• Bulletin of the Korean Chemical Society
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• v.27 no.4
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• pp.495-502
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• 2006

Intramolecular energy flow and C-$H_{methyl}$ and C-$H_{ring}$ bond dissociations in vibrationally excited toluene in the collision with HF have been studied by use of classical trajectory procedures. The energy lost by the vibrationally excited toluene upon collision is not large and it increases slowly with increasing total vibrational energy content between 20,000 and 45,000 $cm ^{-1}$. Above the energy content of 45,000 $cm ^{-1}$, however, energy loss decreases. Furthermore, in the highly excited toluene, toluene gains energy from incident HF. The temperature dependence of energy loss is negligible between 200 and 400 K. Energy transfer to or from the excited methyl C-H bond occurs in strong collisions with HF transferring relatively large amount of its translational energy (>> $k_BT$) in a single step, whereas energy transfer to the ring C-H bond occurs in a series of small steps. When the total energy content $E_T$ of toluene is sufficiently high, either C-H bond can dissociate. The C-$H_{methyl}$ dissociation probability is higher than the C-$H_{ring}$ dissociation probability. The dissociation of the ring C-H bond is not the result of the intermolecular energy flow from the direct collision between the ring C-H and HF but the intramolecular flow of energy from the methyl group to the ring C-H stretch. The C-$H_{ring}$${\cdot}{\cdot}{\cdot}$HF interaction is not important in transferring energy and in turn bond dissociation.

• Bulletin of the Korean Chemical Society
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• v.27 no.12
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• pp.2002-2010
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• 2006

This study examined the quenching of ofloxacin (OFL) and flumequine (FLU) fluorescence by $Cuj^{2+}$, $Ni^{2+}$, $Co^{2+}$ and $Mn^{2+}$ in an aqueous solution. The change in the fluorescence intensity and lifetime was measured at various temperatures as a function of the quencher concentration. According to the Stern-Volmer plots, the fluorescence emission was quenched by both collisions (dynamic quenching) and complex formation (static quenching) with the same quencher but the effect of static quenching was larger than that of dynamic quenching. Large static and dynamic quenching constants for both OFL and FLU support significant ion-dipole and orbital-orbital interactions between fluorophore and quencher. For both molecules, the static and dynamic quenching constants by $Cu^{2+}$ were the largest among all the metal quenchers examined in this study. In addition, both the static and dynamic quenching mechanisms by $Cu^{2+}$ were somewhat different from the quenching caused by other metals. Between $Ni^{2+}$ and FLU, a different form of chemical interaction was observed compared with the interaction by other metals. The change in the absorption spectra as a result of the addition of a quencher provided information on static quenching. With all these metals, the static quenching constant of FLU was larger than those of OFL. The fluorescence of OFL was quite insensitive to both the dynamic and static quenching compared with FLU. This property of OFL can be explained by the twisted intramolecular charge transfer in the excited state.

• Journal of Ocean Engineering and Technology
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• v.30 no.6
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• pp.474-483
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• 2016

Accidental events such as collisions, groundings, and hydrocarbon explosions in marine structures can cause catastrophic damage. Thus, it is extremely important to predict the extent of such damage, which determines the total amount of oil spills and the residual hull girder strength. Punching fracture tests were conducted by Choung (2009b), where various sizes of indenters and circular unstiffened steel plates with different thicknesses were used to quasi-statically realize damage extents. A three-dimensional fracture strain surface was developed based on a reference (Choung et al., 2015b), where the average stress triaxiality and average normalized Lode angle were used as the parameters governing the fracture of ductile steels. In this study, new numerical analyses were performed using very fine axisymmetric elements in combination with an Abaqus user-subroutine to implement the three-dimensional fracture strain surface. Conventional numerical analyses were also conducted for the tests to identify the best fit fracture strain values by changing the fracture strains. Based on the phenomenon of the average normalized Lode angle starting out positive and then becoming slightly negative, it was inferred that the shear stress primarily dominates in determining the fractures locations, with a partial contribution from the compressive stress. It should be stated that the three-dimensional fracture surface effectively predicted at least the shear stress-dominant fracture behavior of a mild steel.

• Journal of the Korean Institute of Intelligent Systems
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• v.27 no.2
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• pp.113-118
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• 2017

Various studies on the method of ship collision risk assessment for alarm have been reported constantly, and the result of the studies is applied to navigation devices. However, it is known that navigators ignore or turn off frequent alarms from the devices of predicting collision risk, because they may avoid collisions in the most of situations. In oder to make the prediction of ship collision risk more useful, it is necessary to consider the customary actions of ship collision avoidance. This paper proposes a system of analyzing collision avoidance measures of ships according to the types of encounter and managing the avoidance history of each ship. The core module of the system is designed as a neuro-fuzzy based inference system, and the test of the module validates the proposed system.

