• Advances in materials Research
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• v.11 no.4
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• pp.299-330
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• 2022

This review article highlights the physical, mechanical, and chemical properties of coconut shells, and the fresh and hardened properties of the coconut shell concrete are summarized and were compared with other types of aggregates. Furthermore, the structural behavior in terms of flexural, shear, and torsion was also highlighted, with other properties including shrinkage, elastic modulus, and permeability of the coconut shell concrete. Based on the reviewed literature, concrete containing coconut shell as coarse aggregate with normal sand as fine showed the 28-day compressive strength between 2 and 36 MPa with the dried density range of 1865 to 2300 kg/m³. Coconut shell concretes showed a 28-day modulus of rupture and splitting tensile strength values in the ranges of 2.59 to 8.45 MPa and 0.8 to 3.70 MPa, respectively, and these values were in the range of 5-20% of the compressive strength. The flexural behavior of CSC was found similar to other types of lightweight concrete. There were no horizontal cracks on beams which indicate no bond failure. Whereas, the diagonal shear failure was prominent in beams with no shear reinforcements while flexural failure mode was seen in beams having shear reinforcement. Under torsion, CSC beams behave like conventional concrete. Finally, future recommendations are also suggested in this study to investigate the innovative lightweight aggregate concrete based on the environmental and financial design factors.

• Applied Chemistry for Engineering
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• v.35 no.1
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• pp.37-41
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• 2024

The coconut shell, a by-product of popular tropical fruit, is a promising material due to its interesting properties. The preparation of the composite consisted of conducting polymer and coconut shell using a simple wet method, and subsequent carbonization produced a carbonized material under a controlled carbonization cycle. In addition, its electrochemical performance as an anode in lithium-ion batteries was also investigated. The appearance of the obtained materials was observed with a scanning electron microscope. The internal structure of the carbon derived from the coconut shell under a controlled heating profile was analyzed using a Raman spectroscope. A simple electrical measurement based on the ohmic relationship showed that the carbonized product has a significant electrical conductivity. The application of the carbonized product as anode in a lithium-ion battery was tested using half-cell charge/discharge experiments. This article provides important information for future research regarding the recycling of fruit shells and food waste.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.6
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• pp.357-362
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• 2015

A novel $TiO_2$-Coconut Shell Powder Composite (TCSPS), prepared by the controlled sol-gel method with subsequent heat treatment, was evaluated as an innovative photocatalytic absorbent for the removal of methylene blue. Optimal preparation conditions of TCSPC were obtained by a response surface methodology and a central composite design model. As compared with the results obtained from one-factor-at-a-time experiments, the values were approximated to the nearest condition of these values and the following experimental parameters were set as the optimum : $600^{\circ}C$ calcination temperature and 20 g of coconut shell powder loading amount.

• Journal of the Korean Chemical Society
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• v.51 no.2
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• pp.154-159
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• 2007

Biodegradation of Quinoline by free and immobilized Bacillus brevis has been investigated. The rate of quinoline degradation by immobilized Bacillus brevis on coconut shell carbon is faster than the rate by the microorganism immobilized on foam pieces and free cells. A complete removal of 100 ppm of Quinoline in the sample was achieved at a hydraulic retention time of 20 hours with the biocatalyst prepared by immobilizing Bacillus brevis onto coconut shell carbon. The biocatalyst had a reasonable shelf life and desirable recycle capacity.

• Journal of the Korean Society of Tobacco Science
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• v.16 no.2
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• pp.181-190
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• 1994

Various active carbons were made from plant sources of coconut shell, pine tree, oak tree and lignite coal. Pore characteristics of these adsorbents were investigated. 1, With increasing activation time, specific surface area and pore volume increased, but the development of micropores was limited at a certain level. The average pore diameter, by BET, of coconut active carbon was 15.5-21.8$\AA$ and that of lignite carbon was 15.6-31.3$\AA$. The pore diameters of silica-gel, sepiolite and zeolite was 30.9$\AA$, 58.6$\AA$ and 55.7$\AA$, respectively. 2. The Horvath - Kawazoe micropore diameter of coconut shell active carbon was under 10.5$\AA$ and that of the other active carbon was under 20.9$\AA$ but silica-gel 33$\AA$, sepiolite 103 $\AA$ and zeolite was unexpectedly large to be 175$\AA$. From the difference between BET micropore diameter and Howath - Kawazoe diameter, it could be said that silica - gel has comparatively uniform pore diameter but sepiolite and zeolite have very uneven diameter. 3. Total pore volume of coconut shell active carbon was 0.27-1.04 cm3/g but that of the other active carbon, 0.23-0.62 cm3/g, was much lower than that of coconut shell active carbon. Hydrophilic adsorbent silica - gel and sepiolite showed big difference in specific surface area, but pore volumes of these were 0.47 and 0.56 cm3/g showing similar value and micropore volumes of these were, respectively, 0.06 cm3/g and 0.04 cm3/g. Total pore volume of zeolite was 0.1 cm3/g and that of micropore was only 0.02 cm3/g.

