• Title/Summary/Keyword: Cobalt effect

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FRICTIONAL FORCES BETWEEN ORTHODONTIC WIRE AND BRACKET UNDER ARTIFICIAL SALIVA (인공타액하에서 교정선과 Bracket간의 마찰력에 대한 연구)

  • Ko, Jeong-Seok;Yang, Kyu-Ho
    • The korean journal of orthodontics
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    • v.18 no.1 s.25
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    • pp.55-63
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    • 1988
  • It has been suggested that the frictional force between bracket and arch wire may impede the tooth movement. The present study was aimed to compare and analyze the effect of wire size, type of ligation, and duration of ligation on the magnitude of frictional force between cobalt chromium wire and stainless steel bracket under the artificial saliva. The results were as follows: 1. Type of ligation and size of wire were the main influencing factor on the level of friction. 2. Stainless steel ligature generated higher frictional forces than elastomeric module. 3. The rectangular wire consistently exhibited more frictional force values than round wires, while there was no significant difference between frictional forces of round wires. 4. In elastic ligature, frictional force decreased with time. 5. Artificial saliva had no significant influence on the frictional force between cobalt chromium wire and bracket.

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Effect of metal ions on the secondary structure and activity of calf intestine phosphatase

  • Chen, Fengjuan;Liu, Guoqi;Xu, Zhihong;Zeng, Zhengzhi
    • BMB Reports
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    • v.41 no.4
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    • pp.305-309
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    • 2008
  • Cobalt is an essential microelements in many biological processes involving enzymatic activity. We found that $Zn^{2+}$ and $Mg^{2+}$, which are in the active site of native calf intestine alkaline phosphatase (CIP), can be replaced by $Co^{2+}$ directly in solution. The effect of $Co^{2+}$ concentration on the substitution reaction was examined at ratios of [$Co^{2+}$]/[CIP] from 0:1 to 8:1. The quantity of $Zn^{2+}$ in CIP decreased progressively as the ratio was increased, but the amount of $Mg^{2+}$ changed in irrregular fashion. A series of active site models of the reaction mechanism of CIP are proposed. Low pH was found to promote the replacement of $Mg^{2+}$ by $Co^{2+}$. To understand how the substitution affects the enzyme, we also solved the secondary structure of CIP after reaction with $Co^{2+}$ in different conditions.

The Effects of Siegesbeckiae Herba on EDRF in the Carotid Artery of the Rabbit (희렴이 가토(家兎)의 혈관내피세포성(血管內皮細胞性) 이완인자(弛緩因子)에 미치는 영향(影響))

  • Kim, Ho-Hyun;Kim, Gil-Whon
    • The Journal of Korean Medicine
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    • v.18 no.2
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    • pp.15-32
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    • 1997
  • This study was undertaken to define the mechanism of Siegesbeckiae Herba-induced relaxation in rabbit common carotid artery contracted by agonists. In order to investigate the effect of Siegesbeckiae Herba on contracted rabbit carotid arterial strips, transverse strips with intact or damaged endothelium were used for the experiment using organ bath. To analyze the mechanism of Siegesbeckiae Herba-induced relaxation, Siegesbeckiae Herba extract infused into contracted arterial strips induced by agonists after treatment of lanthanum chloride, indomethacin, atropine, $N\omega-nitro-{_L}-arginine$, cobalt chloride or methylene blue. The relaxation effect of Siegesbeckiae Herba was dependent on the presence of endothelium, showing that Siegesbeckiae Herba-induced relaxation was not observed in the strips without endothelium. The endothelium-dependent relaxation induced by Siegesbeckiae Herba was suppressed by the pretreatment of lanthanum chloride, $N\omega-nitro-{_L}-arginine$, cobalt chloride or methylene blue, but it was not observed in the strips pretreated with indomethacin or atropine. These results demonstrated that Siegesbeckiae Herba may inhibit agonist-induced contraction through an increase in the cyclic GMP by the production of nitric oxide in the vascular endothelial cells.

