Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Effect of Manganese Promotion on Al-Pillared Montmorillonite Supported Cobalt Nanoparticles for Fischer-Tropsch Synthesis

  • Ahmad, N. (Department of Chemistry, Hazara University) ;
  • Hussain, S.T. (National Centre for Physics, QAU Campus) ;
  • Muhammad, B. (Department of Chemistry, Hazara University) ;
  • Ali, N. (Department of Physics, University of the Punjab) ;
  • Abbas, S.M. (National Centre for Physics, QAU Campus) ;
  • Khan, Y. (National Centre for Physics, QAU Campus)
  • Received : 2013.02.23
  • Accepted : 2013.07.22
  • Published : 2013.10.20
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Abstract

The effect of Mn-promotion on high surface area Al-pillared montmorillonite (AlMMT) supported Co nanoparticles prepared by hydrothermal method have been investigated. A series of different weight% Mn-promoted Co nanoparticles were prepared and characterized by XRD, TPR, TGA, BET and SEM techniques. An increase in the surface area of MMT is observed with Al-pillaring. Fischer-Tropsch catalytic activity of the as prepared catalysts was studied in a fixed bed micro reactor at $225^{\circ}C$, $H_2/CO$ = 2 and at 1 atm pressure. The data showed that by the addition of Mn the selectivity of $C_1$ dropped drastically while that of $C_2-C_{12}$ hydrocarbons increased significantly over all the Mn-promoted Co/AlMMT catalysts. The $C_{13}-C_{20}$ hydrocarbons remained almost same for all the catalysts while the selectivity of $C_{21+}$ long chain hydrocarbons decreased considerably with the addition of Mn. The catalyst with 3.5%Mn showed lowest $C_{21+}$ and highest $C_2-C_{12}$ hydrocarbons selectivity due to cracking of long chain hydrocarbons over acidic sites of MMT.

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