• Journal of Environmental Health Sciences
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• v.19 no.4
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• pp.25-32
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• 1993

Granular activated carbon is commonly used in fixed-bed adsorbers to remove organic chemicals. In this experiment organic chemical solutions were prepared by adding the reagent grade organic chemical to distilled water. Isotherm adsorption tests of volatile organic chemicals were conducted using bottle-point technique and column test. Organic chemicals after passing through the column were extracted with hexane and analyzed with gas chromatography (Hewlett-Packard 5890) to check the adsorption capacity and breakthrough curve. The result were as follows: 1. The BET surface area of coconut activated carbon was 658~1,010 m$^2$/g where as coconut shell carbon was 6.6 m$^2$/g. Coconut activated carbon increased the BET surface area and adsorption capacity in bottle-point isotherm. 2. The adsorption capacity of coconut activated carbon for trichloroethylene (TCE) was reduced in the presence of humic substance. 3. A decrease in particle size of activated carbon resulted in higher adsorption capacity and lower intraparticle diffusion coefficient. It is reflected not only as a decrease in Freudlich adsorption capacity value (K) but also as an increase in Freudlich exponenent value (1/n).

• Environmental Analysis Health and Toxicology
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• v.4 no.3_4
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• pp.29-59
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• 1989

For the purpose of electrolytic treatment of wastewater containing various heavy metals, the BPBE Cell of batch and continuous type was considered and experimented. Some results from this study were summarized as follows: 1. When the artificial wastewater containing 500 mg/l of the concentration of various heavy metallic ion was electrolyzed in BPBE Cell of batch type, the removal efficicency was over 95% in cadmiun (II), lead (II), chromium (Ⅵ) and over 85% in copper (II), chromium (III). 2, As granular activated carbon packed in BPBE Cell, coconut shell was superior to lignite and the removal efficiency was the highest when the activated carbon was 4/6 mesh, the voltage was 20V. 3. When the heavy metallic ion in wastewater was electrolyzed in BPBE Cell of continuous type, about 1,000mg of heavy metal per 1kg of coconut sell could be removed. 4. The treatment method of heavy metallic ion in wastewater by BPBE Cell cost less than in the former chemical treatment method and the coconut shell packed in BPBE Cell could be regenerated by chemical method.

• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.362-370
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• 2013

The coconut shell based activated carbon was applied for EDLC (electric double layer capacitor) electrode with the post treatments. The electrochemical properties were evaluated with a coin cell using the activated carbon as electrode. The initial gravimetric and volumetric capacitance of the coconut shell based activated carbon electrode s were 66 F/g and 39 F/cc, and these values decreased to 54 F/g and 32 F/cc after 100 cycles, respectively showing 82% of charge-discharge efficiency. The properties of CV graph with the commercial activated carbon electrodes showed the serious polarization as the result of additional reaction between electrolyte and impurities of the electrode materials. In order to remove impurities efficiently, the commercial activated carbon was treated by alkali and acid solutions consecutively, and then heat treated to control the pore size distribution and the content of surface functional groups. The surface functional groups decreased with the increased heat temperature and the specific capacitance increased with the decreased surface functional groups. The initial capacitance of coconut shell based activated carbon elec trode which was treated with NaOH and HNO3, and then heat treated at $800^{\circ}C$ was 44 F/cc, and the value turned out to be 42 F/cc after 100 cycles, showing over 95% of charge-discharge efficiency.

• Carbon letters
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• v.20
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• pp.1-9
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• 2016

Activated carbon was synthesized from coconut shells. The Brunauer, Emmett and Teller surface area of the synthesized activated carbon was found to be 1640 m²/g with a pore volume of 1.032 cm³/g. The average pore diameter of the activated carbon was found to be 2.52 nm. By applying the size-strain plot method to the X-ray diffraction data, the crystallite size and the crystal strain was determined to be 42.46 nm and 0.000489897, respectively, which indicate a perfect crystallite structure. The field emission scanning electron microscopy image showed the presence of well-developed pores on the surface of the activated carbon. The presence of important functional groups was shown by the Fourier transform infrared spectroscopy spectrum. The adsorption of methyl orange onto the activated carbon reached 100% after 12 min. Kinetic analysis indicated that the adsorption of methyl orange solution by the activated carbon followed a pseudo-second-order kinetic mechanism (R² > 0.995). Therefore, the results show that the produced activated carbon can be used as a proper adsorbent for dye containing effluents.

• Journal of environmental and Sanitary engineering
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• v.14 no.2
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• pp.18-24
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• 1999

The purpose of this study was carried out to estimate removal possibility of IBMP and IPMP causing odor in raw water. As a result of Freundlich isotherm. IBMP was superior to IPMP in adsorptive capacity. Adsorptive capacities of activated carbon were found to be in order of Lignite, Coconut shell, and Charcoal. These were well fitted with Freundlich isotherm. According to adsorption breakthrough tests for Lignite GAC, breakthrough time of IPMP and IBMP were 5.7hr and 5.5hr, respectively. Because adsorptive capacities of target material were very different with pore size distribution, it seemed that Lignite and Coconut shell based activated carbons were recommended in order to remove door compounds.