• 대한치과기공학회지
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• 제43권4호
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• pp.160-167
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• 2021

Purpose: In this study, when the etching treatment method, which is a chemical surface treatment method, is applied to colored zirconia, the shear bond strength between the veneering ceramic material and colored zirconia is compared with that without surface treatment, and the fracture type is observed to evaluate the etching treatment effect of colored zirconia. Methods: Experiments were conducted after dividing the study sample into two groups, which are the zirconia control group without surface treatment using colored zirconia blocks (without etching zirconia, NZC group) and the zirconia group treated with a commercially available etching solution (etching liquid zirconia, EZC group). Results: The mean shear bond strength of the NZC group was 20.31±2.32 Mpa, and that of the EZC group was 25.95±2.34 Mpa, and the difference between these two values was statistically significant (p<0.05). Further, the surface roughness Ra value was higher in the EZC group than in the NZC group. In the fracture pattern, cohesive fractures were dominant, and adhesive fractures and cohesive fractures were mixed. Conclusion: The bond strength was significantly higher in the group treated with colored zirconia. The fracture pattern was mostly cohesive failure in the group not treated with etching and changed to mixed failure as the etching treatment progressed.

• The Journal of Advanced Prosthodontics
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• 제8권3호
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• pp.181-186
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• 2016

PURPOSE. The opacity of zirconia is an esthetic disadvantage that hinders achieving natural and shade-matched restorations. The aim of this study was to evaluate the translucency of non-colored and colored framework zirconia and monolithic zirconia. MATERIALS AND METHODS. The three groups tested were: non-colored framework zirconia, colored framework zirconia with the A3 shade according to Vita Classic Scale, and monolithic zirconia (n=5). The specimens were fabricated in the dimensions of $15{\times}12{\times}0.5mm$. A spectrophotometer was used to measure the contrast ratio, which is indicative of translucency. Three measurements were made to obtain the contrast ratios of the materials over a white background ($L^*w$) and a black background ($L^*b$). The data were analyzed using the one-way analysis of variance and Tukey HSD tests. One specimen from each group was chosen for scanning electron microscope analysis. The determined areas of the SEM images were divided by the number of grains in order to calculate the mean grain size. RESULTS. Statistically significant differences were observed among all groups (P<.05). Non-colored zirconia had the highest translucency with a contrast ratio of 0.75, while monolithic zirconia had the lowest translucency with a contrast ratio of 0.8. The mean grain sizes of the non-colored, colored, and monolithic zirconia were 233, 256, and 361 nm, respectively. CONCLUSION. The translucency of the zirconia was affected by the coloring procedure and the grain size. Although monolithic zirconia may not be the best esthetic material for the anterior region, it may serve as an alternative in the posterior region for the bilayered zirconia restorations.

• 구강회복응용과학지
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• 제23권2호
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• pp.119-130
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• 2007

Purpose: This investigation was designed to estimate the flexure strength, density, and microstructure of the colored and uncolored zirconia oxide ceramics for fixed partial denture. Material and Methods: LAVATM All Ceramic(3M-ESPE, USA), Cercon Smart Ceramic(Dentsply, USA), and Z-match Ceramic(DentAim, Korea) were used for this study. All specimen was fabricated by ASTM C1161. After preparing $25{\times}2{\times}1.5mm$ of rectangular column and sitting rectangular column on universal test machine (UTM), external supporting point distance is 20.0 mm, internal supporting point distance is 10.0 mm. Specimen was loaded with 0.2 mm/min of cross head speed until fracture and at the time of broken of specimen, measuring loading value with PC software. Results: The results were obtained as follows: 1. Flexure strength of uncolored zirconia was higher than that of colored zirconia. 2. In uncolored zirconia, flexure strength of LAVATM Ceramic was more higher than the other ceramics, and it showed statistical difference between LAVATM Ceramic and Cercon Smart Ceramic (P<0.05). 3. In colored zirconia, flexure strength of LAVATM Ceramic was more higher than the other ceramics too, but they did not show statistical difference (p>0.05). 4. In Weibull analysis, Characterastic strength was showed highest value to uncolored LAVATM Ceramic and lowest value to Z-match ceramic, and Weibull modulus(m) of uncolored zirconia was higher than that of colored zirconia. 5. In XRD analysis, all group except Z-match showed high peak of t-ZrO2 but they did not show m-ZrO2. Colored zirconia group showed lower peak of t-ZrO2 than that of uncolored zirconia group.

