• Title/Summary/Keyword: Color degradation

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Development of Natural Color of Bleached Hanji Dyed with Rice Straw Extractives (볏짚 추출물을 이용한 한지의 천연색 발현)

  • 최태호;이연숙
    • Journal of Korea Foresty Energy
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    • v.22 no.3
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    • pp.43-48
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    • 2003
  • Black liquor staining for the development of natural color of bleached Hanji caused problems of discoloration and degradation. This study was carried out not only to complement these problems but also to develop natural dyeing method that was similar to the color of unbleached Hanji, through the dyeing of rice straw extractives. The dyeing properties of Hanji were influenced more by dyestuffs extraction method than extraction and dyeing time. Dyeing ability of hot water extractives was superior to cold-water extractives. Without the relation to the time of extraction and dyeing, the color of Hanji dyeing hot water extractives were similar to the control, and the color of Hanji dyed for 45 min with hot water extractives that extracted for 120 min, were almost same as the control. As natural dyestuffs, hot water extractives of rice straw showed that excellent dyeing ability for the development of various natural colors similar to unbleached Hanjis.

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Color and Chlorophyll of Blanched Vegetable Soybean by NaCl (열처리 시 소금첨가에 의한 풋콩의 색과 Chlorophyll 함량 변화)

  • Song, Jae-Yeun;Kim, Chul-Jai;An, Gil-Hwan
    • Korean Journal of Agricultural Science
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    • v.30 no.2
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    • pp.148-153
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    • 2003
  • Vegetable soybeans were blanched at 80, 90 and $100^{\circ}C$ for 30, 20 and 10min, respectively. NaCl(3%) was also used to measure the protective effect of soybean color. The color of vegetable soybeans was measured by colorimeter, -a value (greenness) was highest at $100^{\circ}C$-10min. However, the chlorophyll contents was highest at $80^{\circ}C$-30min. NaCl (3%) decreased the loss of chlorophyll in blanched vegetable soybeans. The reaction rate constant for the thermal degradation of chlorophyll and greenness doubled per $10^{\circ}C$. The activation energy chlorophyll a of pod for thermal degradation of chlorophyll a in pods were 138.02 (unsalted), 146.63 (salted) Kcal/mol, respectively.

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Degradation of Lead-based Pigments by Atmospheric Environment (납계열 안료의 대기환경에 따른 열화특성)

  • Park, Ju Hyun;Lee, Sun Myung;Kim, Myoung Nam
    • Economic and Environmental Geology
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    • v.55 no.3
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    • pp.281-293
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    • 2022
  • We examined degradation characteristics of lead based pigments(white lead, Red lead, Litharge) according to atmospheric environmet condition, for example atmospheric gas(CO2, NO2) and soluble salt. Painted samples not changed material compositions but were occured the color change(𝚫E 4~31) after exposed UV irradiation. All sample were not affected by CO2 gas not only color but chemical composition. However, samples were remakably changed color exposed NO2 gas and it was formed secondary product like as lead nitrate. Such as red lead and white lead samples' color difference were 𝚫E 2 and 𝚫 10 respectively and became dark, along with litharge became bright and color difference was 𝚫E 5 after react with NO2 gas. It confirm that NO2 was influential factor than CO2 in the case of same concentration. Furthermore salt spray test was taken to figure out soluble salt influence in fine dust. The result showed noticeable color change and secondary product was formed on samples' surface. The glue film peeled off or hole, and color changed around the secondary products. After salt spray, XRD pattern showed decrease peak intensity and lower crystalinity. As a result of salt spray test, white lead was formed new product litharge and litharge was formed litharge and minium. According to the results, influential atmospheric factors for conservation of paint pigments were UV, NO2, soluble salt, and litharge was most weakness throughout lead base pigments.

