• Title/Summary/Keyword: Cobalt effect

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Magnetic Properties of Thin Cu/Co Multilayers Made by Electrodeposition

  • Lee, Jung-Ju;Lee, Jin-Han;Hong, Kim-In
    • Journal of Magnetics
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    • v.10 no.3
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    • pp.118-121
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    • 2005
  • We have investigated the magnetic properties of electroplated thin Cu/Co multilayers by using electrolytes made of copper sulphate and cobalt sulphate and by applying alternating plating voltage. While the multilayers plated with pure electrolyte showed superparamagnetism, those plated with organic additives showed ferromagnetic behavior. These changes are attributed to the so-called 'self-annealing' effect and reduction of grain size caused by the organic additives.

Modification of Survival and Blood-forming Stem Cells in Cobalt-60 Gamma Irradiated Mice by Aloe vera (Aloe vera투여가 Cobalt-60 감마선 조사를 받은 마우스의 생존율과 조혈간세포에 미치는 영향)

  • Choi Min-cheol;Sung Jai-Ki
    • Journal of Veterinary Clinics
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    • v.7 no.2
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    • pp.451-469
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    • 1990
  • The present study was carried out to investigate whether the aloe had a radioprotective effect in mice exposed to cobalt-60 gamma radiation or not. The survival ratio of mice for 30 days, hematopoiesis of blood-forming stem cells by spleen colony assay, chromosomal aberration frequency of bone marrow cells and histopathological findings of bone marrow were investigated. The survival ratios of aloe administered groups with concentration of 250, 500, 1,000 and 1,500mg for 3 days before irradiation and control group in cobalt-60 gamma irradiated mice(700rads whole body irradiation, dose rate of 50rads/min.) were 77.4, 79.3, 80.6, 90.0 and 53.1%, respectively. The survival ratios of pre-irradiation aloe administered groups were superior to those of post-irradiation aloe groups and control group. In spleen colony assay, Aloe vera administration before irradiation enhanced the recoveries of numbers of blood-forming stem cells of bone marrow of irradiated mice. There were decreased chromosomal aberrations of bone marrow cells at the first day after irradiation in aloe administered groups compared to that of control group. Histopathological findings in the bone marrow of irradiated mice were hypocellularity due to the depletion of myelocytes, abundant of fat vacuoles and these changes were weakened in aloe administered groups compared to that of control group.

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EFFECT OF COBALT-60 IRRADIATION ON THE DEVELOPING TOOTH GERM OF RAT (Cobalt-60이 발육치배조직에 미치는 영향에 관한 실험적 연구)

  • Lee Ki Sik
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.6 no.1
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    • pp.33-38
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    • 1976
  • The author observed the effects of the cobalt-60 irradiation on the amelogenesis and dentinogenesis of the albino rat fetuses by means of histological and histochemical methods. Females in oestrus were mated overnight and examined the next morning for evidence of copulation. The lower left abdomen of mothers were exposed to cobalt-60 irradiation on the 10th day of gestation, l00R 200R and 300R respectively. The fetuses were removed from the mothers on the 18th day of gestation. The employed histochemical methods were PAS reaction, colloidal iron reaction, aldehyde fuchsin stain, α-amino acid reaction, -SH radical reaction and methyl- green pyronin stain. The results were as follows; 1. The group irradiated by l00R made no histological differences in comparison with the control group. 2. Increasing the irradiation to 200R, abnormal dentin formation occured, and resulted in enamel hypoplasia and in atrophy and necrosis of odontoblasts. In dentinal papilla, the dilation and the degeneration of the blood vessels, excessive reticular atrophy and osteodentin were revealed. 3. With the more irradiation (200R-300R), the positive material of PAS, α-amino acid and aldehyde fuchsin tended to decrease in the ameloblast and the odontoblast. No significant changes appeared in DNA, the stainability of methylgreen pyronin.

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Effect of Sulfurization on SILAR Synthesized Cobalt Phosphate Hydrate Nanosheets for Oxygen Evolution Reaction

  • Kamble, Girish;Malavekar, Dhanaji;Jang, Suyoung;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.32 no.10
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    • pp.408-413
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    • 2022
  • The oxygen evolution reaction (OER) is very sluggish compared to the hydrogen evolution reaction (HER). Considering this difference is essential when designing and developing a cost-effective and facile synthesis method for a catalyst that can effectively perform OER activity. The material should possess a high surface area and more active sites. Considering these points, in this work we successfully synthesized sheets of cobalt phosphate hydrate (CP) and sulphurated cobalt phosphate hydrate (CPS) material, using simple successive ionic layered adsorption and reaction (SILAR) methods followed by sulfurization. The CP and CPS electrodes exhibited overpotentials of 279 mV with a Tafel slope of 212 mV dec-1 and 381 mV with a Tafel slope of 212 mV dec-1, respectively. The superior performance after sulfurization is attributed to the intrinsic activity of the deposited well-aligned nanosheet structures, which provided a substantial number of electrochemically active surface sites, speeded electron transfer, and at the same time improved the diffusion of the electrolyte.

