• Title/Summary/Keyword: Coal-ash

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CONTAMINANT LEACHABILITY FROM UTILIZED WASTES IN GEOSYSTEMS

  • Inyang Hilary I.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.10a
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    • pp.5-21
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    • 2005
  • Urbanization rates of population range from about 1% in the developed countries to about 4% in developing countries. For a global population that may reach 10 billion within the next 40 years, pressure has arisen for an increase in the large-scale use of wastes and byproducts in construction. Ironically, most of the wastes that need to be recycled are generated in large cities where the need for constructed facilities to serve large population is high. Waste and recycled materials (WRM) that are used in construction are required to satisfy material strength, durability and contaminant teachability requirements. These materials exhibit a wide variety of characteristics owing to the diversity of industrial processes through which they are produced. Several laboratory-based investigations have been conducted to assess the pollution potential and load bearing capacity of materials such as petroleum-contaminated soils, coal combustion ash, flue-gas desulphurization gypsum and foundry sand. For full-scale systems, although environmental pollution potential and structural integrity of constructed facilities that incorporate WRM are interrelated, comprehensive schemes have not been developed for integrated assessment of the relevant field-scale performance factors. In this presentation, a framework for such an assessment is proposed and presented in the form of a flowchart. The proposed scheme enables economic, environmental, worker safety and engineering factors to be addressed in a number of sequential steps. Quantitative methods and test protocols that have been developed can be incorporated into the proposed scheme for assessing the feasibility of using WRM as partial or full substitutes for earthen highway materials in the field.

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Study on the Suppression of Sulfur Trioxide in High Sulfur Boiler (고유황 보일러에서의 Sulfur Trioxide의 억제에 대한 연구)

  • Choi, Sung-Bu
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.455-463
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    • 2011
  • The average sulfur content of crude oil is 2.2%. Coal is about 0.3 to 4.0 percent of the sulfur gases or particles being discharged into the atmosphere through the chimney as 1 to 2% $SO_3$(Sulfur trioxide) and about 95% of the $SO_2$ is reported. $SO_3$ gas, which has many different causes of, as the combustion of sulfur containing fuel during the air due to the excess $SO_2$ gas is oxidized to $SO_3$ gas. Sulfur trioxide emitted from high sulfur heavy oil fired boiler caused white plume in stack and high temperature and cold end corrosion of facilities. So, in order to control sulfur trioxide concentration of Fuel gas in boiler, various of additives are used in other foreign. They are injected to Fuel Oil and consumed in boiler and reduce ash and the conversion rate of sulfur trioxide. In domestic, MgO compounds are used as additives but the total volume of them are made from other foreign company. In this study, MgO compounds were developed with liquid MgO compounds and field application was accomplished. The effect of newly developed chemicals and process were nearly equal to foreign products. In Consequent, the chemicals and process produced by newly developed technology can be substituted for foreign products and reduce the cost of plant operation.

The Effect of Silicious Raw Materials on Mineralogical Properties in Clinkering Process. (규산질 원료의 성상이 클링커 소결 반응에 미치는 영향)

  • 박병철;임응극;정수진;서능일
    • Journal of the Korean Ceramic Society
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    • v.18 no.4
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    • pp.219-228
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    • 1981
  • To clarify influences of silicious raw materials on mineralogcal and petrological properties in clinkering process clay, shale, quartzite, sand and coal ash have been used as silicious raw materials. The tests on thermal properties, reactivity and burnability of raw mixtures which have different silicious raw materials respectively have been made by means of X-ray diffractometry, differential thermal analysis, optical microscopy and transmission electron microscopy. Limestone contains coarse crystalline grains which show 0.1-1.0mm and its decarbonation temperature is 86$0^{\circ}C$. Reaction temperatures among raw mixtures have been determined by X-ray diffractometry and their results are as follows; clay minerals under 1, 00$0^{\circ}C$, mica group, 100$0^{\circ}C$-110$0^{\circ}C$, feldspar group, 1, 10$0^{\circ}C$-1, 20$0^{\circ}C$ and quartz 1, 20$0^{\circ}C$-1, 30$0^{\circ}C$. Burnabilities of raw mixtures of different temperatures have been found that they mainly depend upon their mineral contents in silicious raw materials and their order is as follows; $clay\geq shale\gg quartzite \geq sand$.

