• Title/Summary/Keyword: Coating agent

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Preparation and Properties of UV Curable Hard Coating Materials on PET (자외선 경화형 고경도 PET 필름의 제조 및 특성)

  • Kim, Hyunjoon
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.1
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    • pp.35-41
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    • 2014
  • UV curable transparent hard coating materials have been developed to improve the mechanical and optical properties of PET substrate. The coating materials were synthesized using various urethane acrylate oligomers, monomers, photo initiators, and leveling agents. The materials were coated on PET substrates and UV cured. The hard coated PET films were shown to have the good scratch resistance and transparency. When the urethane acrylate oligomer with more functional groups was introduced into the coating solution, the mechanical and optical properties were improved. However the higher concentration of 9-functional oligomer resulted in the decrease of workability. The addition of trimethylolpropane ethoxylate$(EO/OH)_9$ triacrylate(TMPETA) to coating solution improved the workability and properties. As a result, the UV cured film from the formulation of urethane acrylate oligomer with 9-functional groups, TMPETA as a monomer, IRACURE 754 as a photo initiator and BYK-340 as a leveling agent showed the best mechanical and optical properties in this study.

Development of Control Technology for Acid Mine Drainage by Coating on the Surface of Pyrite using Chemicals (산성광산배수의 발생저감을 위한 황철석 표면의 피막형성 기술개발)

  • Ji, Min-Kyu;Yoon, Hyun-Sik;Ji, Eung-Do;Lee, Woo-Ram;Park, Young-Tae;Yang, Jung-Seok;Jeon, Byong-Hun;Shim, Yon-Sik;Kang, Man-Hee;Choi, Jae-Young
    • Journal of Soil and Groundwater Environment
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    • v.15 no.4
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    • pp.46-52
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    • 2010
  • Acid mine drainage occurs when sulfide minerals are exposed to an oxidizing environment. The objective of this study was to inhibit the oxidation of pyrite by applying various coating agent such as $KH_2PO_4$, MgO and $KMnO_4$ over its surface as an oxidation inhibitors. Experiments were conducted for 8 days to test the feasibility of oxidation inhibitors. The optimal condition of coating agent for standard pyrite and IK mine was the combination of 0.01M $KH_2PO_4$, 0.01M NaOAc and 0.01M NaClO. Otherwise, for YD mine the combination of 0.01M $KMnO_4$, 0.01M NaOAc and 0.01M NaClO. The $SO_4^{2-}$ reduction efficiency of pyrite, IK and YD mine samples was 70, 92 and 84%, respectively. For 8 days, no significant increase of $SO_4^{2-}$ from pyrite sample coated with inhibitor was observed. The pH of solution remains in between 4 to 6 for the reaction conditions.

The Physical Properties of Polycarbonate Films Coated with Hard and Color Coating Materials (내마모성 색상코팅제를 코팅한 폴리카보네이트 필름의 물리적 특성)

  • Kim, Hyunjoon
    • Korean Chemical Engineering Research
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    • v.47 no.3
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    • pp.316-320
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    • 2009
  • UV curable hard and color coatings were formed on polycarbonate(PC) films. The coating materials were composed of a commercially available end-capped polyester(EB830), diacrylate monomer(HDDA), silicon acrylate, photoinitiator, and organic dye as a coloring agent. The surface properties of coating films were evaluated, and the influences of the compositions of coating materials were investigated. The coating films showed high transmission and good adhesion between coating layer and PC substrate. And the coating films exhibited higher hardness than bare PC film. The coating films with various colors were obtained by wet process, and the clear and color window lenses for mobile phone were prepared successfully.

