• 제목/요약/키워드: Combinatorial Material Science

검색결과 11건 처리시간 0.01초

Search for Phosphors for Use in Displays and Lightings using Heuristics-based Combinatorial Materials Science

  • Sharma, Asish Kumar;Sohn, Kee-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.207-210
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    • 2009
  • According to the recent demand for materials for use in various displays and solid state lightings, new phosphors with improved performance have been pursued consistently. Multi objective genetic algorithm assisted combinatorial material search (MOGACMS) strategies have been applied to various multi-compositional inorganic systems to search for new phosphors and to optimize the properties of phosphors.

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Combinatorial 방법으로 증착한 Zn-Sn-O계 박막의 열처리 효과 (Annealing effect of Zn-Sn-O films deposited using combinatorial method)

  • 고지훈;김인호;김동환;이경석;박종극;이택성;백영준;정병기;김원목
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.998-1001
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    • 2004
  • ZnO, $SnO_2$ 타겟 각각의 RF 파워를 50 W, 38 W로 고정시킨 후 combinatorial RF magnetron sputtering법을 사용하여 기판 위치에 따라서 조성 구배를 주어 여러 가지 조성의 Zn-Sn-O(ZTO) 박막을 제작하였다. 시편의 열처리에 따른 물성 변화를 분석하기 위해 Rapid Thermal Annealer(RTA)을 이용하여 450, $650{^\circ}C$의 온도 및 $10^{-2}$ Ton의 진공 분위기에서 각각 1 시간 동안 열처리하였다. XRD 분석 결과 상온에서 제작된 ZTO 박막은 Sn 18 at%의 조성을 갖는 시편을 제외하고 모두 비정질상으로 나타났다. $450^{\circ}C$에서 열처리 후 구조적인 변화는 보이지 않았으나, 캐리어 농도와 이동도는 증가하였으며 Sn 54 at%의 조성에서 최고 $25.4cm^2/Vsec$의 전자 이동도를 나타내었다. $26{\leq}Sn$ $at%{\leq}65$의 조성 범위를 갖는 박막은 가시광 영역에서 80 % 이상의 투과도를 가졌으며 $650^{\circ}C$에서 결정화가 되면서 투과도가 증가하였다.

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트레일러와 트렉터를 사용하는 하는 운송문제 분석 (Analysis of transportation problems with trailers and tractors)

  • 한윤택;장수영
    • 한국경영과학회:학술대회논문집
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    • 대한산업공학회/한국경영과학회 2006년도 춘계공동학술대회 논문집
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    • pp.1-8
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    • 2006
  • This paper considers an interesting transportation problem where trailers and tractors are involved in moving material. We identified a class of combinatorial optimization problems for minimizing the number of tractors and trailers required to accommodate the transportation needs. Then, we show that the fundamental problem is NP-hard and analyze its properties to develop efficient heuristic to handle the problem effectively.

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Novel characterisation methods for Polymer Applications

  • Bailey, R.S.;McNicol, A.;Lambert, P.
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.142-143
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    • 2006
  • Combinatorial methods are being used increasingly to develop the next generation of polymers, coatings and adhesive formulations. Allied to this approach, a new genre of measurement and characterization methods are emerging. These characterization techniques are required to handle and take measurements from small samples. This has led to a number of uses for this technology which usefully fall between convention test specimen and micro- or nano-scale test methods. A versatile measurement platform will be presented which can offer useful indentation, puncture, compression, adhesion and scratch resistance data for a wide variety of material types and that continues to develop and evolve in capability.

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Distinctive Combinations of RBD Mutations Contribute to Antibody Evasion in the Case of the SARS-CoV-2 Beta Variant

  • Tae-Hun Kim;Sojung Bae;Sunggeun Goo;Jinjong Myoung
    • Journal of Microbiology and Biotechnology
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    • 제33권12호
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    • pp.1587-1594
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    • 2023
  • Since its first report in 2019, severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has posed a grave threat to public health. Virus-specific countermeasures, such as vaccines and therapeutics, have been developed and have contributed to the control of the viral pandemic, which has become endemic. Nonetheless, new variants continue to emerge and could cause a new pandemic. Consequently, it is important to comprehensively understand viral evolution and the roles of mutations in viral infectivity and transmission. SARS-CoV-2 beta variant encode mutations (D614G, N501Y, E484K, and K417N) in the spike which are frequently found in other variants as well. While their individual role in viral infectivity has been elucidated against various therapeutic antibodies, it still remains unclear whether those mutations may act additively or synergistically when combined. Here, we report that N501Y mutation shows differential effect on two therapeutic antibodies tested. Interestingly, the relative importance of E484K and K417N mutations in antibody evasion varies depending on the antibody type. Collectively, these findings suggest that continuous efforts to develop effective antibody therapeutics and combinatorial treatment with multiple antibodies are more rational and effective forms of treatment.