Effect of Carrier Gas on the Microstructure and Magnetic Properties of Co Nanoparticles Synthesized by Chemical Vapor Condensation (화학기상응축공정(Chemical Vapor Condensation)으로 제조된 Co 나노분말의 미세구조 및 자기적 성질에 미치는 운송기체의 영향)

  • ;X. L. Dong
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.16-21
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    • 2004
  • The nano-sized Co particles were successfully synthesized by chemical vapor condensation (CVC) process using the precursor of cobalt carbonyl ($Co_2(CO)_8$). The influence of carrier gases on the microstructure and magnetic properties of nanoparticles was investigated by means of XRD, TEM, XPS and VSM. The Co nano-particles with different phases and shapes were synthesized with a change of carrier gas : long string morphologies with coexistence of fcc and hcp structure in Ar carrier gas condition; finer Co core in a mass of cobalt oxide with only fcc structure in He; rod type cobalt oxide phase in Ar+6vol%$O_2$. The saturation magnetization and coercivity was lower in Co nanoparticles synthesized in He carrier gas, due to their finer size.

Factors affecting sisomicin production by Micromonospora inyoensis (Micromonospora inyoensis에 의한 시소마이신 생산에 영향을 미치는 인자들)

  • Lee, Jae-Heung;Gil, Gwang-Hoon;Cho, Young-Je;Yoo, Moo-Young
    • Microbiology and Biotechnology Letters
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    • v.14 no.5
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    • pp.355-358
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    • 1986
  • The effects of cobalt chloride, methionine, and various carbon sources on the sisomicin production by M. inyoensis NRRL 3292 were investigated. It was found that both cobalt chloride and methionine exerted a greater stimulatory effect on sisomicin formation. Kinetic studies with various carbon sources revealed thai polysaccharide such as starch or dextrin was found io be better than glucose for sisomicin production Moreover, the relatively low concentration of dissolved carbon dioxide was one of the most important factors In accelerating sisomicin production during idiophase.

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Heat and Mass Transfer Properties of Mm-Based Metal Hydride upon Co Content (Mm계 금속수소화물의 Co함량에 따른 열 및 물질전달특성)

  • Park, Chan-kyo
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.2
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    • pp.144-151
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    • 2004
  • The effect of the cobalt content on the thermodynamic and, heat and mass transfer properties of the $MmNi_{5-y}B_{y-z}C_z(y=0.5{\sim}1.5,\;z=0.5)$hydrogen storage alloys has been studied systematically. The P-C isotherms curves show that with increasing cobalt content in the alloys, the plateau pressure of the hydrogen absorption and desorption and enthalpy(${\Delta}H$) increases steeply and the plateau region becomes flat, while entropy(${\Delta}S$) decreases. Also at the constant cobalt content the hydrogen transfer rate decreases with the reaction temperature, while the initial reaction kinetics increases. But the initial reaction with hydrogen completes within 1min, although the reaction proceeds about 30minutes thereafter.

The Heat Shock Protein 27 (Hsp27) Operates Predominantly by Blocking the Mitochondrial-Independent/Extrinsic Pathway of Cellular Apoptosis

  • Tan, Cheau Yih;Ban, Hongseok;Kim, Young-Hee;Lee, Sang-Kyung
    • Molecules and Cells
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    • v.27 no.5
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    • pp.533-538
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    • 2009
  • Heat shock protein 27 (Hsp27) is a molecular chaperone protein which regulates cell apoptosis by interacting directly with the caspase activation components in the apoptotic pathways. With the assistance of the Tat protein transduction domain we directly delivered the Hsp27 into the myocardial cell line, H9c2 and demonstrate that this protein can reverse hypoxia-induced apoptosis of cells. In order to characterize the contribution of Hsp27 in blocking the two major apoptotic pathways operational within cells, we exposed H9c2 cells to staurosporine and cobalt chloride, agents that induce mitochondria-dependent (intrinsic) and -independent (extrinsic) pathways of apoptosis in cells respectively. The Tat-Hsp27 fusion protein showed a greater propensity to inhibit the effect induced by the cobalt chloride treatment. These data suggest that the Hsp27 predominantly exerts its protective effect by interfering with the components of the extrinsic pathway of apoptosis.

Effects of Metallaic Dialkyldithiophosphates on Lubricating Oil (금속 디알킬디티오인산염이 윤활유에 미치는 영향)

  • Moon Tak Jin;Kwon Oh Kwan
    • Journal of the Korean Chemical Society
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    • v.23 no.1
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    • pp.52-58
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    • 1979
  • Metallic dialkyldithiophosphates are widely used in lubricating oils as antioxidant and antiwear agents. Zinc DDTP are used most frequently in lubricating oil. Zinc, lead, tin and cobalt DDTP were prepared with primary and secondary alkyl groups. The effects of oxidation, thermal stability, metal corrosion and antiwear of each metallic DDTP prepared were studied. Based on the results, cobalt DDTP has a significant effect of antiwear on chrome alloy steel comparing with the other metallic DDTP. Also cobalt DDTP has a characteristic property of thermal sensitivity in its color, which was shown by the color change from brown to blue over a certain temperature. Another phenomenon obtained was that all metallic DDTP initiates the effect of antioxidation at the time of reaching to a certain effective acid concentration in lubricating oil.

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