• Proceedings of the Korean Society of Medical Physics Conference
• /
• 2002.09a
• /
• pp.501-505
• /
• 2002

The specific radioactivity concentrations of $\^$238/U, $\^$232/Th, $\^$40/K were measured in soil samples around Zuunmod town of Mongolia using HP-Ge gamma-spectrometer. Also the specific radioactivity concentrations of above elements were measured in coal and ash samples which were collected from the Central steam heating in Zuunmod town. It was determined the effective equivalent dose.

• Journal of the Korean Society of Combustion
• /
• v.22 no.4
• /
• pp.35-42
• /
• 2017

This case covers the issues related to the operation problem, cause analysis and improvement cases of the FGD that employed the non-leakage type GGH in coal-fired power plant for the first time in Korea. In the Cooler, there was a main problem that the tube is damaged by the ash cutting due to the high velocity of flue gas in the duct and by the weak wear resistance of material. In the Reheater, there was a main problem that the tube was corroded due to chlorine and sulfur in the circumstance of the low temperature. In order to solve those problems, we have improved the Reheater tube and tube fins by coating enamel to reduce corrosion rate.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.4 no.4
• /
• pp.349-355
• /
• 2016

This study is about the reuse of bottom ash, which is released as a necessity in thermal power plant. In general, coal-ash are classified as fly-ash, bottom-ash, cinder-ash. Of these, a large amount of fly ash is being recycled as cement substitutes. While, recycling rates of bottom ash are the lowest due to its porosity and high absorption. In this study, the durability of the concrete using bottom ash as a concrete fine aggregate was evaluated. The using level of the bottom ash ranges to step-by-step from 0% to 30%. According to the result of the durability test, regardless of the presence of the bottom ash, freeze-thaw durability could be secured by air entrainment. In case of the resistance to chloride ions penetration, the length change, and the effects on heavy metals, the replacement of bottom ash as fine aggregate was not critical. Although carbonation penetration was higher as the replacement level of bottom ash increased, the experiment showed that it could be possible to use bottom ash as concrete fine aggregate with proper mix design.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.35 no.10
• /
• pp.997-1003
• /
• 2011

In order to investigate devolatilization characteristics for ashless coal with relatively low ash content and high heating value, an experiment was performed in different bed configurations of TGA and DTF(Drop Tube Furnace) at atmospheric pressure condition. The heating rate was $10^{\circ}C$/min up to $950^{\circ}C$ in TGA, while the temperatures of DTF varied from 500 to $1300^{\circ}C$ in step of $200^{\circ}C$. A weight loss and particle temperature were obtained to determine devolatilization kinetics. The kinetic parameters including an activation energy and pre-exponential factor for ashless coal were obtained using Coats-Redfern method in TGA and single step method in DTF. Furthermore, the devolatilization kinetics of the ashless coal were compared with the results of different kinds of conventional coal such as sub-bituminous and bituminous. The results show that the activation energy of devolatilazation for ashless coal is lower than those of others in fixed and entrained conditions.

• Journal of the Korean GEO-environmental Society
• /
• v.11 no.1
• /
• pp.19-26
• /
• 2010

The batch experiments and response surface methodology (RSM) have been applied to the investigation of the cadmium (Cd) adsorption by coal fly ash (CFA). CFA having maximum Cd removal mass of 8.51 mg/g were calculated from Langmuir model. Cd removal reaction with different initial pH ranged from 4 to 9. When the initial pH was higher, Cd was removed more by adsorption and precipitation. These results suggest that the lower pH cause an increase of $H^+$ ion concentration which competed with Cd ions for exchange sites in CFA. Also, The Cd adsorption was mathematically described as a function of parameters initial Cd concentration ($X_1$), initial pH ($X_2$), and initial CFA mass ($X_3$) being modeled by use of the Box-Behnken methods. Empirical models were developed to describe relationship between the experimental variables and response. Statistical analysis indicates that tree factors ($X_1$, $X_2$, and $X_3$) on the linear term (main effects), and tree factors ($X_1X_2$, $X_1X_3$, and $X_2X_3$) on the non-linear term (Interaction effect; cross-product) had significant effects, respectively. In this case, the value of the adjusted determination coefficient (adjusted $R^2=0.9280$) was closed to 1, showing a high significance of the model. Statistical results showed the order of Cd removal at experimental factors to be initial initial pH > initial Cd concentration > initial CFA mass.

• Korean Journal of Soil Science and Fertilizer
• /
• v.47 no.6
• /
• pp.406-411
• /
• 2014