Color and Carotenoid Changes During Storage of Dried Red Pepper (건조(乾燥) 고추 저장(貯藏) 중(中)의 변색(變色)에 관(關)한 연구(硏究))

  • Kim, Dong-Youn;Rhee, Chong-Ouk
    • Korean Journal of Food Science and Technology
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    • v.12 no.1
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    • pp.53-58
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    • 1980
  • The effects of water activity, oxygen, light and storage temperature on the color degradation of dried red pepper were investigated during storage. Some packing materials were used for improving the storage life of red pepper by minimizing those factors. The results obtained were summarized as follows: 1. The critical water activity to the capsanthin of red pepper was 0.75. 2. Color degradation of dried red pepper was the most severe by U.V. light among 100 watt infra-red lamp, 15 watt U.V. lamp and 200 watt glow lamp. 3. Effect of light was not significant in the presence of nitrogen, Main factor of color degradation of red pepper in storage appeared spontaneous oxidation by the existence of oxygen. 4. The capsanthin content and the lightness as hunter value in powder type storage of red pepper was higher than that in whole pod type during 3 month's storage. 5. The air and damp-proof packing materials showed better results than polyethylene film packing in capsanthin content and lightness during 3 month's storage.

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Chemical and Morphological Change and Discoloration of Cedar Wood Stored Indoor (실내 보관 삼나무 목재의 재색 및 화학적·현미경적 변화 특성)

  • Lee, Kwang Ho;Cha, Mi Young;Chung, Woo Yang;Bae, Hyeun-Jong;Kim, Yoon Soo
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.6
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    • pp.566-577
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    • 2009
  • The modification of wood color occurs rapidly during the service period at indoor. It is crucial to investigate the characteristics of color change, chemical and microscopical modification of wood at indoor. Wood products made of Japanese cedar at different years were used for this work. The tests were performed in order to evaluate the degree of color change of wood surface, breakpoint of brightness from surface to inside of wood, chemical analysis with FT-IR, and microscopical characteristics using the LM and TEM. Surface color of cedar wood stored indoor were rapidly changed at early stage, particularly ${\Delta}a$ (yellow), and ${\Delta}b$ (red) values were steeply decreased for one year old indoor wood, ${\Delta}L$ (white) value was dropped until 5 years old indoor wood compared with control sample. Decrease of peaks related to polysaccharide and lignin was noticed, especially, lignin was severely degraded. Although degradation of cell wall limited only to surface layers of indoor wood, degradation pattern of indoor wood showed similar degradation pattern to natural weathering of wood during outdoor weathering or wood behavior under artificial UV irradiation.

Degradation Characteristics of Ligninsulfonate by Laccase and Mn-peroxidase (Laccase와 Mn-peroxidase에 의한 Ligninsulfonate의 분해 특성)

  • Bae, Hyeun-Jong;Kim, Yoon-Soo;Mun, Sung-Phil
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.4
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    • pp.27-32
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    • 1995
  • To understand whether ligninolytic enzyme catalyze polymerization or depolymerization of the high molecular weight (HMW) lignin, the action of laccase and Mn-peroxidase (MnP) towards commercial ligninsulfonates (LS) was examined in various conditions of pH and cosubstrates. Polymerization occurred when LS was incubated with laccase at pH 6.0. In contrast, the high molecular weight portions were significant1y reduced at pH 4.5, especially when glucose was added. When LS was treated with MnP at pH 4.5, compounds of low molecular weight were produced. In particular, when cellobiose was added to Mn-P reaction mixture, the breakdown of LS was observed. In conclusion, degradation of LS by laccase and MnP occurred primarily at pH 4.5 where-as polymerization of LS was dominant at pH 6.0. Color index, however, was not greatly changed in the degradation mixtures of LS.

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Red Pigment of the Korean Cockcomb Flower: Color Stability of the Red Pigment (한국산 맨드래미 꽃의 적색 색소 : 적색 색소의 식품학적 안정성)

  • Lee, S.Y.;Cho, S.J.;Lee, K.A.;Byun, P.H.;Byun, S.M.
    • Korean Journal of Food Science and Technology
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    • v.21 no.3
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    • pp.446-452
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    • 1989
  • The pigment of the Korean cockscomb flower, a betacyanin, was evaluated for its stability in terms of temperature, pH, and its behavior upon exposure to water, light, and air. The pigment was the most stable at pH 4.0, and its activation energy (Ea) for degradation was shown to be 17.55Kcal/mol. In general, sugars protected against color degradation at the concentration of 0.1M. Degradation of this pigment in the presence of food constituents, such as organic acids , metal ions, or antioxidants, at the concentrations normally present in food preparations, can be kept to a minimum by selective adjustment of conditions. This pigment, therefore, has potential value as a food colorant under selected conditions.