Corrosion Behavior of TiN Ion Plated Steel Plate(I)-Effects of Ti interlayer and TiN coating thickness (TiN 이온 플레이팅한 강판의 내식성에 관한 연구(I)-Ti 하지 코팅 및 TiN 코팅 두께의 영향)

  • Yeon, Yun Mo;Han, Jeon Geon;Kim, Dae Jin;Bae, Eun Hyeon
    • Journal of the Korean institute of surface engineering
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    • v.24 no.1
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    • pp.34-34
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    • 1991
  • Corrosion behavior of TiN coated steel was studied in terms of thickness of interlayer Ti and TiN coating TiN was are ion plated to a thickness of 1$\mu\textrm{m}$ and 2$\mu\textrm{m}$ respectively with interlayer coating of Ti of 1$\mu\textrm{m}$, 2$\mu\textrm{m}$ and 3$\mu\textrm{m}$. Corrosion resistance of TiN coated steel was evaluated by anodic palarization test in 1N H2SO4 as well as salt spray test. Porosity of each coating was also tested by using SO2 test method. Corrosion current density decreased with increasing TiN coating thickness and Ti interlayer coating markedly enhanced the corrosion resistance. Ti interlayer coating of 2$\mu\textrm{m}$ and 3$\mu\textrm{m}$ prior to 2$\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 2. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ti interlayer. Ti interlayer coating was also very effective in improvement of corrosion resistance under salt atmosphere.

Corrosion Behavior of TiN Ion Plated Steel Plate(I) -Effects of Ti interlayer and TiN coating thickness- (TiN 이온 플레이팅한 강판의 내식성에 관한 연구(I) - Ti 하지 코팅 및 TiN 코팅 두께의 영향 -)

  • 연윤모;한전건;김대진;배은현
    • Journal of the Korean institute of surface engineering
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    • v.25 no.1
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    • pp.34-39
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    • 1992
  • Corrosion behavior of TiN coated steel was studied in terms of thickness of interlayer Ti and TiN coating. TiN was arc ion plated to a thickness of 1$\mu\textrm{m}$ and 2$\mu\textrm{m}$ respectively with interlayer coating of Ti of 1$\mu\textrm{m}$, $2\mu\textrm{m}$ and $3\mu\textrm{m}$. Corrosion resistance of TiN coated steel was evaluated by anodic palarization test in 1N $H_2$SO$_4$ as well as salt spray test. Porosity of each coating was also tested by using $SO_2$ test method. Corrosion current density decreased with increasing TiN coating thickness and Ti interlayer coating markedly enhanced the corrosion resistance. Ti interlayer coating of $2\mu\textrm{m}$ and $3\mu\textrm{m}$ prior to $2\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 2. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ti interlayer. Ti interlayer coating was also very effective in improvement of corrosion resistance under salt atmosphere.

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Corrosion Behavior of TiN Ion Plated Steel Plate(II)-Effects of Ni and Ni/Ti interlayers- (TiN 이온 플레이팅한 강판의 내식성에 관한 연구 (II)-Ni 및 Ni-Ti 하지코팅의 영향-)

  • 한전건;연윤모;홍준희
    • Journal of the Korean institute of surface engineering
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    • v.25 no.2
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    • pp.82-89
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    • 1992
  • The effect of interlayer coating of Ni and Ti on corrosion behavior was studied in TiN ion plated steel plate. Interlayer coating was carried out in a single and bi-layer to a various thickness combination prior to final TiN coating of $2\mu\textrm{m}$. Corrosion behavior was evaluated by anodic polarization test in 1N H2SO4 as well as salt spray test. Porosity of each coating was also tested by using SO2 test. Corrosion resistance was improved with increasing the thickness of Ni interlayer coating and Ni-Ti interlayer coating markedly enhanced the corrosion resistance. Ni/Ti interlayer coating of $2\mu\textrm{m}$/2$\mu\textrm{m}$ prior to $2\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 1. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ni and Ti interlayers, Ni/Ti interlayers coating were also very effective in improvement of corrosion resistance under salt atmosphere.

