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Statistical Thermodynamical Properties and Adsorption Characteristics of Heavy Water (중수의 열역학적 성질과 흡착특성)

  • Chang-Hyun Jho;Hyungsuk Park;Seihun Chang
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.285-293
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    • 1971
  • The statistical thermodynamical properties of heavy water are calculated according to the transient state theory of significant liquid structure. The calculated values are shown to be in good agreement with the observed ones. The grand canonical ensemble partition function for the adsorbed phase of heavy water on graphite surface is derived using the theory. The adsorption isotherm, the surface pressure, the molar entropy and the molar internal energy for the adsorbed phase and then the molar heat of adsorption are calculated according to the derived partition function. The thermodynamic properties of the adsorbed water are also calculated and the results are compared with those of heavy water and discussed in view of the experimentally observed phenomena.

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Calculation of Force Constants of Hydrogen Molecule by Use of One Center Function (일점전개함수에 의한 수소분자의 Force Constants 의 계산)

  • Kim, Ho-Jing;Choi, Ung-In;Choi, Suk-Jin
    • Journal of the Korean Chemical Society
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    • v.14 no.1
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    • pp.133-136
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    • 1970
  • The quadratic and cubic force constants of hydrogen molecule are calculated by use of the one center function of Bishop. The master formula on which the computation is based was suggested by the previous work of one of the present authors. The results are in good agreement with the experimental values.

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CONTROLLABILITY OF IMPULSIVE NEUTRAL STOCHASTIC FUNCTIONAL INTEGRODIFFERENTIAL SYSTEM VIA RESOLVENT OPERATOR

  • K. RAMKUMAR;K. RAVIKUMAR;DIMPLEKUMAR CHALISHAJAR;A. ANGURAJ;MAMADOU ABDOUL DIOP
    • Journal of Applied and Pure Mathematics
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    • v.5 no.1_2
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    • pp.23-40
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    • 2023
  • This paper is concerned by the controllability results of impulsive neutral stochastic functional integrodifferential equations (INSFIDEs) driven by fractional Brownian motion with infinite delay in a real separable Hilbert space. The controllability results are obtained using stochastic analysis, Krasnoselkii fixed point method and the theory of resolvent operator in the sense of Grimmer. A practical example is provided to illustrate the viability of the abstract result of this work.

Computer Simulation of Ink Transfer in the Different Printing Speed and Ink Viscosity in the Screen Printing (스크린 인쇄에서 인쇄 속도와 잉크 점도에 따른 잉크 전이 시뮬레이션에 관한 연구)

  • Choi, Song-Ah;Youn, Jong-Tae;Mok, Jee-Soo;Koo, Chul-Whoi
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.1
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    • pp.75-83
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    • 2011
  • As screen printing is changed by automation recently, could print more exactly. However, must suffer great many trial and error to have still gotten perfect result. By the way, at this step, fair time and money should be invested. Therefore, if search for optimum condition in early time visualizing screen printing process using simulator program before progress printing, is judged that may be correct and gets printing result efficiently. In this paper, searched optimum printing speed and ink viscosity using FLOW-3D program. Also, the result could confirm truth that is agreeing almost with experiment contents. Through this, is thought that may expect extension of screen printing wide application that vivify advantage of screen print if use simulation program.

COMPLETE CONTROLLABILITY OF SEMILINEAR STOCHASTIC INTEGRO-DIFFERENTIAL EQUATIONS WITH INFINITE DELAY AND POISSON JUMPS

  • D.N., CHALISHAJAR;A., ANGURAJ;K., RAVIKUMAR;K., MALAR
    • Journal of Applied and Pure Mathematics
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    • v.4 no.5_6
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    • pp.299-315
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    • 2022
  • This manuscript deals with the exact (complete) controllability of semilinear stochastic differential equations with infinite delay and Poisson jumps utilizing some basic and readily verified conditions. The results are obtained by using fixed-point approach and by using advance phase space definition for infinite delay part. We have used the axiomatic definition of the phase space in terms of stochastic process to consider the time delay of the system. An infinite delay along with the Poisson jump is the new investigation for the given stochastic system. An example is given to illustrate the effectiveness of the results.

