• Title/Summary/Keyword: Colorimetric

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Camparision and Analysis about the Weighted-Ordinate Colorimetric Method and the Direct Colorimetric Method of Halftone Dot Printing Colors (망점색인쇄물의 분광측색법과 자극치직독측색법에 대한 비교분석)

  • SangNamLee
    • Journal of the Korean Graphic Arts Communication Society
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    • v.6 no.1
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    • pp.13-39
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    • 1988
  • Test colors are halftone dot printed at the rate of 10% halftone dot area by process inksblack, cyan, magenta and yellow ink. Reproduced colors are measured by the weighted-ordinate colorimetric method and the direct colorimetric method. The weighted-ordinate colorimetric method compare favorably with the direct colorimetric method, because the former has good regular changes of tristimuIus values, chromacity coordinates, excitation purities, value functions and has smaller errors of dominant and complementary wavelengths than the latter. All test colors classify with the Munsell renotation.tation.

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A Study for the Calculation of the Surface Chloride on the concrete by using Colorimetric method (비색판별법을 이용한 콘크리트의 표면염화물량 산정)

  • 이진우;이문환;서치호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.815-820
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    • 2001
  • This study is to set a new standard for using of the colorimetric method through grasping the character of the colorimetric method, and measuring the chloride concentration at the place of the change of color. Also, to predict chloride concentration around rebar and time reaching limit chloride concentration through measuring the chloride concentration of concrete surface by the colorimetric method and this study presents the new program of concrete degradation and diagnosis of the durability by salt damage. First the use of the colorimetric method was examinated, second the chloride concentration through slicing concrete submerged in artificial seawater for 6 months was measured. And the chloride concentration at the place of the change of color was calculated by using colorimetric method. Finally, the cloride concentration of the concrete surface was calculated.

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Application of Colorimetric Method for Evaluation of Apparent Chloride Diffusion Coefficient of Concrete (콘크리트 중 겉보기 염소이온 확산계수 추정을 위한 비색법의 적용)

  • 문한영;김홍삼;최두선;오세민
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.541-544
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    • 2003
  • Chloride diffusivity is one of the important properties of concrete affecting the durability of a structure. The diffusivity for porous materials is determined conventionally by immersion in a solution. However, this method is complicate and time-consuming, often requiring months or years to obtain results. Thus, the application of colorimetric method to estimate the apparent diffusivity of chloride ion was verified in this study. The result reveals that the apparent diffusivity of chloride ion can be predicted to use colorimetric method. Additionally the colorimetric method is capable to predict the profile of chloride ion.

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Estimating dehalogenation reactivity of nanoscale zero-valent iron by simple colorimetric assay by way of 4-chlorophenol reduction

  • Mines, Paul D.;Kaarsholm, Kamilla M.S.;Droumpali, Ariadni;Andersen, Henrik R.;Hwang, Yuhoon
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.197-204
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    • 2020
  • A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.

Role of Gel to Fluid Transition Temperatures of Polydiacetylene Vesicles with 10,12-Pentacosadiynoic Acid and Cholesterol in Their Thermochromisms

  • Kwon, Jun Han;Song, Ji Eun;Yoon, Bora;Kim, Jong Man;Cho, Eun Chul
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1809-1816
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    • 2014
  • This study demonstrates gel-to-fluid transition temperatures of polydiacetylene bilayer vesicles could play important roles in their colorimetric transition temperatures. We prepared five types of polydiaceylene vesicles with 10,12-pentacosadiynoic acid (PCDA) and cholesterol (0-40 mol % of total content). From temperature-dependent observations of the optical signals (colors and UV-vis spectra), the blue-to-red colorimetric transition temperatures of polydiacetylene vesicles were decreased with the cholesterol contents. A further study with microcalorimetry and dynamic light scattering revealed that the polydiacetylene vesicles first underwent gel-to-fluid transitions, which were followed by event(s) responsible for the colorimetric transitions. Energies required for each event were quantified from analysis of the peaks in the microcalorimetry thermograms. The inclusion of cholesterol in the vesicles decreased both the gel-to-fluid and the colorimetric transition temperatures, suggesting that the colorimetric transition of the polydiacetylene vesicles was mediated by the former event although the event was not the direct reason for the color change.

