• 제목/요약/키워드: Coking

검색결과 64건 처리시간 0.021초

디젤 엔진의 인젝터 설계 변수가 노즐 코킹에 미치는 영향 분석 (Effects of Injector Design Parameter on Nozzle Coking in Diesel Engines)

  • 김용래;송한호
    • 한국분무공학회지
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    • 제17권3호
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    • pp.140-145
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    • 2012
  • Recent common-rail injector of a diesel engine needs more smaller nozzle hole to meet the stringent emission regulation. But, small nozzle hole diameter can cause nozzle coking which is occurred due to the deposits of post-combustion products. Nozzle coking has a negative effect on the performance of fuel injector because it obstructs the fuel flow inside a nozzle hole. In this study DFSS (Design for six sigma) method was applied to find the effect of nozzle design parameter on nozzle coking. Total 9 injector samples were chosen and tested at diesel engine. The results show that nozzle hole diameter and K-factor have more effect on nozzle coking than A-mass and hole length. Large hole diameter and A-mass, small hole length and K-factor give more positive performance on nozzle coking in these experimental conditions. But, a performance about nozzle coking and exhaust gas emission shows the opposite tendency. Further study is needed to find the relation between nozzle coking and emission characteristic for the optimization of injector nozzle design.

코킹 공정(工程)을 이용한 오일샌드 역청(瀝靑)의 열화학(熱化學)적 전환(轉換) (Thermochemical Conversion of Oil sand Bitumen in Delayed Coking Reactor)

  • 이시훈;윤상준;이재구;김재호
    • 자원리싸이클링
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    • 제17권3호
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    • pp.35-41
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    • 2008
  • 석유를 대체할 수 있는 자원 중의 하나인 오일샌드 역청의 열화학적 전환을 통해 생산된 연료유 특성을 열천칭 분석기와 중질유들의 전환 공정에 사용되는 딜레이드 코킹 반응기(600ml)를 이용하여 분석하였다. 동일한 $50^{\circ}C/min$의 승온 속도로 최종 코킹 온도를 $400{\sim}550^{\circ}C$까지 변화시킨 결과, 최종 코킹 온도가 증가할수록 코킹이 완료되는 시간과 전환률이 증가하였다. 그러나 $450^{\circ}C$이상의 온도에서는 미비하게 증가하여 코킹 운전이 적어도 $450^{\circ}C$ 이상이 되어야 함을 알 수 있었다. 딜레이드 코킹 반응기의 최대 액체 수율은 $475^{\circ}C$의 조건으로 나타났으며 코킹에 의해 생성되는 오일의 API, SIMDAS분석을 통해 경질화가 진행되어 일반적인 디젤과 비슷한 연료 특성을 가짐을 확인하였다.

코크스 공정에서의 열유동 현상 모델링 (Modeling of Coking Process in a Coke Oven)

  • 양광혁;양원;최상민
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1184-1189
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    • 2004
  • Coking process is the thermal decomposition of bituminous coal with final temperature of about $900^{\circ}C$ Because coke plays important roles in ironmaking process in a blast furnace it's essential for developing modeling of coke oven. In this study, An unsteady 2-dimesional model is proposed to simulate coking process in a coke oven. In this model, gas and solid phase are assumed homogeneous continnum and solid bed is assumed as porous media . The model contains governing equations for the solid phase and the gas phase. Complicated phenomena such as swelling, softening, resolidification and shrinkage are neglected and mass loss by drying and devolatilization is reflected by generation of internal pores. Drying, devolatilization, heat transfer and generation of internal pores are also reflected in source terms. Calulated results are compared with experimental data

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Preparation of needle coke from petroleum by-products