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Porous Alumina/Mullite Layered Composites with Unidirectional Pore Channels and Improved Compressive Strength (일축배향 기공채널과 향상된 압축강도를 갖는 다공질 알루미나/뮬라이트 층상 복합체)

  • Kim, Kyu Heon;Kim, Tae Rim;Kim, Dong Hyun;Yoon, Seog Young;Park, Hong Chae
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.19-24
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    • 2014
  • Three-layer porous alumina-mullite composites with a symmetric gradient porosity are prepared using a controlled freeze/gel-casting method. In this work, tertiary-butyl alcohol (TBA) and coal fly ash with an appropriate addition of $Al_2O_3$ were used as the freezing vehicle and the starting material, respectively. When sintered at $1300-1500^{\circ}C$, unidirectional macro-pore channels aligned regularly along the growth direction of solid TBA were developed. Simultaneously, the pore channels were surrounded by less porous structured walls. A high degree of solid loading resulted in low porosity and a small pore size, leading to higher compressive strength. The sintered porous layered composite exhibited improved compressive strength with a slight decrease in its porosity. After sintering at $1500^{\circ}C$, the layered composite consisting of outer layers with a 50 wt% solid loading showed the highest compressive strength ($90.8{\pm}3.7MPa$) with porosity of approximately 26.4%.

A Study on Combustion Characteristics of Pulverized Fuel Made from Food Waste (음식물쓰레기로 부터 제조한 분체연료 연소특성)

  • Son, Hyun-Suk;Park, Yung-Sung;Kim, Sang-Guk
    • New & Renewable Energy
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    • v.4 no.4
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    • pp.37-43
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    • 2008
  • Three properties of food waste are water 80%, ash 3%, volatile matter 17%. When food waste goes through treatment process such as removal of foreign substances, removal of water as well as sodium, dryness, and pulverization, it transforms into 4,000 Kcal/kg purverized fuel if moisture content is below 13%. Fuel ratio (fixed carbon/volatile matter) of purverized fuel is low compared with bituminuous coal. Ignition temperature measured by thermogravimetry analyzer is about $460^{\circ}C$. Combustion test of purverized fuel have been performed using energy recovery facility which include storage tank of dewatered cake, dryer, hammer mill, combuster including burner, boiler, flue gas treatment equipment. When 160-180 kg/hr of fuel is steadily supplied to burner for 3 hours, combustor temperature reaches about $1000^{\circ}C$ and CO is 77-103 ppm at 1.55 excess air ratio and SOx and Cl are under 2 ppm and 1ppm, respectively. This experiment demonstrate that purverized fuel made from food waste could be an alternative clean energy at the age of high oil price.

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A Study on Combustion Characteristics of Purverized Fuel Made from Food Waste (음식물쓰레기로부터 제조한 분체연료 연소특성)

  • Son, Hyun-Suk;Park, Yung-Sung;Yun, Jong-Deuk;Lee, Ho-Nam;Lee, Seung-Hoon;Kim, Sang-Guk
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.149-152
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    • 2008
  • Three properties of food waste are water 80%, ash 3%, volatile matter 17%. When food waste goes through treatment process such as removal of foreign substances, removal of water as well as sodium, dryness, and pulverization, it transforms into 4,000Kcal/kg purverized fuel if moisture content is below 13%. Fuel ratio(fixed carbon/volatile matter) of purverized fuel is low compared with bituminuous coal. Ignition temperature measured by thermogravimetry analyzer is about $460^{\circ}C$. Combustion test of purverized fuel have been performed using energy recovery facility which include storage tank of dewatered cake, dryer, hammer mill, combuster including burner, boiler, flue gas treatment equipment. When 160-180 kg/hr of fuel is steadily supplied to burner for 3 hours, combueter temperature reaches about $1000^{\circ}C$ and CO is 77-103ppm at 1.55 excess air ratio and SOx and Cl are under 2ppm and 1ppm, respectively. This experiment demonstrate that purverized fuel made from food waste could be an alternative clean energy for high oil price era

