• Journal of Korean Society on Water Environment
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• v.32 no.1
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• pp.23-29
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• 2016

Ozonation was investigated for its ability to remove pyruvic acid in a laboratory-scale batch reactor under various experimental conditions, including UV irradiation, TiO₂ addition, and variations in temperature. An ozone flow rate of 1.0 L min^-1 and a concentration of 75±5 mg L^-1 were maintained throughout the experiment, and pH, COD, and TOC were measured at 10 min intervals during a 60 min reaction. Our results confirmed that the combination of UV irradiation and photocatalytic TiO₂ in the ozonation reaction improved the removal efficiency of both COD and TOC in aqueous solution at 20℃. Pseudo first-order rate constants and activation energies were quantified based on the COD and TOC measurements. We observed that the O₃/UV, O₃/UV/TiO₂ system increased mineralization and reduced the activation energy (E_a) necessary for pyruvic acid decomposition.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.337-343
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• 2013

Membrane reactors have been showing a promising future and attracted increasing attention in the scientific community as they possess advantages in terms of enhanced catalytic activity and selectivity, combination of processes (reaction and separation), simplicity in process design, and safety in operation. In particular, solid electrolyte membrane reactor principles are realized in fuel cells, electrolyzers and reactors for hydrogenation of carbon dioxide and other economically viable reactions. In this review, as a young generation of ion conducting materials, high temperature proton conductors are discussed in terms of the current status of material development and their various applications.

• 제어로봇시스템학회:학술대회논문집
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• 1999.10a
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• pp.57-60
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• 1999

An optimal control technique designed for simultaneous tracking and quality control for batch processes. The proposed technique is designed by transforming quadratic-criterion based iterative learning control(Q-ILC) into linear quadratic control problem. For real-time quality inferential control, the quality is modeled by linear combination of control input around target qualify and then the relationship between quality and control input can be transformed into time-varying linear state space model. With this state space model, the real-time quality inferential control can be incorporated to LQ control Problem. As a consequence, both the quality variable as well as other controlled variables can progressively reduce their control error as the batch number increases while rejecting real-time disturbances, and finally reach the best achievable states dictated by a quadratic criterion even in case that there is significant model error Also the computational burden is much reduced since the most computation is calculated in off-line. The Proposed control technique is applied to a semi-batch reactor model where series-parallelreactions take place.

• Nuclear Engineering and Technology
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• v.52 no.2
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• pp.238-247
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• 2020

The Burnable Poison (BP) is very important for all Light Water Reactors in order to hold-down the initial excess reactivity and to control power peaking. The use of BP is even more essential as the excess reactivity increases significantly with a longer operation cycle. In this paper a feasibility study was conducted in order to investigate the benefits of a new combinational BP concept designed for 24-month cycle PWR core. The reference designs in this study are based on the two Korean fuel assemblies; 17 × 17 Westinghouse (WH) design and 16 × 16 Combustion Engineering (CE) design. A modification was done on these two designs to extend their cycle length from 18 months into 24 months. DeCART2D-MASTER code system was used to perform assembly and core calculations for both designs. A preliminary test was conducted in order to choose the best BP suitable for 24-month as a representative for single BP concept. The comparison between the results of two concepts (combinational BP concept and single BP concept) showed that the combinational BP concept can replace the single BP concept with better performance on holding down the initial excess reactivity without violating the design limitations.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.4
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• pp.449-454
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• 2008

Some pretreatment methods have been proposed to enhance the biodegradability and to shorten the hydrolysis reaction time. By means of efficient pretreatment the suspended solids (SS) can be made of better accessible for the anaerobic bacteria. There are several ways how this can be accomplished, which include biological, mechanical, thermal, and chemical methods. For the sludge solubilization using the cavitation phenomenon, we have tried to develop a pretreatment process consisted of a reactor and pumps. The objectives of this study were to develop a advanced wastewater treatment consisted of IABR and the cavitation with PGA. The most effective removal for organic matter and nutrients were occured when both cavitation pretreatment and ${\gamma}$-PGA were applied at the IABR process. Only small portion of ${\gamma}$-PGA at a rate of 1.38mg/L, was enough to improve sedimentation ability, SS removal efficiencies, and sludge volume reduction. After the sludge solubilization by the cavitation, SCOD increased to 193% and SS decreased to 36%. The removal ratio of BOD was 94.5%, T-N removal ratio was 85.5% and T-P removal ratio was 84.9%. The combination process of the IABR with the cavitation and PGA addition seems to be very effective alternative wastewater treatment process.

