• Nuclear Engineering and Technology
• /
• 제41권5호
• /
• pp.715-722
• /
• 2009

A model to predict failure of designed-to-fail (dtf) fuel particles is discussed. The dtf fuel under study consisted of a uranium oxycarbide kernel coated with a single pyrocarbon seal coat. Coating failure was assumed to be due to fission gas recoil and knockout mechanisms and direct diffusive release of fission gas from the kernel, which acted to increase pressure and stress in the pyrocarbon layer until it ruptured. Predictions of dtf fuel failure using General Atomics' particle fuel performance code for HRB-17/18 and HFR-B1 irradiation tests were reasonably accurate; however, the model could not predict the failure for COMEDIE BD-1. This was most likely due to insufficient information on reported particle fuel failure at the beginning.

• 한국세라믹학회지
• /
• 제47권6호
• /
• pp.590-597
• /
• 2010

HTGR using a TRISO coated particles as nuclear raw fuel material can be used to produce clean hydrogen gas and process heat for a next-generation energy source. For these purposes, a TRISO coated particle was prepared with 3 pyro-carbon (buffer, IPyC, and OPyC) layers and 1 silicone carbide (SiC) layer using a CVD technique on a spherical $UO_2$ kernel surface as a fissile material. In this study, a spherical $UO_2$ particle was prepared using a modified sol-gel method with a vibrating nozzle system, and TRISO coating fabrication was carried out using a fluidized bed reactor with coating gases, such as acetylene, propylene, and methyltrichlorosilane (MTS). As the results of this study, a spherical $UO_2$ kernel with a sphericity of 1+0.06 was obtained, and the main process parameters in the $UO_2$ kernel preparation were the well-formed nature of the spherical ADU liquid droplets and the suitable temperature control in the thermal treatment of intermediate compounds in the ADU, $UO_3$, and $UO_2$ conversions. Also, the important parameters for the TRISO coating procedure were the coating temperature and feed rate of the feeding gas in the PyC layer coating, the coating temperature, and the volume fraction of the reactant and inert gases in the SiC deposition.

• 한국추진공학회지
• /
• 제21권4호
• /
• pp.79-88
• /
• 2017

램젯 연소실 조건에서 점화보조제가 도포된 Fuel-rich 추진제의 점화 실험을 수행하여 점화 지연과 연소 유지를 확인하였다. 연료 그레인은 HTPB에 AP 파우더 15 wt.%, Al 파우더 5 wt.%가 혼합된 형태로 구성되어 있다. 한편 연료 그레인에 $NC/BKNO_3$와 Composite 추진제로 이루어진 점화보조제를 도포하여 빠른 점화지연이 나타나도록 하였다. 에탄올 블렌딩 과산화수소 가스발생기를 통해 램젯 연소실의 공기와 가깝도록 온도, 압력, 산소 조성을 조절한 산화제 가스를 유속 $200kg/m^2s$으로 공급하였다. 실험 결과, 점화보조제가 잘 작동하여 연료그레인에서 0.6초의 점화 지연시간을 파악하였고 연소 중에는 화염이 유지되는 것을 확인하였다.

• 한국세라믹학회지
• /
• 제44권3호
• /
• pp.169-174
• /
• 2007

TRISO coated fuel particle is one of the most important materials for hydrogen production using HTGR (high temperature gas cooled reactors). It is composed of three isotropic layers: inner pyrolytic carbon (IPyC), silicon carbide (SiC), outer pyrolytic carbon (OPyC) layers. In this study, TRISO coated fuel particle layers were deposited through CVD process in a horizontal hot wall deposition system. Also the computational simulations of input gas velocity, temperature profile and pressure in the reaction chamber were conducted with varying process variable (i.e temperature and input gas ratios). As deposition temperature increased, microstructure, chemical composition and growth behavior changed and deposition rate increased. The simulation showed that the change of reactant states affected growth rate at each position of the susceptor. The experimental results showed a close correlation with the simulation results.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2004년도 추계학술발표회 발표논문집
• /
• pp.947-948
• /
• 2004

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2005년도 춘계학술발표회
• /
• pp.441-442
• /
• 2005

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2005년도 추계학술발표회
• /
• pp.306-307
• /
• 2005

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2005년도 추계학술발표회
• /
• pp.249-251
• /
• 2005

• 한국세라믹학회지
• /
• 제44권7호
• /
• pp.368-374
• /
• 2007

CVD-SiC coating has been introduced as a protective layer in TRISO nuclear fuel particle of high temperature gas cooled reactor (HTGR) due to its excellent mechanical stability at high temperature. In order to prevent the failure of the TRISO particles, it is important to evaluate the fracture strength of the SiC coating layer. It is needed to develop a new simple characterization technique to evaluate the mechanical properties of the coating layer as a pre-irradiation step. In present work, direct strength measurement method with the specimen of hem i-spherical shell configuration was suggested. The indentation experiment on a hemisphere shell with a plate indenter was conducted. The fracture strength of the coating layer is related with the critical load for radial cracking of the shell. The finite element analysis was used to drive the semi-empirical equation for the strength measurement. The SiC hemispherical shells were successfully recovered from the section-grinding of TRISO coated particle and successive heat treatment in air. The strength of CVD-SiC coating layer was evaluated from the experimentally measured critical load during the indentation on SiC hemisphere shell. Weibull diagram of fracture strength was also constructed. This study suggested a new strength equation and experimental method to measure the fracture strength of CVD-SiC coating of TRISO coated fuel particles.

• 한국세라믹학회지
• /
• 제44권10호
• /
• pp.580-584
• /
• 2007

The ZrC layer instead of SiC layer is a critical and essential layer in TRISO coated fuel particles since it is a protective layer against diffusion of fission products and provides mechanical strength for the fuel particle. In this study, we carried out computational simulation before actual experiment. With these simulation results, Zirconium carbide (ZrC) films were chemically vapor deposited on $ZrO_2$ substrate using zirconium tetrachloride $(ZrCl_4),\;CH_4$ as a source and $H_2$ dilution gas, respectively. The change of input gas ratio was correlated with growth rate and morphology of deposited ZrC films. The growth rate of ZrC films increased as the input gas ratio decreased. The microstructure of ZrC films was changed with input gas ratio; small granular type grain structure was exhibited at the low input gas ratio. Angular type structure of increased grain size was observed at the high input gas ratio.