  • Halim, Humala Paulus;Im, Ji Sun;Lee, Chul Wee
    • Carbon letters
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    • 제14권3호
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    • pp.152-161
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    • 2013
  • Needle coke is an important material for graphite electrodes. Delayed coking is used to produce needle coke. Producing good quality needle coke is not simple because it is a multi-parameter controlled process. Apart from that, it is important to understand the mechanism responsible for the delayed coking process, which involves mesophase formation and uniaxial rearrangement. Temperature and pressure need to be optimized for the different substances in every feedstock. Saturate hydrocarbon, aromatic, resin and asphaltene compounds are the main components in the delayed coking process for a low Coefficient Thermal Expansion value. In addition, heteroatoms, such as sulphur, oxygen, nitrogen and metal impurities, must be considered for a better graphitization process that prevents the puffing effect and produces better mesophase formation.

독일 산업·기술문화재 한자 코크스 제조소 재생사례 분석 (Analysis on the Characteristics of the Precedents for Industrial/Technological Cultural Properties of the Hansa Coking Plant)

  • 김홍기;박창호
    • 한국가구학회지
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    • 제27권1호
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    • pp.59-68
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    • 2016
  • The Industrial/Technological Cultural Properties are being protected, the rest facing with demolition and damages. In order to better cope with such situation, Korea has officially introduced the Registered Cultural Properties System since 2001 and began acknowledging the historical values of industrial buildings as modern cultural properties. In the Nordrhein-Westfalen, Germany, there are approximately 3,500 industrial buildings under the cultural asset protection and management not only in the Ruhr-region but also state-wide. Among these, this case study focuses on the Hansa Coking Plant, a large-scale Revitalization project to rehabilitate the old industrial complexes and facility buildings that have been shut down on December 15, 1992. Purpose of this study is to analyze main project plans of each facility in the Hansa Coking Plant and to bring out the main features of the plans, so that they can be utilized to find suggestions for Industrial/Technological Cultural Properties Revitalization in Korea.

코크스제조공정에서 탄화시간과 시료채취방법에 따른 다핵방향족탄화수소 발생에 관한 연구 (A Study on Polynuclear Aromatic Hydrocarbons Emitted by Coking Time and Sampling Method in a Coke Oven Plant)

  • 윤충식;백남원
    • 한국산업보건학회지
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    • 제3권1호
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    • pp.37-53
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    • 1993
  • The polynuclear hydrocarbons (PAHs) emitted from coke oven standpipe were sampled using three sampling systems, including glass fiber filter+silver membrane filter, glass fiber filter+silver membrane filter+XAD-2 adsorbent tube, PTFE membrane filter+XAD-2 adsorbent tube, extracted by methylene chloride and analysed by gas chromathography using flame ionization detector. The results of this study were as follows. 1. Because the amounts of coke oven emissions(COE) were large, the analyses of PAHs were simple and possible without evaporation and concentration. Although the generation of COE was high during early stage of coking, the airborne concentration of PAHs was low and increased during late coking. 2. The contents of PAHs in COE were 1.35-2.81%. 3. The index components of PAHs were fluoranthene and pyrene. Their correlation coefficient to total PAHs were 0.96, 0.95, respectively. 4. The particulate PAHs were sampled by filter and gaseous PAHs by adsorbent tube. The collection efficiency of glass fiber filter+silver membrane filter was 20% of total amount sampled by filters+adsorbent and PTFE membrane filter 50%. Adsorbent tube must be attached to the filter to collect light and small PAH components. 5. The generation of acenaphthene and indeno (1,2,3-cd) pyrene were low and concentrations of fluorene and anthracene were $20-40ug/m^3$ throughout coking time. Other PAH eoncentrations were sometimes high. The generation of PAHs was low at 4-6 hours of coking time. The gaseous PAHs were generated earlier than particulate PAHs.

