed of the mixture. The three cases have been simulated for Machs 4.18, 5.11, and 6.46 with a projectile diameter of 15 mm. Machs 4.18 and 5.11 shows an unsteady reaction front, whereas Mach 6.46 represents a steady reaction front. Thus Chapman-Jouguet speed is one of deciding factor for the instabilities to trigger.

• 대한기계학회논문집
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• 제17권12호
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• pp.3187-3195
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• 1993

Combustion of liquid-fuelled combustion in a high-temperature vitiated-air stream was studied. The mathematical formulation comprise the application of Eulerian conservation equation to the gas phase and Lagrangian equation of droplet motion. The latter is coupled with a droplet-tracking technique (PSI-CELL Model) which regard the droplet phase as a source of mass, momentum, and energy to the gaseous phase. Reaction rate is determined by taking into account the Arrhenius reaction rate based on a single-step reaction mechanism. The calculated profiles show somewhat uncertainess at the upstream, but bases data for designing the combustor followed by 2-phase flow were obtained.

• 대한기계학회논문집B
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• 제23권8호
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• pp.1022-1030
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• 1999

A numerical study was carried out to analyze the effect of flow distribution of stirred part and plug flow part on combustion efficiency at the coal gasification process in an entrained bed coal reactor. The model of computation was based on gas phase eulerian balance equations of mass and momentum. The solid phase was described by lagrangian equations of motion. The $k-{\varepsilon}$ model was used to calculate the turbulence flow and eddy dissipation model was used to describe the gas phase reaction rate. The radiation was solved using a Monte-Carlo method. One-step parallel two reaction model was employed for the devolatilization process of a high volatile bituminous Kideco coal. The computations agreed well with the experiments, but the flame front was closer to the burner than the measured one. The flow distribution of a stirred part and a plug flow part in a reactor was a function of the magnitude of recirculation zone resulted from the swirl. The combustion efficiency was enhanced with decreasing stirred part and the maximum value was found around S=1.2, having the minimum stirred part. The combustion efficiency resulted from not only the flow distribution but also the particle residence time through the hot reaction zone of the stirred part, in particular for the weak swirl without IRZ(internal recirculation zone) and the long lifted flame.