• Transactions of the Korean hydrogen and new energy society
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• v.15 no.3
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• pp.187-193
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• 2004

In this study, Anaerobic sewage sludge in a batch reactor operation at $35^\circ{C}$ was used as the seed to investigate the effect of pretreatments of waste activated sludge and to evaluate its hydrogen production potential by anaerobic fermentation. Various pretreatments including physical, chemical and biological means were conducted to utilize for substrate. As a result, SCODcr of alkali and mechanical treatment was 15 and 12 times enhanced, compared with a supernatant of activated sludge. And SCODcr was 2 time increase after re-treatment with biological hydrolysis. Those were shown that sequential hybridized treatment of sludge by chemical & biological methods to conform hydrogen production potential in bath experiments. When buffer solution was added to the activated sludge, hydrogen production potential increased as compare with no addition. Combination of alkali and mechanical treatment was higher in hydrogen production potential than other treatments.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.19 no.1
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• pp.169-174
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• 2005

The conventional harmonic filters to reduce zero harmonic current from neutral reactors and Zig-Zag connection, have several disadvantages of the decreased reduction rate of harmonics under a light load, because they have the load factor-dependent reduction rate of harmonics, and the risk of potential breaking in the neutral line by heated neutral reactor. Based Zig-Zag connection and Open-Delta mode, this new harmonic eliminating device (HANOS) adopts the combination of Zig-Zag connection and Open-Delta mode-the latter is additionally applied to the transformer's core block for connection to the neutral line. The results of this study demonstrated that the new device could eliminate safely zero harmonic current running in the neutral line without heating.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.1
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• pp.105-112
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• 2002

In recent years, the integrity of reactor Pressure Vessel(RPV) under pressurized thermal shock (PTS) accident has been treated as one of the most critical issues. Under PTS condition, the combination of thermal and mechanical stress by steep temperature gradient and internal pressure causes considerably high tensile stress at the inside of RPV wall. As a result, cracks on inner surface of RPV may experience elastic-plastic behavior which can be characterized by J-integral. In such a case, however, J-integral may possibly lose its vapidity due to the constraint effect. The degree of constraint effect is influenced by the loading mode, crack geometry and material properties. In this paper, in order to investigate the effect of clad thickness and crack geometry on constraint effect, three dimensional finite element analyses were performed for various surface cracks. Total of 27 crack geometries were analyzed and results were presented by a two-parameter characterization based on the J-integral and the f-stress.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2001.11a
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• pp.19-26
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• 2001

The wear characteristic of Zircaloy-4 tube, which is used for a cladding of light water reactor fuel rod, is investigated experimentally. The experiment is conducted with contacting the crossed tube specimens in air as well as in water at room temperature with various combination of contact normal force and sliding distance of reciprocating motion. The contour and the volume of each wear are examined to study the effect of contact condition and environment on wear. As a result, it is found that the wear volume in the water environment is larger than that in the air for all the contact (i.e., force and sliding distance) conditions. However, the wear depth is greater in air than in water if the contact normal force and the sliding distance are larger. These are explained by the ease of detachment of wear particles from the contact surface. On the other hand, workrate model is applied with the contact shear force range measured by our wear tester. Investigated is the correlation between the workrate and the wear volume increase rate of the present experiment. The parabolic curve is found to fit well for the present wear data.

• Nuclear Engineering and Technology
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• v.42 no.5
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• pp.590-599
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• 2010

Recently, efficient operation and practical management of power plants have become important issues in the nuclear industry. In particular, typical aging parameters such as stress and cumulative usage factor should be determined accurately for continued operation of a nuclear power plant beyond design life. However, most of the major components have been designed via conservative codes based on a 2-D concept, which do not take into account exact boundary conditions and asymmetric geometries. The present paper aims to suggest an effective fatigue evaluation methodology that uses a prototype of the integrated model and its transfer functions. The validity of the integrated 3-D Finite Element (FE) model was proven by comparing the analysis results of individual FE models. Also, mechanical and thermal transfer functions, known as Green's functions, were developed for the integrated model with the standard step input. Finally, the stresses estimated from the transfer functions were compared with those obtained from detailed 3-D FE analyses results at critical locations of the major components. The usefulness of the proposed fatigue evaluation methodology can be maximized by combining it with an on-line monitoring system, and this combination, will enhance the continued operations of old nuclear power plants.