Reaction of Nitrous Acid on 5-Aminopyrimidine Derivatives [Ⅱ] Isobarbituric Acid, A New Method of Synthesis (5-Aminopyrimidine에 대한 아질산의 작용 [Ⅱ] Isobarbituric acid의 새 합성법)

  • Chang Sae Hee;Kim In Kyu;Hahn Bo-Sup
    • Journal of the Korean Chemical Society
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    • v.9 no.2
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    • pp.75-77
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    • 1965
  • A new method of synthesis of isobarbituric acid is described. With this method, isobarbituric acid can be synthesized both directly and conveniently. Yields of isobarbituric acid are up to 75 per cent.

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Synthesis, Spectroscopic Studies of Binuclear Ruthenium(II) Carbonyl Thiosemicarba-zone Complexes Containing PPh3/AsPh3 as Co-ligands: DNA Binding/Cleavage

  • Sampath, K.;Sathiyaraj, S.;Jayabalakrishnan, C.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.367-373
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    • 2013
  • The ruthenium(II) ferrocenyl heterocyclic thiosemicarbazone complexes of the type $[RuCl(CO)(EPh_3)]_2L$ (where E = P/As; L = binucleating monobasic tridendate thiosemicarbazone ligand) have been investigated. Strutural features were determined by analytical and spectral techniques. Binding of these complexes with CT-DNA by absorption spectral study indicates that the ruthenium(II) complexes form adducts with DNA and has intrinsic binding constant in the range of $3.3{\times}10^4-1.2{\times}10^5M^{-1}$. The complexes exhibit a remarkable DNA cleavage activity with CT-DNA in the presence of hydrogen oxide and the cleavage activity depends on dosage.

Reaction of Nitrous Acid on 5-Aminopyrimidines (I) Sandmeyer Reaction of Diazotizated 5-Aminouracil (5-Aminopyrimidine 유도체에 대한 아질산의 작용 [I] Diazotizated 5-Aminouracil에 대한 Sandmeyer 반응)

  • Chang, Sae-Hee;Kim, In-Kyu;Park, Do-Soon;Hahn, Bo-Sup
    • Journal of the Korean Chemical Society
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    • v.9 no.1
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    • pp.29-32
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    • 1965
  • A new conventional method for the preparation of 5-iodo-, chloro-and bromouracil by Sandmeyer reaction was described. According to this procedure, 5-halouracils have been prepared in high yields(up to 75%) without any difficulties to remove of impurities. No appreciable competing reaction was observed.

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Studies on the Carotenoid Pigment in Abdominal Skin of Bombina Orientalis (Ⅲ). Occurrence of 3-Hydroxy-canthaxanthin in the Abdominal Skin of Bombina Orientalis (무당개구리의 복피 Carotenoid 색소에 관한 연구 (제3보). 3-Hydroxy-canthaxanthin의 분리 및 확인)

  • Chang Sae Hee;Chong Ui Chun;Choi Il Young
    • Journal of the Korean Chemical Society
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    • v.19 no.1
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    • pp.34-37
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    • 1975
  • 3-Hydroxy-canthaxanthin, reddish purple needle shaped crystals, has been isolated from the abdominal skin of Bombina Orientalis. Its structure has been established by visible and IR spectral characteristics, chromatographic behaviors, and physical and chemical properties.

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Reactions of trichloroethylideneacetophenone with hydrazines (I) synthesis of pyrazoline and pyridazinone derivatives (Trichloroethylideneacetophenone과 hydrazine들의 반응 (I) pyrazoline 및 pyridazinone 유도체의 합성)

  • Lee, Youn-Young;Lee, Woo-Young;Chang, Sae-Hee
    • Journal of the Korean Chemical Society
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    • v.14 no.1
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    • pp.61-64
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    • 1970
  • 3-Phenyl-5-trichloromethyl-2-pyrazoline was synthesized from the reaction of trichloroethylideneacetophenone with hydrazine hydrate. Pyridazinone derivatives were synthesized from the reaction of trichloroethylideneacetophenone with phenylhydrazine or substituted phenylhydrazines.

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