• Title/Summary/Keyword: Coking

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Effects of Injector Design Parameter on Nozzle Coking in Diesel Engines (디젤 엔진의 인젝터 설계 변수가 노즐 코킹에 미치는 영향 분석)

  • Kim, Yongrae;Song, Hanho
    • Journal of ILASS-Korea
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    • v.17 no.3
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    • pp.140-145
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    • 2012
  • Recent common-rail injector of a diesel engine needs more smaller nozzle hole to meet the stringent emission regulation. But, small nozzle hole diameter can cause nozzle coking which is occurred due to the deposits of post-combustion products. Nozzle coking has a negative effect on the performance of fuel injector because it obstructs the fuel flow inside a nozzle hole. In this study DFSS (Design for six sigma) method was applied to find the effect of nozzle design parameter on nozzle coking. Total 9 injector samples were chosen and tested at diesel engine. The results show that nozzle hole diameter and K-factor have more effect on nozzle coking than A-mass and hole length. Large hole diameter and A-mass, small hole length and K-factor give more positive performance on nozzle coking in these experimental conditions. But, a performance about nozzle coking and exhaust gas emission shows the opposite tendency. Further study is needed to find the relation between nozzle coking and emission characteristic for the optimization of injector nozzle design.

Thermochemical Conversion of Oil sand Bitumen in Delayed Coking Reactor (코킹 공정(工程)을 이용한 오일샌드 역청(瀝靑)의 열화학(熱化學)적 전환(轉換))

  • Lee, See-Hoon;Yoon, Sang-Jun;Lee, Jae-Goo;Kim, Jae-Ho
    • Resources Recycling
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    • v.17 no.3
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    • pp.35-41
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    • 2008
  • The study of coking technology to upgrade oil sand bitumen which is considered as alternative fuel was performed by using thermogravity analyzer and delayed coking reactor(600ml). To analyzed and compared coking characteristics of oil sand bitumen, the reactivities of oil sand bitumen were measured in the TGA. At the temperature conditions of $400{\sim}550^{\circ}C$ and the temperature rising velocity of $50^{\circ}C/min$. the termination time of coking reaction and conversion efficiencies increased with an increase of bed temperature. However the increase rate decreased over $450^{\circ}C$. So the coking reaction with oil sand bitumen might be over $450^{\circ}C$. Also the termination time decreased with increasing the temperature rising velocity. But the content of coke increased with increasing temperature rising velocity. At the experiments in the delayed coker, the temperature condition at maximum oil yield was $475^{\circ}C$ and the fuel properties of oil from coking reaction was almost equal with conventional diesel. It was verified that the coking process might be useful process to upgrade the oil sand bitumem by using API and SIMDAS.

Modeling of Coking Process in a Coke Oven (코크스 공정에서의 열유동 현상 모델링)

  • Yang, Kwang-Heok;Yang, Won;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1184-1189
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    • 2004
  • Coking process is the thermal decomposition of bituminous coal with final temperature of about $900^{\circ}C$ Because coke plays important roles in ironmaking process in a blast furnace it's essential for developing modeling of coke oven. In this study, An unsteady 2-dimesional model is proposed to simulate coking process in a coke oven. In this model, gas and solid phase are assumed homogeneous continnum and solid bed is assumed as porous media . The model contains governing equations for the solid phase and the gas phase. Complicated phenomena such as swelling, softening, resolidification and shrinkage are neglected and mass loss by drying and devolatilization is reflected by generation of internal pores. Drying, devolatilization, heat transfer and generation of internal pores are also reflected in source terms. Calulated results are compared with experimental data

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Preparation of needle coke from petroleum by-products

  • Halim, Humala Paulus;Im, Ji Sun;Lee, Chul Wee
    • Carbon letters
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    • v.14 no.3
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    • pp.152-161
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    • 2013
  • Needle coke is an important material for graphite electrodes. Delayed coking is used to produce needle coke. Producing good quality needle coke is not simple because it is a multi-parameter controlled process. Apart from that, it is important to understand the mechanism responsible for the delayed coking process, which involves mesophase formation and uniaxial rearrangement. Temperature and pressure need to be optimized for the different substances in every feedstock. Saturate hydrocarbon, aromatic, resin and asphaltene compounds are the main components in the delayed coking process for a low Coefficient Thermal Expansion value. In addition, heteroatoms, such as sulphur, oxygen, nitrogen and metal impurities, must be considered for a better graphitization process that prevents the puffing effect and produces better mesophase formation.

Analysis on the Characteristics of the Precedents for Industrial/Technological Cultural Properties of the Hansa Coking Plant (독일 산업·기술문화재 한자 코크스 제조소 재생사례 분석)

  • Kim, Hong-Gi;Park, Chang-Ho
    • Journal of the Korea Furniture Society
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    • v.27 no.1
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    • pp.59-68
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    • 2016
  • The Industrial/Technological Cultural Properties are being protected, the rest facing with demolition and damages. In order to better cope with such situation, Korea has officially introduced the Registered Cultural Properties System since 2001 and began acknowledging the historical values of industrial buildings as modern cultural properties. In the Nordrhein-Westfalen, Germany, there are approximately 3,500 industrial buildings under the cultural asset protection and management not only in the Ruhr-region but also state-wide. Among these, this case study focuses on the Hansa Coking Plant, a large-scale Revitalization project to rehabilitate the old industrial complexes and facility buildings that have been shut down on December 15, 1992. Purpose of this study is to analyze main project plans of each facility in the Hansa Coking Plant and to bring out the main features of the plans, so that they can be utilized to find suggestions for Industrial/Technological Cultural Properties Revitalization in Korea.