Growth Mechanism of SnO Nanostructures and Applications as an Anode of Lithium-ion Battery

  • Shin, Jeong-Ho;Park, Hyun-Min;Song, Jae-Yong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.598-598
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    • 2012
  • Rechargeable lithium-ion batteries have been considered the most attractive power sources for mobile electronic devices. Although graphite is widely used as the anode material for commercial lithium-ion batteries, it cannot fulfill the requirement for higher storage capacity because of its insufficient theoretical capacity of 372 mAh/g. For the sake of replacing graphite, Sn-based materials have been extensively investigated as anode materials because they can have much higher theoretical capacities (994 mAh/g for Sn, 875 mAh/g for SnO, 783 mAh/g for $SnO_2$). However, these materials generate huge volume expansion and shrinkage during $Li^+$ intercalation and de-intercalation and result in the pulverization and cracking of the contact between anode materials and current collector. Therefore, there have been significant efforts of avoiding these drawbacks by using nanostructures. In this study, we present the CVD growth of SnO branched nanostructures on Cu current collector without any binder, using a combinatorial system of the vapor transport method and resistance heating technique. The growth mechanism of SnO branched nanostructures is introduced. The SnO nanostructures are evaluated as an anode for lithium-ion battery. Remarkably, they exhibited very high discharge capacities, over 520mAh/g and good coulombic efficiency up to 50 cylces.

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조합화학을 이용한 Y(As, Nb, P, V)O4:Eu3+ 적색형광체의 합성 및 광 특성 분석 (Synthesis and Luminescent Properties of Y(As, Nb, P, V)O4:Eu3+ Red Phosphors by Combinatorial Chemistry Method)

  • 전일운;손기선;박희동;류승곤
    • 대한화학회지
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    • 제45권6호
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    • pp.577-588
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    • 2001
  • 조합화학 기법을 적용하여 $YRO_4$ (R=As, Nb, P, V)계 모체에 Eu을 활성하여 적색형광체를 합성하였다. 합성된 형광체는 UV PL,VUV PL, 및 색좌표 분석을 하였고, 254nm 및 147nm 여기하에서의 발광세기 및 색좌표 사면체 라이브러리를 완성하였다. Eu이 0.1 mol 도핑된 적색 형광체는 254nm로 여기 시켰을 때 $YRO_4$를 중심으로 다른 중심으로 다른 성분이 미량 첨가되었을 때 가장 좋은 발광 세기를 나타내었으나. 147nm에서는 $YRO_4$를 중심으로 좋은 발광 세기가 나타났다. 합성된 형광체 중 $Y_{0.9}$(A$S_{0.06}$N$B_{0.06}$$P_{0.83}$$V_{0.06}$) $O_4$: $Eu_{0.1}$의 조성으로 1200$^{\circ}C$에서 소성하였을 때 상용 형광체와 대등한 발광세기가 색순도가 우수하였다.

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고분자 착체 조합 화학법을 이용한 Tb이 첨가된 $SrO-Gd_2O_3-Al_2O_3$계 형광물질의 합성 및 탐색 (Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry)

  • 정양선;김창해;박희동;박준택;강성권
    • 대한화학회지
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    • 제45권5호
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    • pp.461-469
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    • 2001
  • 조합화학은 한번에 여러 후보 물질을 소량 합성하여 원하는 물성을 갖는 물질을 탐색하는 기술이다. 본 연구에서는 고분자 착체 조합 화학법을 이용하여, 터븀이 도핑된 $SrO-Gd_2O_3-Al_2O_3$계에 대한 형광 물질을 합성하고 특성을 검색하였다. 합성 실험은 세 성분의 조성이 약 0.05몰씩 차이를 갖게하되 모든 금속 이온 당량의 합이 1몰이 되도록 작성한 조성표에 따라 금속이온 용액, 구연산 용액 및 에틸렌 글리콜 용액을 사용하여, 고분자 착체 전구체를 형성하는 Pechini법으로 합성하였다. 합성된 전구체를 1000~1500$^{\circ}C$로 열처리한 후 제조된 분말을 UV PL(Photoluminescence)과 VUV(Vacuum-UV: 147nm) PL로 측정하여 그 특성을 검토하였다. 또한 합성된 분말의 결정성과 입자형상은 XRD와 SEM을 이용하여 확인하고 관찰하였다. UV PL 측정 결과, 240nm 여기하에서는 $Sr_{0.6}Gd_{0.12}Al_{0.17}Tb_{0.1}$$O_{\delta}$, 275 nm 여기하에서는 $Sr_{0.03}Gd_{0.89}Al_{0.03}Tb_{0.06}O_{\delta}$$Sr_{0.6}Gd_{0.12}Al_{0.17}Tb_{0.1}O_{\delta}$ 그리고 307nm 여기하에서는 $Sr_{0.03}Gd_{0.89}Al_{0.03}Tb_{0.06}O_{\delta}$의 조성에서 543nm의 발광 세기가 크게 나타났다. 그리고 VUV PL 측정 결과는 $Gd_{1-x-y}Al_xTb_yO_{\delta}$: 0.595 < x < 0.733, 0.016 < y < 0.017 그리고 $Sr_xAl_{1-x-y}Tb_yO_{\delta}$: 0.049 < x < 0.064, 0.02 < y < 0.039의 조성범위에서 345nm 의 발광세기가 크게 나타났다. 이 조성의 녹색 형광체는 plasma display panel에 적용 가능하다.

