• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.124-124
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• 2018

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.3
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• pp.108-117
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• 2013

Among the byproducts from thermal power plant using coal combustion, fly ash as mineral admixture is widely utilized in concrete manufacturing for its engineering merits. However residuals including bottom ash are usually reclaimed. This study presents an evaluation of engineering properties in cement mortar with pond ash (PA). For this work, two types of pond ash (anthracite and bituminous coal) are selected from two reclamation sites. Cement mortar specimens considering two w/c (0.385 and 0.485) ratios and three replacement ratio of sand (0%, 30%, and 60%) are prepared and their workability, mechanical, and durability performance are evaluated. Anthracite pond ash has high absorption and smooth surface so that it shows reasonable workability, strength development, and durability performance since it has dense pore structure due to smooth surface and sufficient mixing water inside. Reuse of PA is expected to be feasible since PA cement mortar has reasonable engineering performance compared with normal cement mortar.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.1
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• pp.39-45
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• 2018

Research on FA(Fly ash) is actively carried out, while the research on BA(Bottom ash) is not so, and research on BA recycling field is urgently required. Therefore, in this study, we investigated the lightweight and thermal insulation characteristics of BA mortar by comparing BA mortar made with porous dry BA(air-cooled) and general mortar. To investigate the lightweight of BA, density test, unit volume mass test and SEM(Scanning Electron Microscope) test were performed. BA mortar and general mortar molds were prepared for the thermal insulation test at room temperature and humidity environment determined by KS A 0006 and they were dried at the temperature of $105{\pm}2^{\circ}C$ until the weight became constant. As a result of the lightweight test, the lightweight of BA mortar is about 30% lighter than the general mortar. Therefore, BA is expected to contribute to reduce the building load when used as building material. As a result of thermal insulation test, the thermal conductivity of BA mortar is about 30% better than that of general mortar.

• Journal of computational fluids engineering
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• v.16 no.2
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• pp.66-74
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• 2011

The SCR catalyst in coal-fired power plant is eroded by the collision of fly ash on the catalyst surface. However the erosion of SCR catalyst by the collision of fly ash has not been fully studied, especially in terms of fluid dynamics. Hence, in the present study, we focus on the gas and solid flows inside the SCR catalyst duct and their consequent effect on the erosion characteristics. For this purpose, computational fluid dynamics is applied to investigate the two-phase flows and to evaluate the erosion rate for different flow and particle injection conditions. Also, the erosion rate and pressure drop of commonly used square shape are compared with equilateral triangle and hexagon shapes. The pressure drop of SCR catalyst is increased when SCR catalyst surface area per unit volume increases. The erosion rate of SCR catalyst is enhanced when the particle velocity, mass flow rate of particle, particle diameter and cell density of SCR catalyst are increased. From the results, the pressure drop and erosion rate at the catalyst surface can be minimized by reducing cell density of SCR catalyst to decrease particle velocity and number of particle impacts.

• Computers and Concrete
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• v.31 no.4
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• pp.327-335
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• 2023

The most popular building material, concrete, is intrinsically linked to the advancement of humanity. Due to the ever-increasing complexity of cementitious systems, concrete formulation for desired qualities remains a difficult undertaking despite conceptual and methodological advancement in the field of concrete science. Recognising the significant pollution caused by the traditional cement industry, construction of civil engineering structures has been carried out successfully using Geopolymer Concrete (GPC), also known as High Performance Concrete (HPC). These are concretes formed by the reaction of inorganic materials with a high content of Silicon and Aluminium (Pozzolans) with alkalis to achieve cementitious properties. These supplementary cementitious materials include Ground Granulated Blast Furnace Slag (GGBFS), a waste material generated in the steel manufacturing industry; Fly Ash, which is a fine waste product produced by coal-fired power stations and Silica Fume, a by-product of producing silicon metal or ferrosilicon alloys. This result demonstrated that GPC/HPC can be utilised as a substitute for traditional Portland cement-based concrete, resulting in improvements in concrete properties in addition to environmental and economic benefits. This study explores utilising experimental data to train artificial neural networks, which are then used to determine the effect of supplementary cementitious material replacement, namely fly ash, Ground Granulated Blast Furnace Slag (GGBFS) and silica fume, on the compressive strength, tensile strength, and modulus of elasticity of concrete and to predict these values accordingly.

• Membrane and Water Treatment
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• v.11 no.3
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• pp.195-200
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• 2020

In this study, a biocatalyst composite was prepared by immobilizing oxidoreductases onto Cu-activated zeolite to facilitate biochemical decomposition of 4-chlorophenol (4-CP). 4-CP monooxygenase (CphC-I) was cloned from a 4-CP degrading bacterium, Pseudarthrobacter chlorophenolicus A6, and then overexpressed and purified. Type X zeolite was synthesized from non-magnetic coal fly ash using acetic acid treatment, and its surfaces were coated with copper ions via impregnation (Cu-zeolite). Then, the recombinant oxidative and reductive enzymes were immobilized onto Cu-zeolite. The enzymes were effectively immobilized onto the Cu-zeolite (79% of immobilization yield). The retained catalytic activity of CphC-I after immobilization was 0.3423 U/g-Cu-zeolite, which was 63.3% of the value of free enzymes. The results of this study suggest that copper can be used as an effective enzyme immobilization binder because it provides favorable metalhistidine binding between the enzyme and Cu-zeolite.