A Study on Polynuclear Aromatic Hydrocarbons Emitted by Coking Time and Sampling Method in a Coke Oven Plant (코크스제조공정에서 탄화시간과 시료채취방법에 따른 다핵방향족탄화수소 발생에 관한 연구)

  • Yun, Chung Sik;Paik, Nam Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.3 no.1
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    • pp.37-53
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    • 1993
  • The polynuclear hydrocarbons (PAHs) emitted from coke oven standpipe were sampled using three sampling systems, including glass fiber filter+silver membrane filter, glass fiber filter+silver membrane filter+XAD-2 adsorbent tube, PTFE membrane filter+XAD-2 adsorbent tube, extracted by methylene chloride and analysed by gas chromathography using flame ionization detector. The results of this study were as follows. 1. Because the amounts of coke oven emissions(COE) were large, the analyses of PAHs were simple and possible without evaporation and concentration. Although the generation of COE was high during early stage of coking, the airborne concentration of PAHs was low and increased during late coking. 2. The contents of PAHs in COE were 1.35-2.81%. 3. The index components of PAHs were fluoranthene and pyrene. Their correlation coefficient to total PAHs were 0.96, 0.95, respectively. 4. The particulate PAHs were sampled by filter and gaseous PAHs by adsorbent tube. The collection efficiency of glass fiber filter+silver membrane filter was 20% of total amount sampled by filters+adsorbent and PTFE membrane filter 50%. Adsorbent tube must be attached to the filter to collect light and small PAH components. 5. The generation of acenaphthene and indeno (1,2,3-cd) pyrene were low and concentrations of fluorene and anthracene were $20-40ug/m^3$ throughout coking time. Other PAH eoncentrations were sometimes high. The generation of PAHs was low at 4-6 hours of coking time. The gaseous PAHs were generated earlier than particulate PAHs.

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The Efficiency Evaluation of Coking Coals Using Data Envelopment Analysis (DEA 모형에 의한 제철용 석탄의 효율성 평가)

  • Seong, Deok-Hyun;Suh, Min-Soo
    • Journal of Information Technology Services
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    • v.10 no.2
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    • pp.177-188
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    • 2011
  • This paper proposes a DEA model for the performance evaluation of each brand of coking coals in an integrated steel mill. The performance is defined as the efficiency which is the ratio of two linear combinations of the output factors to the input factors. There is only one input factor considered in the model : unit price of each brand based on CIF. Five output factors are chosen in consideration of their impact to the quality of cokes such as Ash, VM, LMF, TD, and Rm. Some of the output factors are treated as undesirable in DEA model because the quality criteria are given by the range. The CCR and BCC efficiencies are derived by the DEA model, and the scale efficiency is calculated, too. Each brand of coking coal is classified into four categories according to the CCR and BCC efficiencies, and the most inferior brands are identified as a result. The impact of the input and output factors to the efficiency is analyzed using a multiple regression, then the unit price is revealed as the most critical among them. Also, ANOVA results show that there exist efficiency differences among the coal types and the countries imported, respectively. Finally, the quantitative projection for the inefficient brands is performed if they are to be efficient. The result could be utilized in selecting the good or bad brands of coking coal based on the efficiency in an integrated steel mill. Also, this model will be used to assess the relative efficiency of a new brand of coking coal if it is a candidate to be imported.

Effects of Temperature on the Coking Characteristics of Kerosene (케로신 연료의 침탄 특성에 대한 온도의 영향)

  • Kim, Min Cheol;Kim, Yeong Jin;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.46-52
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    • 2019
  • This research was conducted to analyze the effects of temperature on coking characteristics of kerosene. The kerosene was heated to 600 K, 700 K, and 800 K, and the cooled samples were collected. The used copper tubes were replaced according to the temperature conditions. The liquid and copper specimens were analyzed by gas chromatography-mass spectrometry and scanning electron microscopy equipped with an energy dispersive x-ray spectrometer, respectively. The results of the analysis confirmed that a carbon deposit was formed from the coking of fuel on the inner surface of the copper specimen at a relatively high temperature (800 K) of the copper tube.

Jet A-1 Coking Tests under Conditions Simulating Gas Turbine Combustor (가스터빈 연소기 모사 조건에서의 Jet A-1 코킹시험)

  • Lee, Dain;Lee, Kangyeong;Han, Sunwoo;Ahn, Kyubok;Ryu, Gyong Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.1
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    • pp.1-11
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    • 2022
  • In a gas turbine, fuel is exposed to a high temperature environment until it is fed to the combustor through the injector. Hydrocarbon fuels can coke under high temperature conditions, which can cause coking material to deposit on fuel lines or block the injector passages. In this study, a specimen simulating a fuel line located inside a gas turbine and Jet A-1 were heated using electric devices. Jet A-1 coking tests were performed by changing the wall temperature of the stainless steel specimen and the temperature of Jet A-1 supplied to the specimen. After the coked specimens were cut, the coking material and the inner surface were analyzed using an energy dispersive X-ray spectrometer and a field emission scanning electron microscope.

Mathematical Approach of Thermo-fluid Characteristics in a Coke Oven (코크스로에서의 열유동 특성에 관한 수치적 연구)

  • Yang, Kwang-Heok;Yang, Won;Ryu, Chang-Kook;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.43-47
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    • 2003
  • Coke oven is used in an iron-making process for producing coke through devolatilization of the coking coal. An unsteady 2-dimensional model of solid bed is proposed to simulate a coke oven. The model contains governing equations with partial differential equation forms for the solid phase and the gas phase. Drying and devolatilization of coking coal, heat transfer, and generation of internal pores in the coking coal are also reflected to the source terms. Simulation results show a reasonable trend compared with the physical data.

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