• The Journal of Advanced Prosthodontics
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• 제9권2호
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• pp.118-123
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• 2017

PURPOSE. To investigate the effect of non-thermal atmospheric pressure plasma (NTAPP) treatment on shear bond strength (SBS) between resin cement and colored zirconia made with metal chlorides. MATERIALS AND METHODS. 60 zirconia specimens were divided into 3 groups using coloring liquid. Each group was divided again into 2 sub-groups using plasma treatment; the experimental group was treated with plasma, and the control group was untreated. The sub-groups were: N (non-colored), C (0.1 wt% aqueous chromium chloride solution), M (0.1 wt% aqueous molybdenum chloride solution), NP (non-colored with plasma), CP (0.1 wt% aqueous chromium chloride solution with plasma), and MP (0.1 wt% aqueous molybdenum chloride solution with plasma). Composite resin cylinders were bonded to zirconia specimens with MDP-based resin cement, and SBS was measured using a universal testing machine. All data was analyzed statistically using a 2-way ANOVA test and a Tukey test. RESULTS. SBS significantly increased when specimens were treated with NTAPP regardless of coloring (P<.001). Colored zirconia containing molybdenum showed the highest value of SBS, regardless of NTAPP. The molybdenum group showed the highest SBS, whereas the chromium group showed the lowest. CONCLUSION. NTAPP may increase the SBS of colored zirconia and resin cement. The NTAPP effect on SBS is not influenced by the presence of zirconia coloring.

• 한국결정성장학회지
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• 제17권6호
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• pp.272-276
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• 2007

생산성이 우수한 스컬용융법(Skull melting method)에 의해 다양한 색의 보석용 큐빅지르코니아(Cubic Zirconia) 단결정을 성장시켰다. 큐빅지르코니아 단결정은 굴절률, 분산, 경도가 다이아몬드와 유사하고 3d 전이원소, 4f 희토류원소를 첨가하여 다양한 색개발이 가능하므로 합성보석으로 대표적이다. 첨가제로는 $Pr_6O_{11},\;TiO_2,\;MnO_2,\;Er_2O_3$를 2가지 이상적정 혼합하여 성장시켰고, 색향상과 균일성을 위해 열처리를 병행하였다. 본 연구는 천연 유색보석인 페리도트, 연수정, 적색 투어멀린의 색재현에 그 목적이 있다.

• 대한치과기공학회지
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• 제38권4호
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• pp.291-298
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• 2016

Purpose: This study was to evaluate the effect of coloring liquids on the shear bond strength between zirconia and veneering ceramic. Methods: Zirconia(15 mm in diameter, 2.5 mm in thickness; n=40) used in the experiment were divided into 5 groups depending on the coloring liquid. Each specimen were polished using a polishing machine(LaboPol-2, Struers, UK). A cylinder of veneering porcelain(6 mm in diameter, 3 mm in thickness) was fabricated and fired on zirconia surfaces. The shear bond strength was measured using a universal testing machine(Model 4302, Instron, USA). All data were analyzed statistically using a one-way ANOVA and Tukey's multiple comparisons test. After the shear bond test, fracture surfaces were examined by SEM. Results: Colored zirconia showed a higher shear bonding strength than that of uncolored zirconia except for colored zirconia immersed in Zirkonzahn coloring liquid. In particular, colored zirconia immersed in Kuwotech coloring liquid showed the highest shear bond strength. After the shear bond test, mixed failure patterns were mainly observed in the failure between zirconia and veneering ceramic. Conclusion: Coloring liquid enhanced the shear bond strength zirconia and veneering ceramic than uncolored zirconia.

• The Journal of Advanced Prosthodontics
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• 제3권3호
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• pp.166-171
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• 2011

PURPOSE. The purpose of this study is to evaluate and compare the shear bond strength of the gingiva-colored composite resin and the tooth-colored composite resin to porcelain, metal and zirconia. MATERIALS AND METHODS. Sixty cylindrical specimens were fabricated and divided into the following 6 groups (Group 1-W: tooth-colored composite bonded to porcelain, Group 1-P: gingiva-colored composite bonded to porcelain, Group 2-W: tooth-colored composite bonded to base metal, Group 2-P: gingiva-colored composite bonded to base metal, Group 3-W: tooth-colored composite bonded to zirconia, Group 3-P: gingiva-colored composite bonded to zirconia). The shear bond strength was measured with a universal testing machine after thermocycling and the failure mode was noted. All data were analyzed using the two-way analysis of variance test and the Bonferroni post-hoc test at a significance level of 0.05. RESULTS. The mean shear bond strength values in MPa were 12.39, 13.42, 8.78, 7.98, 4.64 and 3.74 for Group 1-W, 1-P, 2-W, 2-P, 3-W and 3-P, respectively. The difference between the two kinds of composite resin was not significant. The shear bond strength of Group 1 was the highest and that of Group 3 was the lowest. The differences among Group 1, 2 and 3 were all significant (P<.05). CONCLUSION. The shear bond strength of the gingiva-colored composite was not less than that of the tooth-colored composite. Thus, repairing or fabricating ceramic restorations using the gingiva-colored composite resin can be regarded as a practical method. Especially, the prognosis would be fine when applied on porcelain surfaces.