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Effect of Manganese Promotion on Al-Pillared Montmorillonite Supported Cobalt Nanoparticles for Fischer-Tropsch Synthesis

  • Ahmad, N.;Hussain, S.T.;Muhammad, B.;Ali, N.;Abbas, S.M.;Khan, Y.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3005-3012
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    • 2013
  • The effect of Mn-promotion on high surface area Al-pillared montmorillonite (AlMMT) supported Co nanoparticles prepared by hydrothermal method have been investigated. A series of different weight% Mn-promoted Co nanoparticles were prepared and characterized by XRD, TPR, TGA, BET and SEM techniques. An increase in the surface area of MMT is observed with Al-pillaring. Fischer-Tropsch catalytic activity of the as prepared catalysts was studied in a fixed bed micro reactor at $225^{\circ}C$, $H_2/CO$ = 2 and at 1 atm pressure. The data showed that by the addition of Mn the selectivity of $C_1$ dropped drastically while that of $C_2-C_{12}$ hydrocarbons increased significantly over all the Mn-promoted Co/AlMMT catalysts. The $C_{13}-C_{20}$ hydrocarbons remained almost same for all the catalysts while the selectivity of $C_{21+}$ long chain hydrocarbons decreased considerably with the addition of Mn. The catalyst with 3.5%Mn showed lowest $C_{21+}$ and highest $C_2-C_{12}$ hydrocarbons selectivity due to cracking of long chain hydrocarbons over acidic sites of MMT.

Effect of TIBA on the Brassiolide-induced Gravitropic Response in the Primary Roots of Maize (옥수수 일차뿌리에서 TIBA가 brassinolide에 의해 유도된 굴중성 반응에 미치는 영향)

  • Kang, Byung-Hee;Park, Jea-Hye;Kim, Jong-Sik;Jang, Soo-Chul;Kim, Seung-Ki;Kim, Soon-Young
    • Journal of Life Science
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    • v.19 no.8
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    • pp.1139-1144
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    • 2009
  • It has been known that brassiolide (BL) increased the positive gravitropic response and ethylene production in maize roots. This study examined the relationship between the BL-induced gravitropic response and ethylene Production. The ethylene production was inhibited to about 90% of the control by the treatment of $10^{-4}$ M aminoethoxyvinylglycine (AVG), the ethylene synthesis inhibitor. However, the gravitropic response did not show any significant changes compared to the control at $10^{-4}$ M AVG. In the case of treatment of AVG with BL, the ethylene production decreased to 60% of the control. However, the gravitropic response increased to the level which was induced by BL. Cobalt ions, another ethylene biosynthesis inhibitor, inhibited ethylene production, but not gravitropic response. When roots were treated with BL and cobalt ions, they showed the inhibition of ethylene production and promotion of gravitropic response. To elucidate the possibility that the effect of BL is related to auxin transport, roots were treated with TIBA (2,3,5-triiodobenzoic acid), an auxin transport inhibitor. Both treatment of TIBA alone and TIBA with BL stimulated ethylene production to about 96% and 132%, respectively. However, gravitropic response was completely inhibited in both treatments. Further, roots treated with BL in the presence of TIBA and IAA showed a negative gravitropic response, which means that IAA accumulates in the upper side of horizontal roots. Root elongation was also stimulated in this treatment. Taken together, these results suggest that BL might affect the differential distribution of internal IAA on roots, causing the regulation of positive gravitropic response.

Recovery of Tungsten from WC-Co Hardmetal Sludge by Aqua regia Treatment (WC-Co 초경합금(超硬合金) 슬러지로부터 왕수처리(王水處理)를 이용한 텅스텐의 회수(回收))

  • Kim, Ji-Hye;Kim, Eun-Young;Kim, Won-Back;Kim, Byung-Su;Lee, Jae-Chun;Shin, Jae-Soo
    • Resources Recycling
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    • v.19 no.4
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    • pp.41-50
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    • 2010
  • A fundamental study was carried out to develop a process for recycling tungsten and cobalt from WC-Co hardmetal sludge generated in the manufacturing process of hardmetal tools. The complete extraction of cobalt and simultaneous formation of tungstic was achieved by treating the sludge using aqua regia. The effect of aqua regia concentration, reaction temperature and time, pulp density on cobalt leaching and tungstic acid formation was investigated. The complete leaching of cobalt was attained at the optimum conditions: 100 vol.% aqua regia concentration, $100^{\circ}C$ temperature, 60 min. reaction time and 400 g/L pulp density. A complete conversion of tungsten carbide of the sludge to tungstic acid was however, obtained at the pulp densities lower than 150 g/L under the above condition. The progress of reaction during the aqua regia treatment of the sludge was monitored through the XRD phase identification of the residue. The metallic impurities in the tungstic acid so produced could be further removed as insoluble residues by dissolving the tungsten values in ammonia solution. The ammonium paratungstate($(NH_4)_{10}{\cdot}H_2W_{12}O_{42}{\cdot}4H_2O$) of 99.85% purity was prepared from the ammonium polytungstate solution by the evaporation crystallization method.