• Journal of environmental and Sanitary engineering
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• v.14 no.3
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• pp.63-70
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• 1999

A study on the zeolite synthesized of bituminous coal fly ash from power plant has been carried out to reuse industrial waste. The synthesized zeolite was proved to be 4A type by means of the X-ray diffraction analysis and the degree of crystallinity was found to be higher than 90%. Then the synthesized zeolite was used as an adsorbent to remove the heavy metal ions in the CU, Pb, and Cd containing wastewater and water. Also, adsorption characteristics and kinetics of synthesized zeolite in the each metal ion solutions were studied. In each ion solutions, the adsorbed amounts of Pb, Cd, and Cu to the unit weight of synthesized zeolite were 141.6, 118.8, and 131.4mg/g respectively when each metal ion concentration was 500mg/L solution. The adsorption kinetics was fitted well to the Freundlich isotherms. The value of l/n for Pb, Cd, and Cu and 0.27, 0.50, and 0.66, respectively. Those results showed that the synthesized zeolite could be used as an adsorbent to remove single heavy metal ions in the wastewater and water. The heats of adsorption, H values of Pb, Cd, and Cu were 4.87, 14.95, and 18.23kacl/mol by the Henry-van't Hoff equation.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.7-10
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• 2001

Adsorption of the pesticides (phosphamidon, fenitrothion, triadimefon and diniconazole) in natural zeolite (CL $I_{N}$) and several synthetic zeolites was incestigated. The pesticides were not adsorbed on zeolites (Na-Pl, SOD, ANA, JBW and CAN) synthesized from Jeju scoria. The distribution coefficient ( $K_{D}$) and the Freundlich constant ( $K_{F}$) decreased in the following sequences. FC $C_{W}$ (waste catalytic cracking catalyst)>FA $U_{F}$ (FAU Synthesized from coal fly ash)>(FAU+Na-Pl)$_{SF}$ (the mixture of FAU and Na-Pl synthesized from the ratio of Jeju scoria 6 to coal fly ash 4 by weight)>CL $I_{N}$ among the zeolites; diniconazole>fenitrothion> triadimefon>phosphamidon. As the temperature was increased, the amount of pesticide adsorbed per unit mass of zeolite increased for FC $C_{W}$, FA $U_{F}$ and (FAU+Na-Pl)$_{SF}$ but it decreased for CL $I_{N}$, for all the pesticides used in this study. It was independent of pH for phosphamidon, fenitrothion and triadimefon, but decresed as pH was increased for all the zeolites used in this study.y.udy.y.y.y.y.y.y.

• Korean Journal of Materials Research
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• v.21 no.9
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• pp.502-508
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• 2011

The goal of the present work was to investigate the development of a geopolymeric ceramic material from a mixture of mine residue, coal fly ash, blast furnace slag, and alkali activator solution by the geopolymer technique. The results showed that the higher compressive strength of geopolymeric ceramic material increased with an increase in active filler (blast furnace slag + coal fly ash) contents and with a reduction of mine residue contents. The geopolymeric ceramic had very high early age strength. The compressive strength of the geopolymeric ceramic depended on the added active filler content. The maximum compressive strength of the geopolymeric ceramic containing 20 wt.% mine residue was 141.2 MPa. The compressive strength of geopolymeric ceramic manufactured by adding mine residue was higher than that of portland cement mortar, which is 60 MPa, when cured for 28 days. SEM observation showed the possibility of having amorphous aluminosilicate gel within geopolymeric ceramic. XRD patterns indicate that the geopolymeric ceramic was composed of amorphous aluminosilicate, calcite, quartz, and muscovite. The Korea Standard Leaching Test (KSLT) was used to determine the leaching potential of the geopolymeric ceramic. The amounts of heavy metals were noticeably reduced after the solidification of mine residue with active filler.

• Geomechanics and Engineering
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• v.24 no.1
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• pp.81-89
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• 2021

Uniaxial compression tests were conducted on sandstone-CGFB composite samples with different interface angles, and their strength, acoustic emission (AE), and failure characteristics were investigated. Three macro-failure patterns were identified: the splitting failure accompanied by local spalling failure in CGFB (Type-I), the mixed failure with small sliding failure along with the interface and Type-I failure (Type-II), and the sliding failure along with the interface (Type-III). With an increase of interface angle β measured horizontally, the macro-failure pattern changed from Type-I to Type-II, and then to Type-III, and the uniaxial compressive strength and elastic modulus generally decreased. Due to the small sliding failure along with the interface in the composite sample with β of 45°, AE events underwent fluctuations in peak values at the later post-peak failure stage. The composite samples with β of 60° occurred Type-III failure before the completion of initial compaction stage, and the post-peak stress-time curve initially exhibited a slow decrease, followed by a steep linear drop with peaks in AE events.