• 한국세라믹학회지
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• 제45권4호
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• pp.214-219
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• 2008

The zirconia ceramics are widely used because of their excellent mechanical properties. Recently, many researches to make a colored zirconia was achieved to satisfy the individual aesthetic requirements. In this study, the synthesis of black-color spinel-based inorganic pigments which are stable above $1400^{\circ}C$ and the fabrication of black-colored zirconia using the synthesized pigments are investigated. Inorganic pigments which have spinel structure and near black color were synthesized by a solid state reaction method using a $Fe_2O_3,\;Cr_2O_3$, CoO and NiO powder as a starting materials at $1600^{\circ}C$. Most of synthesized pigments were black colored spinel phases and single spinel phase was successfully synthesized at the composition range of $Cr_2O_3:25{\sim}35%,\;Fe_2O_3:45{\sim}55%$, CoO:20% and NiO:$6{\sim}10%$. The black-colored zirconia was fabricated at $1410^{\circ}C$ with the 5 wt% synthesized pigments and their properties were evaluated. The results showed that the strength value was more than 848 MPa, absorption rate was 0.1%, the brightness of color was $L^*:40{\sim}42$, the tone of color is $a^*:0.2{\sim}0.8$ and $b^*:-1.1{\sim}2.4$. As a result, the black-colored zirconia was suitable for a artificial jewelry or decoration zirconia goods.

• 대한치과기공학회지
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• 제36권4호
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• pp.247-253
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• 2014

Purpose: The aim of this study was to evaluate the effect of colored zirconia with different coloring liquids. Methods: Total 30 specimens were prepared. Specimens were classified into 6 groups: IPS e.max Ceram(P), Uncolored zirconia(C), VITA In-Ceram$^{(R)}$2000 YZ LL1(L), Zirkonzahn coloring liquid(Z), Wieland coloring liquid(W), and Kuwotech coloring liquid(K). Four different types of zirconia coloring liquid, VITA In-Ceram$^{(R)}$ 2000 YZ LL1(VITA Zahnfabrik, Germany), Zirkonzahn coloring liquid(Zirkonzahn, Italy), Wieland coloring liquid(Wieland, Germany), Kuwotech coloring liquid(Kuwotech, Korea) were used to fabricate colored zirconia by using infiltrating method and then completely sintered. The color of the all specimens was measured using the spectrophotometer(CM-2600d, Konica Minolta, Japan) and expressed in terms of the 3-coordinated values(CIE $L^*a^*b^*$). Color differences were calculated using the equation $${\Delta}E^*=[({\Delta}L^*)^2+({\Delta}a^*)^2+({\Delta}b^*)^2]^{1/2}$$. Results: $L^*a^*b^*$ values of the colored zirconia were affected by the coloring liquids. The uncolored zirconia(C) group showed the highest $L^*$ value and zirkonzahn coloring liquid(Z) group showed the lowest $L^*$ value. Zirkonzahn coloring liquid(Z) showed the highest $a^*$ value and VITA In-Ceram 2000 YZ LL1(L) group showed the highest $b^*$ value. Generally, the color difference(${\Delta}E^*$) in all groups showed higher than 3.7 except between IPS e.max Ceram(P) and wieland coloring liquid(W) group. Conclusion: Within the limitations of this study, various coloring liquids influenced the $L^*$, $a^*$, and $b^*$ values of colored zirconia. IPS e.max Ceram(P) and wieland coloring liquid(W) group did not show clinically perceiving color difference.

• The Journal of Advanced Prosthodontics
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• 제3권4호
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• pp.221-228
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• 2011

PURPOSE. Veneering porcelain might be delaminated from underlying zirconia-based ceramics. The aim of this study was the evaluation of the effect of different surface treatments and type of zirconia (white or colored) on shear bond strength (SBS) of zirconia core and its veneering porcelain. MATERIALS AND METHODS. Eighty zirconia disks (40 white and 40 colored; 10 mm in diameter and 4 mm thick) were treated with three different mechanical surface conditioning methods (Sandblasting with $110{\mu}m$ $Al_2O_3$ particle, grinding, sandblasting and liner application). One group had received no treatment. These disks were veneered with 3 mm thick and 5 mm diameter Cercon Ceram Kiss porcelain and SBS test was conducted (cross-head speed = 1 mm/min). Two and one way ANOVA, Tukey's HSD Past hoc, and T- test were selected to analyzed the data (${\alpha}=0.05$). RESULTS. In this study, the factor of different types of zirconia ceramics (P=.462) had no significant effect on SBS, but the factors of different surface modification techniques (P=.005) and interaction effect (P=.018) had a significant effect on SBS. Within colored zirconia group, there were no significant differences in mean SBS among the four surface treatment subgroups (P=0.183). Within white zirconia group, "Ground group" exhibited a significantly lower SBS value than "as milled" or control (P=0.001) and liner (P=.05) groups. CONCLUSION. Type of zirconia did not have any effect on bond strength between zirconia core and veneer ceramic. Surface treatment had different effects on the SBS of the different zirconia types and grinding dramatically decreased the SBS of white zirconia- porcelain.