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Evaluation of Bond Strength in cp-Ti and Non-precious Metal-Ceramic System Using a Gold Bonding Agent (티타늄과 비귀금속 합금에 중간층으로 적용한 Au bonding agent의 금속-도재 결합에 대한 평가)

  • Lee, Jung-Hwan;Ahn, Jae-Seok
    • Journal of Technologic Dentistry
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    • v.31 no.4
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    • pp.15-23
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    • 2009
  • The aim of this study was to evaluate the bond strength of using a Au bonding agent applied on cp-Ti and nonprecious metal-gold-ceramic system. Metallic frameworks(diameter: 5mm, height: 20mm)(N=56, n=7per group) cast in Ni-Cr alloy, Co-Cr alloy and cp-Ti were obtained using acrylic templates and airborne particle abraded with $110{\mu}m$ aluminum oxide. Au bonding agent was applied on wash opaque firing as intermediate layer. SEM and SEM/EDS line profile were performed on the cutting the cross-section of the metal substrate-porcelain with intermediate Au coating. Groups were tested using shear bond strength(SBS) testing at 0.5mm/min. The mean SBS values for the ceramic-Au layer-metal combination were significantly higher than those ceramic-metal combination. While ceramic-Au layer-cp-Ti combinations failed to increase bond strength instead of using a titanium bonding porcelain. The appication of using Au intermediate layer significantly improve the bond strength combination with metal-ceramic system.

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Setting Time and Compressive Strength Gains of Glycocalix Coating Materials with Silica-based Accelerating Agents (실리케이트계 급결제를 혼입한 글라이코 캘릭스 코팅재의 응결시간 및 압축강도 발현 특성)

  • Jeong, Yun-Ji;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.105-111
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    • 2020
  • The present study examined the effect of the silica-based accelerating agents on the setting time and compressive strength gain of biomimetic glycocalix coating materials that has been developed for protecting the substrate of concrete exposed to chemical and microbiological attacks. The accelerating agent contents varied from 10mL/L to 40mL/L in the mixtures of glycocalix coating materials determined for shotcrete and lining techniques. Test results showed that the setting time of coating materials containing accelerating agents was affected by the contents of the bacteria carrier. When the accelerating agent content was 40mL/L, the final setting time was 80 minutes for shotcrete mixtures and 318 minutes for lining mixtures. Meanwhile, the compressive strength gain of coating materials with accelerating agents tended to be lower than that of counterpart materials without accelerating agents.

Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(II) - Application Methods of Chemicals for Improving Water and Moisture Resistance of Corrugated Boards - (농산물 저온유통용 내수 골판지 상자의 제조(제2보) - 골판지의 내수 및 내습성 향상을 위한 약품 적용 방법 -)

  • Jo, Jung-Yeon;Min, Choon-Ki;Shin, Jun-Seop
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2004.04a
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    • pp.192-210
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    • 2004
  • Application methods of chemicals were investigated tn minimize strength reduction of corrugated boards under the high humidity environment encountered in the cold chain system. Starch insolubilizers were introduced in the starch solution preparation of the Stain hall method and their insolubilization effect of starch binder were estimated. The performance of water repellent agents(WRA) and moisture proof agents(MPA) were evaluated in terms of water and moisture resistance. And effects of the combination of the chemicals and the coating method were also examined. Addition of the polyamine polyamide insolubilizer to the main part in the Stain hall process improved the binding force and water resistance of starch, which contributed to minimize the strength reduction of paper under the high humidity environment. AZC and Glyoxal type insolubilizers could not be used in the experiment due to an excessively increased viscosity of starch solution and the poor stability. Conventional WRA treatment to the base paper enhanced water and moisture resistance very slightly even though water repellency of the paper reached R10 by the treatment. MPA showed excellent performance than WRA not only in water and moisture resistance but in water repellency. Double coating on paper with MPA was more effective than the single coating at the same coating weight. A newly developed MPA showed excellent performance and runnability only by a single coating instead of a double coating.

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