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2-Stage Optimal Design and Analysis for Disassembly System with Environmental and Economic Parts Selection Using the Recyclability Evaluation Method

  • Igarashi, Kento;Yamada, Tetsuo;Inoue, Masato
    • Industrial Engineering and Management Systems
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    • 제13권1호
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    • pp.52-66
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    • 2014
  • Promotion of a closed-loop supply chain requires disassembly systems that recycle end-of-life (EOL) assembled products. To operate the recycling disassembly system, parts selection is environmentally and economically carried out with non-destructive or destructive disassembly, and the recycling rate of the whole EOL product is determined. As the number of disassembled parts increases, the recycling rate basically increases. However, the labor cost also increases and brings lower profit, which is the difference between the recovered material prices and the disassembly costs. On the other hand, since the precedence relationships among disassembly tasks of the product also change with the parts selections, it is also required to optimize allocation of the tasks in designing a disassembly line. In addition, because information is required for such a design, the recycling rate, profit of each part and disassembly task times take precedence among the disassembly tasks. However, it is difficult to obtain that information in advance before collecting the actual EOL product. This study proposes and analyzes an optimal disassembly system design using integer programming with the environmental and economic parts selection (Igarashi et al., 2013), which harmonizes the recycling rate and profit using recyclability evaluation method (REM) developed by Hitachi, Ltd. The first stage involves optimization of environmental and economic parts selection with integer programming with ${\varepsilon}$ constraint, and the second stage involves optimization of the line balancing with integer programming in terms of minimizing the number of stations. The first and second stages are generally and mathematically formulized, and the relationships between them are analyzed in the cases of cell phones, computers and cleaners.

CaO-Gd2O3-Al2O3계에서의 PDP용 Eu3+와 Tb3+ 활성 형광체의 탐색 (Screening of Eu3+-and Tb3+-Activated Phosphors for PDP in the System of CaO-Gd2O3-Al2O3)

  • 박상미;김창해;박희동;장호겸;박준택
    • 대한화학회지
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    • 제46권4호
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    • pp.336-345
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    • 2002
  • 본 연구에서는 조합화학을 이용하여 $CaO-Gd_2O_3-Al_2O_3$계에서 $Eu^{3+}$$Tb^{3+}$활성 적색 및 녹색 PDP용 형광체를 탐색하였으며 탐색된 형광체의 합성온도, 최적조성,발광 특성 등을 조사하였다. $CaO-Gd_2O_3-Al_2O_3$의 삼성분계의 형광특성 라이브러리를 작성하기 위하여 210개의 다른 조성을 가진 시료를 고분자 착체 중합법으로 합성하였다. 합성된 형광체 분말을 VUV PL로 측정하여 형광 특성 라이브러리를 작성하였고 발광특성이 잘 나타난 시료를 XPD를 이용하여 결정 구조를 확인하였다. 적색 형광체로서 탐색된 $Ca_{\alpha}$G$d_{0.95-\alpha-\beta}$$Al_\beta$$O_\delta$ : Eu(0.02< $\alpha+\beta$ <0.04)형광체는 색순도 면에서 상용형광체보다 개선된 특성을 보였으며 녹색 형광체로서 탐색된 $CaGdAl_3O_7$ : Tb, Ca$Al_{12}$$O_{19}$ : Tb, $Gd_4Al_2$$O_9$ : Tb, $Gd_3Al_5$$O_{12}$ : Tb 형광체 중에서 $CaGdAl_3O_7$ : Tb, Ca$Al_{12}$$O_{19}$ : Tb형광체는 상용 형광체에 비해 잔광시간이 짧은 특성을 보였다