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DEA 모형에 의한 제철용 석탄의 효율성 평가 (The Efficiency Evaluation of Coking Coals Using Data Envelopment Analysis)

  • 성덕현;서민수
    • 한국IT서비스학회지
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    • 제10권2호
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    • pp.177-188
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    • 2011
  • This paper proposes a DEA model for the performance evaluation of each brand of coking coals in an integrated steel mill. The performance is defined as the efficiency which is the ratio of two linear combinations of the output factors to the input factors. There is only one input factor considered in the model : unit price of each brand based on CIF. Five output factors are chosen in consideration of their impact to the quality of cokes such as Ash, VM, LMF, TD, and Rm. Some of the output factors are treated as undesirable in DEA model because the quality criteria are given by the range. The CCR and BCC efficiencies are derived by the DEA model, and the scale efficiency is calculated, too. Each brand of coking coal is classified into four categories according to the CCR and BCC efficiencies, and the most inferior brands are identified as a result. The impact of the input and output factors to the efficiency is analyzed using a multiple regression, then the unit price is revealed as the most critical among them. Also, ANOVA results show that there exist efficiency differences among the coal types and the countries imported, respectively. Finally, the quantitative projection for the inefficient brands is performed if they are to be efficient. The result could be utilized in selecting the good or bad brands of coking coal based on the efficiency in an integrated steel mill. Also, this model will be used to assess the relative efficiency of a new brand of coking coal if it is a candidate to be imported.

케로신 연료의 침탄 특성에 대한 온도의 영향 (Effects of Temperature on the Coking Characteristics of Kerosene)

  • 김민철;김영진;김정수
    • 한국추진공학회지
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    • 제23권2호
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    • pp.46-52
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    • 2019
  • 케로신 연료의 침탄 특성에 대한 온도의 영향을 분석한 실험이 수행되었다. 케로신을 각각 600 K, 700 K, 800 K으로 가열한 후, 냉각시킨 시료를 채취하였다. 사용된 구리관은 온도조건에 따라 새로이 교체했다. 기체 크로마토그래피-질량분석과 에너지분산형 X선 분광기가 장착된 주사전자현미경을 통해 액체 시료와 구리 시편의 침탄 특성을 각각 분석하였다. 그 결과, 비교적 고온(800 K)으로 가열된 구리 시편의 내부표면에서 연료의 침탄으로 인해 침전물이 발생한 것을 확인하였다.

가스터빈 연소기 모사 조건에서의 Jet A-1 코킹시험 (Jet A-1 Coking Tests under Conditions Simulating Gas Turbine Combustor)

  • 이다인;이강영;한선우;안규복;유경원
    • 한국추진공학회지
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    • 제26권1호
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    • pp.1-11
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    • 2022
  • 가스터빈에서 연료는 분사기를 통해 연소기에 공급될 때까지 고온 환경에 노출된다. 탄화수소 연료는 고온 조건에서 코킹이 발생하여 코킹 물질이 연료관에 퇴적되거나 분사기 통로를 막을 수 있다. 본 연구에서는 가스터빈 내부에 위치한 연료관을 모사한 시편과 Jet A-1을 전기적인 장치들을 이용해 가열하였다. 스테인리스강 시편의 벽면 온도와 시편에 공급되는 Jet A-1의 온도를 변화시키며, Jet A-1 코킹시험을 수행하였다. 코킹이 발생한 시편들을 절단한 후 코킹 물질과 내부 표면을 에너지 분산 X-선 분석기와 전계방사형주사전자현미경을 통해 분석하였다.

코크스로에서의 열유동 특성에 관한 수치적 연구 (Mathematical Approach of Thermo-fluid Characteristics in a Coke Oven)

  • 양광혁;양원;류창국;최상민
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.43-47
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    • 2003
  • Coke oven is used in an iron-making process for producing coke through devolatilization of the coking coal. An unsteady 2-dimensional model of solid bed is proposed to simulate a coke oven. The model contains governing equations with partial differential equation forms for the solid phase and the gas phase. Drying and devolatilization of coking coal, heat transfer, and generation of internal pores in the coking coal are also reflected to the source terms. Simulation results show a reasonable trend compared with the physical data.

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