• Journal of IKEEE
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• v.24 no.1
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• pp.147-153
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• 2020

Conventional lane detection algorithms have problems in that the detection rate is lowered in road environments having a large change in curvature and illumination. The probabilistic Hough transform method has low lane detection rate since it exploits edges and restrictive angles. On the other hand, the method using a sliding window can detect a curved lane as the lane is detected by dividing the image into windows. However, the detection rate of this method is affected by road slopes because it uses affine transformation. In order to detect lanes robustly and avoid obstacles, we propose driving assist system using semantic segmentation based on deep learning. The architecture for segmentation is SegNet based on VGG-16. The semantic image segmentation feature can be used to calculate safety space and predict collisions so that we control a vehicle using adaptive-MPC to avoid objects and keep lanes. Simulation results with CARLA show that the proposed algorithm detects lanes robustly and avoids unknown obstacles in front of vehicle.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2018.11a
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• pp.12-13
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• 2018

For navigation safety, navigators have to be familiar with maneuverabilities. When a vessel encounters a danger of collisions and stranding, maneuverability is essential for the safety of ship. It is composed of turning, course change, speed change, etc. In the latter part, maneuverabilities and motion of Training Ship HANBADA are provided by full-scale measurement in the $10^{\circ}/10^{\circ}$ Zig-Zag Test, $20^{\circ}/20^{\circ}$ Zig-Zag Test and Turning Circle Test(Port and Starboard). It aims to provide information on maneuverabilities and motion of Training Ship HANBADA so that the navigators can take proper action to avoid.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.17 no.2
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• pp.99-113
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• 1992

In general, TDMA and FDMA have been used for multiple access communication methods. Recently. However, ALOHA and CSMA protocols came to exist as new schemes for VSAT data networks and LANs, respectively. These schemes are proven to be effective for packet switched communication systems that has bursty traffic but packet collisions. In this paper we analyze capture statistics arising from fading channels in packet radio communication systems in the context of ALOHA protocol. We derive general results of the exact form of capture probabilities and present numerical data for wide range of fading parameters. Since the capture probabilities are found to approach zero when the number of transmitted signals become larger, we are able to determine the achievable channel throughput by a least squares fitting of an exponential-type function to the probabilities.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.37 no.1C
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• pp.54-62
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• 2012

A Wi-Fi mesh network providing multi-hop wireless connections based on IEEE 802.11 PHY/MAC technology has recently received a significant attention as a network infrastructure that interconnects RFID systems and wireless sensor networks (WSNs). However, the current IEEE 802.11 contention-based MAC protocol cannot fully utilize the network capacity due to eithor frame collisions or unused network resources. In this paper, we propose a novel multi-channel scheduling MAC (MCS-MAC) protocol for Wi-Fi mesh networks. Under the secondary interference model of Wi-Fi mesh networks, the MCS-MAC protocol can maximize the network throughput via activation of collision-free links that has a maximal link weight. Through the simulations, we show that the throughput of the MCS-MAC protocol is at least three times higher than that of existing MAC protocols in Wi-Fi mesh networks.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.33 no.3B
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• pp.135-143
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• 2008

In this paper, we propose a QoS guaranteed and energy-efficient transmission scheme for Wireless Personal Area Networks (WPANs), which operate in conjunction with contention-based access protocols such as CSMA/CA. Energy consumption is one of the most important issues in WPAN systems, because WPAN devices are often required to operate under limited battery capacity. Furthermore, if the WPAN adopts a contention-based medium access protocol, the energy consumption problem becomes even more critical due to the collisions caused by independent channel access trials. Therefore, in this paper, we propose an algorithm that selects the optimum fragment size, modulation level, and transmission power, in order to minimize the energy consumption and guaranteethe QoS (Quality of Service) requirements, simultaneously. Our simulation results show that the proposed algorithm has better performance than the previous ones.

• Journal of Digital Contents Society
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• v.14 no.1
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• pp.25-33
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• 2013

P2P(Peer-to-Peer) architecture can reduce the network bandwidth and resource on the server since peers exchange data chunks with each other, while server-client architecture causes a lot of traffic on the server. Peers receive a data more reliably when the number of participating peer increases. Currently, P2P traffic has accounted for about 65% of the world's Internet traffic and diverse P2P streaming services have launched combining to video streaming technology. However, the requirements and data chunk delivery algorithms for mobile P2P streaming service should be investigated, since the existing P2P technologies have been developed and designed for the wired network. In particular, the bandwidth fluctuation caused by user mobility, wireless packet collisions, and packet losses brings about different problems on the mobile P2P streaming service compared to existing P2P streaming service. In this paper, we analyzed the problem of mobile P2P streaming services in the 802.11n wireless LAN environment through experiments.