Highly Sensitive Colorimetric Formaldehyde Gas Sensors using Nylon Sheet and Dye (나일론 시트와 염료를 이용한 고감도 색변환 포름알데히드 가스 센서)

  • Jung, Suenghwa;Cho, Yeong Beom;Kim, Yong Shin
    • Journal of Sensor Science and Technology
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    • v.26 no.6
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    • pp.420-426
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    • 2017
  • A colorimetric sensor was investigated to achieve a low-cost warning device for harmful gaseous formaldehyde (HCHO). The sensor is based on selective reactions between hydroxylamine sulfate and HCHO, leading to the production of sulfuric acid. The produced acid results in color-changing response through the acid-base reaction with dye molecules impregnated on a solid membrane substrate. For attaining this purpose, sensors were fabricated by drop-casting a dye solution prepared using different pH indicators on various commercially available polymer sheets, and their colorimetric responses were evaluated in terms of sensitivity and reliability. The colorimetric sensor using bromophenol blue (BPB) and nylon sheet was found to exhibit the best performance in HCHO detection. An initial bluish green of a sensor was changed to yellow when exposed to gaseous formaldehyde. The color change was recorded using an office scanner and further analyzed in term of RGB distance for quantifying sensor's response at different HCHO(g) concentrations. It exhibited a recognizable colorimetric response even at 50 ppb, being lower than WHO's standard of 80 ppb. In addition, the sensor was found to have quite good selectivity in HCHO detection under the presence of common volatile organic compounds such as ethanol, toluene, and hexane.

Propectives of Environmental Colorimetric-Sensors (환경색센서에 관한 기술 전망)

  • Kim, Younghun;Lee, Byunghwan
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.393-399
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    • 2011
  • The electrochemical or optical sensors for environmental pollutants are developed over the past several years. Nowadays, the development of colorimetric sensing is particularly challenging since it requires no equipment at all as color changes can be detected by the naked eye. Visual detection can give immediate qualitative information and is becoming increasingly appreciated in terms of quantitative analysis. In addition, simple colorimetric-sensor have shown useful in the detection, identification, and quantification of volatile organic compounds(VOC) in gas phase or heavy metal ion in aqueous phase. In this review, we investigated the wide applications and some drawbacks of colorimetric-sensors. And thus, we try to suggest the methodologies of development approach of multi-functional and reversible colorimetric-sensor.

Analysis of Dimethylamine and Trimethylamine in Fishes by Gas Chromatography

  • Oh, Myung-Cheol;Oh, Chang-Kyung;Kim, Sung-Hong;Kim, Soo-Hyun
    • Preventive Nutrition and Food Science
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    • v.2 no.3
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    • pp.197-201
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    • 1997
  • To develop a rapid analytical method of dimethylamine(DMA) and trimethylamine(TMA) in fish, the contents of DMA and TMA in squid(Illex illecebrosus and Sepiell maindroni), cod(Gadus marcrocephalus) and plaice (Paralichthys olivaceus) by gas chromatographic (GC) and colorimetric method were determined. Recoveries for DMA in fish were 86.8~102.5% by GC and 74.2~94.5% by colorimetric method, while those for TMA were 93.0~101.1% by GC and 62.9~117.5% by colorimetric method. The contents of DMA and TMA in fish by GC were 29.7~325.3mg/kg and 145.6~356.0 mg/kg, respectively, and these by colorimetric method were 20.0~241.2mg/kg and 139.1~304.3mg/kg, respectively. The analysis of DMA and TMA in fishes by GC after the solvent extraction was simpler and faster and showed better recovery than colorimetric method.

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Change of color transfer of Photochromic lens (Photochromic 렌즈의 광변색 이동)

  • Kim, Yong-Geun;Seong, Jeong-Sub
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.1
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    • pp.59-64
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    • 2003
  • To Photochoromic lens light irradiation side darkening status and fading status photo-transmittance decrease. If remove light irradiation, get into fading state and photo-transmittance has reversibility process that get back originally in state. Get CIE $L^*a^*b^*$ relationship colorimetric using darkening in Photochoromic lens and at fading process. Photochromism's spectrophotometer that produce itself. Darkening and fading state colorimetric ($a^*-b^*$) linear be curvy, and is gradidnt of (-) value. And change lineally. The colorimetric transfer amount is Blue ${\rightarrow}$ Yellow, Red ${\rightarrow}$ Green form. Colorimetric is low $b^*$ value than darkning state in fading state, and Photochromism's coodination transfer moves on the contrary with darkning state, photochoromism relationship estimation method about photochoromic lens can use by colorimetric difference about darkening and fading.

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Studies on the Colorimetric Determination of Drugs with Phosphomolybdic Acid. I. Colorimetric Determination of Ampicillin with Phosphomolybdic acid

  • Lee, Wang-Kyu;Yoo, Byung-Tai;Kang, Gil-Jong
    • YAKHAK HOEJI
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    • v.18 no.3
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    • pp.190-196
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    • 1974
  • A new colorimetric method established for the determination of ampicillin was based on the reductions of phosphomolybdic acid by ampicillin to be resutled in a molybdenum blue which showed a mezimal absorbance at 770nm. The pH effects on a molybodenum blue solution was dependent significantly on temeprature, but the wave-length shift was not effected by the molybdenum blue.

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