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Optimization and Characteristics of Removal Condition of Livestock Wastewater Using a Photocatalytic Process (광촉매공정 적용시 축산폐수의 처리특성 및 최적화)

  • Park, Jae-Hong
    • Clean Technology
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    • v.13 no.3
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    • pp.222-227
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    • 2007
  • The photocatalytic degradation of livestock wastewater has been investigated over $TiO_2$ photocatalysts irradiated with a ultraviolet (UV) light. The effect of operational parameters, i.e., distance, reaction area, concentration of suspended solids(SS), and column diameter on the degradation of livestock wastewater has been performed in lab-scale. The optimal conditions for livestock wastewater were determined: distance was 3 cm (less than 7 cm), reaction area was $3.6\;m^2$, SS concentration was 40 mg/L (less than 300 mg/L) and column diameter was 5 mm (less than 10 mm). Under the optimal conditions, COD, color and coliform removal efficiencies were approximately 49%, 53% and 100%, respectively. Non-biodegradable COD removal efficiency increased with 57% using by photocatalysis process. Therefore, it is shown that photocatalysis has an effect on degradation of non-biodegradable organic matter.

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Color Interpolation Algorithm for Pixel Resolution Modus of Image Sensor (영상센서의 출력 해상도 모드를 고려한 색상 보간 알고리즘)

  • Kim, Bu-Gong;Kim, Moon-Cheol
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.9
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    • pp.129-138
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    • 2014
  • Various interpolations for digital imaging devices with a single image sensor have proposed. However, conventional methods did not consider the resolution modus of image sensor using periodic sampling. Therefore, the resulting images have problems such as quality degradation and color artifacts(color moire, zipper). In this paper, we propose a color interpolation algorithm for pixel resolution modus of image sensor. The proposed algorithm consisted of an initial step to compensate edge prediction effectively and refinement step using minimum directions for pixel resolution modus. To analyze a result of the proposed algorithm with conventional methods, we evaluated subjectively using images quality comparison and objectively using PSNR(Peak Signal to Noise Ratio). Experimental results showed that the proposed algorithm was more successful in eliminating the color artifacts than conventional methods judged by both objective and subjective criteria.

Investigation of Degradation Mechanism of Rabeprazole with Solid State Pharmaceutical Excipients

  • Ren, Shan;Tran, Thao Truong-Dinh;Tran, Phuong Ha-Lien;Rhee, Yun-Seok;Lee, Beom-Jin
    • Journal of Pharmaceutical Investigation
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    • v.40 no.6
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    • pp.367-372
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    • 2010
  • Rabeprazole sodium (RPN) is known to be very unstable at acidic condition or some acidic pharmaceutical excipients such as acrylic acid polymer (carbomer 934) with carboxylic acids. Thus, degradation mechanism of binary blends of rabeprazole with pharmaceutical excipients in a solid state without using solvents at three different ratios (3:1, 1:1 and 1:3) was investigated using Fourier transform infrad (FTIR) spectroscopy. Alkalizer (MgO), neutral hydroxypropymethylcellulose (HPMC 4000) were also tested for comparison. The binary blends were stored under accelerated conditions ($40^{\circ}C$/75% relative humidity) for two weeks. The concentration of thioether rabeprazole from the binary blends with acidic carbomer 934 increased as the rabeprazole concentration decreased. In addition, the degradation half-life of rabeprazole as well as the relative peak area ratios obtained from FTIR spectra of S=O stretching at $1094.1\;cm^{-1}$ decreased consistently as the fraction of carbomer 934 increased due to its sensitivity between the basic benzimidazole nitrogen and carboxylic acid group of carbomer 934. The physical appearance also turned into strong brown color in the presence of carbomer 934. In contrast, there were no significant changes in the degradation kinetics of rabeprazole with MgO and HPMC 4000 in a solid state. This present study demonstrated that the solid-state compatibility test with the aid of HPLC chromatographic and FTIR spectral analyses could offer a valuable methodology to select suitable pharmaceutical excipients and to elucidate the degradation mechanism of RPN for drug formulations at the early formulation stages.