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Treatment of Industrial Wastes by Melting Using H.F. Induction Furnace (고주파 유도로를 이용한 산업 폐기물의 용융처리)

  • 정진기;정헌생;이재천;윤인주;남기대
    • Resources Recycling
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    • v.6 no.1
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    • pp.23-28
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    • 1997
  • Iron and slag were prepared by melting mixed industrial wastes in an induction furnace. The wastes were steel can, limestone sludge, waste foundry sand, coal fly ash, and glasses. The effects of their mixing ratio on the charactenstics of the meltcd slag were investigated. The wastes were melted to slag under the constant basicity of 1.2. It was found that the major phases of the slag were P-C,S and C,AS and then ratio was determined by the mixing ratio af waste materials. The recovery of iron was about 93-95%. The feasibility of using the slag as the aggregate was confirmed by thc elution and campression tests.

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Reliability Evaluation of Accelerated Carbonation Results According to Carbon Dioxide Concentration (이산화탄소 농도에 따른 촉진 탄산화 결과의 신뢰도 평가)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.166-167
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    • 2022
  • The International Energy Agency(IEA) recommends that intergovernmental agreements reduce CO2 emissions by 2050 to about 50% in 2005 in its report. To realize these demands, it is suggested to actively utilize energy efficiency improvement technology, renewable energy, nuclear power, carbon dioxide capture & storage technology (CCS). In the field of building materials and cement, mineral carbonization technology is widely used. Inorganic by-products applicable to greenhouse gas storage include waste concrete, slag, coal ash, and gypsum. If the Mineral Carbonation Act is used, it is expected that about 12 million tons of greenhouse gases can be immobilized every year. Greenhouse gas immobilization using cement hydrate can be immobilized by injecting carbon dioxide into the hydrated products C-S-H, and Ca(OH)2. In the case of immobilization through concrete carbonization, a carbon dioxide promotion test is used, which is often different from the actual carbon dioxide carbonization reaction. If the external carbon dioxide concentration is abnormally higher than the reality, it is thought that it will be different from the actual reaction. In this study, the carbonation phenomenon according to the concentration and identification of the carbon dioxide reaction mechanism of cement hydrate was to be considered.

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Properties and Applicability Evaluation of Control Low Strength Materials Used Industrial by-Products of A Great Quantity (다량의 산업부산물을 활용한 슬러리계 되메움 재료의 물성 및 현장적용 가능성 평가)

  • Liao, Xiaokai;Her, Jae-Won;Kim, Dong-Hun;Lim, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.40-41
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    • 2020
  • This study has resulted in the following findings. First, Using more than 30% of GBFS to replace FA enabled bleeding control through improved fluidity. Moreover, it has been confirmed that effective strength and proper quality can be achieved when it was applied as a backfilling material with higher early strength than the base material. Second, When using more than 30% of FNS to replace sand, it was found that adding 0.3~0.35 of the AE agent is effective for bleeding control through improved fluidity. Third, When using more than 30% of both GBFS and FNS in combination, it was found that adding 0.3~0.35 of the AE agent is effective for bleeding control through improved fluidity. Also, it was confirmed that proper mixing of 15~60% of GF secured the effective strength and desired quality as a refiller and joint filler material.

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Evaluation of Field Applicability of Controlled Low Strength Materials as Cavity Filling Materials Various Industrial by Products (공동충전재로써 산업부산물을 복합적으로 활용한 슬러리계 되메움의 현장적용성 평가)

  • Liao, XiaoKai;Kim, Dong-Hun;Lim, Nam Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.72-73
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    • 2021
  • In this study, the engineering characteristics of CLSM mixed with GBFS and GF were identified to review the applicability as a replacement material and further evaluate the recharge and field applicability as a joint filler material. First, Using more than 30% of GBFS to replace FA enabled bleeding control through improved fluidity. Second, When using more than 30% of FNS to replace sand, it was found that adding 0.25~0.35 of the AE agent is effective for bleeding control through improved fluidity. Third, When using more than 30% of both GBFS and FNS in combination, it was found that adding 0.3~0.35 of the AE agent is effective for bleeding control through improved fluidity. Also, it was confirmed that proper mixing of 15~60% of GF secured the effective strength and desired quality as a refiller and joint filler material.

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