Serious problems in reclaimed land agriculture are high soil salinity and poor vertical drainage, so desalinization in these soils is very difficult. Also, although desalinization is accomplished in reclaimed top soils, before long, soils are resalinized according to capillary rise of salts from the subsurface soils. To resolve these problems, multi-layered soil columns with subsurface layer of macroporous medium utilizing coal bottom ash (CBA) were constructed and the effects of blocked resalinization of these soils were investigated. In this experiment soil samples were collected from Munpo series (coarse-loamy, nonacid, mixed, mesic, typic Fluvaquents). The soil texture was silt loam and the EC was $33.9dS\;m^{-1}$. As for groundwater seawater was used and groundwater level of 1 cm from the bottom was maintained. The overall rate of capillary rise was $2.38cm\;hr^{-1}$ in soil 60 cm column, $0.25cm\;hr^{-1}$ in topsoil (30 cm) + CBA (5 cm) + subsurface soil (10 cm) column and $0.08cm\;hr^{-1}$ in topsoil (30 cm) + CBA (10 cm) + subsurface soil (10 cm) column. In multi-layered soil columns with CBA 20, 30 cm layer, wetting front due to capillary rise could not be seen in top soil layer. After 70 days capillary rise experiment water soluble Na+ accumulated in top soil of soil columns with CBA 20, 30 cm was diminished by 92.8, 96.5% respectively in comparison with Na+ accumulated in top soil of soil 60 cm column because CBA layer cut off capillary rise of salts from the subsurface soil. From these results we could conclude that the macroporous layer utilizing CBA placed at subsurface layer cut off capillary rise of solutes from subsurface soil, resulting in lowered level of salinity in top soil and this method can be more effective in newly reclaimed saline soil.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.32 no.1C
• /
• pp.17-25
• /
• 2012

CLSM (Controlled Low Strength Material) using coal ash, which has the advantages of self-leveling, self-compacting, flowability, easy re-excavation, has been developed. In this study, CLSM additionally mixed with foaming agent for structural backfill material, aimed at lightness of materials, was developed called light-weight foamed CLSM. As the basic study of this material, to determine the optimum final mixing time and dilution ratio of existing light-weight foamed CLSM, flow, slurry unit weight and unconfined compressive strength test according to each impact factor were performed at the standard mix proportion. As the results of tests, CASE N (Final mixing time 4 min, dilution ratio 2%), CASE O (Final mixing time 3 min, foam agents ratio 3%, dilution ratio 2%) were satisfied with the standard of flow test (above 20cm), slurry unit weight test (12~15 $kN/m^3$) and unconfined compressive strength test (800 kPa~1200 kPa). These results will indicate the standard optimum final mixing time and dilution ratio of light-weight foamed CLSM for structural backfill.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.21 no.1
• /
• pp.41-46
• /
• 2011

The artificial aggregates (AAs) composing of 2 wastes, coal bottom ash and dredged soil (7 : 3, weight ratio) were fabricated as a function of red mud contents,0~30 wt% using direct sintering method at $1050{\sim}1250^{\circ}C$ for 10 min, and those physical properties were evaluated. Especially, in order to analyze the red mud addition effect on the bloating phenomenon of AAs manufactured, the specific gravity and water absorption were measured and studied linked with the microstructural observation results. The lightening of AAs was enhanced due to increased bloating with increasing temperature and red mud contents. The AAS sintered at $1050{\sim}1150^{\circ}C$ showed well-developed black-coring structure, but for the specimens containing red mud sintered over $1200^{\circ}C$ generated excessive liquid and gas caused by reduction of $Fe_2O_3$, thus the black-coring part was gradually burst open out of shell of AAs. Particularly, all specimens containing 30 wt% red mud was burst up when sintered over $1100^{\circ}C$. The AAs containing no red mud sintered at $1200^{\circ}C$ had a specific gravity of about 1.2 and those containing 20 wt% had below 1.0 which are characters of lightweight aggregate.

• Journal of the Korean Ceramic Society
• /
• v.40 no.7
• /
• pp.677-682
• /
• 2003

The physical properties of sintered body made from 3 kinds of slip, F (Flocculated), M (Moderate), and D (Dispersed) for coal fly ash 70-clay 30 (wt%) were studied in terms of slip states and pore size distribution of sintered bodies. The floc particle size distribution for slip F was wider than slip D and the slip F contained flocs larger than 11 $\mu\textrm{m}$. The pore size distribution of the green body of all slips ranged over 1∼4 $\mu\textrm{m}$. The pores smaller than 1 $\mu\textrm{m}$ almost disappeared during the sintering process, while the larger pore of 2.5∼3 $\mu\textrm{m}$ growed by 1 $\mu\textrm{m}$. The pore distribution for the green body of slip F became a narrow in width and high in height after sintering and the large pore limit in a slip F sintered body was 5.1 $\mu\textrm{m}$ which is smaller than that of other slip. The slip F rather flocculated was favorable over slip D well dispersed, in offering a higher compressive strength. From these results, the mechanical strength of sintered body is dependent on the pore distribution which could be controlled by dispersion state of the slips.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.20 no.1
• /
• pp.58-63
• /
• 2010

The glass-ceramics made from the mixture of coal bottom ash, produced from a thermal power plant mixed with $Na_2O$ and $Li_2O$ was fabricated and their crystallization behavior was studied using a non-isothermal analyzing method. The temperature for 50% crystallization was higher than the exothermic peak temperature $T_p$ at DTA curve and the quickest crystallization temperature was much the same as $T_p$ as identified from the relationships of crystallized fraction and crystallization rate with temperature. By using Kissinger equation describing a crystallization behavior, the activation energy (262 kJ/mol), the Avrami constant (1.7) and the frequency ($5.7{\times}10^{16}/s$) for crystallization were calculated from which the nepheline crystal could be expected as showing an 1~2-dimensional surface crystallization behavior mainly with some bulk crystallization tendency at the same time. The actual observation of microstructure using SEM showed the considerable amount of surface crystals of dendrite and the bulk crystals with low fraction, so the prediction by the Kissinger equation was in accord with the crystallization behavior of glass-ceramics fabricated in this study.