• 한국염색가공학회지
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• 제17권2호
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• pp.31-39
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• 2005

This study was conducted to remove the dyes in dye wastewater by the chemical precipitation or biological treatment which are one of the main pollutants in dye wastewater. In order to remove the disperse dyes effectively in aqueous solution by chemical precipitation process, coagulation and flocculation tests were carried out using several coagulants on various reaction conditions. It was found that the Ferrous sulfate was the most effective coagulant for the removal of disperse dye(DB79), and we could get the best result for the removal of disperse dye(DB56) in the aspects of TOC removal efficiency and sludge yield. When the Ferrous sulfate dosage was 800mg/l, the sludge settling velocity was very fast$(SV_{30}=4\%)$, and the color was effectively removed in the disperse dye(DB79) solution. Although the color removal was ineffective when the Alum was used as a coagulant, the sludge yield decreased in comparison with the Ferrous sulfate or the Ferric sulfate being used in the disperse dye(DB56) solution. In order to decolorize disperse dye(DR17) by using biological treatment process, a strain which has potential ability to degrade disperse dyes was isolated from natural system. The optimal culture conditions of temperature and pH were found to be $40^{\circ}C\;and\;8.5\~9$, respectively. When yeast extract was mixed with polypeptone at the mixing ratio of 1:1 as a nitrogen source, decolorization efficiency was highest$(93\%)$ among the nitrogen sources. The strain screened was excellent to adjust to pH, and it seems to have ability to control pH needed to growth. The optimal culture conditions in concentration of $MgSO_{4.}\cdot7H_2O\;and\;KH_2PO_4$ were $0.1\%(w/v)\;and\;0.2\%(w/v)$, respectively. Strains degrading and decolorizing reactive dyes, RB198 and RR141 which were isolated from water system, are named RBK1 and RRK. And the cell growth characteristics of RBK1 and RRK were investigated. The optimal culture conditions of temperature and pH were found to be 30t' and 7.0, respectively. Optimum nitrogen source was peptone, and it was found that decolorization efficiencies by strains RBK1 and RRK, were $85\%\;and\;62\%$, respectively, with introduction of 4,000mg/l of peptone. In the case of RBK1, color removal efficiencies were very high below 400mg/l. Decolorization efficiency was over $90\%$ at 20hours of culture time. The Color degradation ability of RRK was lower than that of RBK1.

• 한국물환경학회지
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• 제28권4호
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• pp.608-614
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• 2012

The effluent limitation of industrial wastewater is based on uniform regulatory criteria for effluent discharge facilities of all in Korea. But, an individual effluent limitation on each effluent discharge facility is widely applicable for regulation of industrial wastewater in US.EPA. To decide an individual effluent limitation, TBEL (Technology-based effluent limitation) and WQBEL (Water quality-based effluent limitation) are used. TBEL is based on the capability of a treatment technology to reduce the pollutants. WQBEL is based on ambient water quality standards. In this study, TBEL were derived for the pulp, paper and paper board manufacturing based on best practicable control technology currently available. It was suggested that effluent limitations were $BOD_5$ 4.7 mg/L, $COD_{Mn}$ 44.3 mg/L, SS 13.2 mg/L, TN 1.4 mg/L, TP 0.15 mg/L and best practicable control technology currently available (BPT) was neutralization, activated sludge treatment and coagulation and sedimentation for the pulp, paper and paper board manufacturing.

• 대한환경공학회지
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• 제22권10호
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• pp.1799-1808
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• 2000

본 연구에서는 구입이 용이한 황토를 이용하여 축산폐수외 화학적 응집 처리제로서의 적용가능성과 최적 응집조건을 찾고 기존에 사용되어 왔던 고분자 응집제(PAC, PACS, LAS)와 응집성능을 비교하였다. 연구 결과 황토와 생석회의 최적 혼합비율은 3:7이었으며, 이 혼합 응집제의 적정 주입량은 30 g/L이었다. 기존 응집제와 비교실험에서는 loess : lime = 3 : 7의 경우 탁도, SS, BOD, $COD_{er}$, T-P, TKN의 제거효율이 각각 95.8%, 92.5%, 71.6%, 71.1%, 98.2%. 32.5%를 나타내었다. Loess : lime = 3 : 7은 응집제로서 사용할 수 있으며, 생산된 슬러지는 토양개량제로서의 사용 가능성을 확인할 수 있었다.

• 한국물환경학회지
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• 제23권5호
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• pp.600-606
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• 2007

Livestock wastewater containing concentrated organic matters and nutrients has been known as one of the major pollutants. It is difficult to apply the conventional activated sludge process to treat livestock wastewater because of high Non-biodegradable (NBD) matter and ammonia. The objectives of this study are to remove NBD matters including aromatic compounds and ammonia in livestock wastewater using Coagulation-Fenton oxidation-Zeolite (CFZ) processes and ascertain applicable feasibility in the field through pilot plant experiment. NBD matters and color remained in the treated water were removed over 92% by Fenton oxidation as the second treatment process. Ammonia was removed by over 99.5% in the zeolite ion exchange process as the last treatment method. From $UV_{254}$, $E_2/E_3$ ratio and GC/MS analyses of treated water at each process, the aromatic compound was converted to aliphatic and aromaticity was decreased. In pilot scale test, organics and ammonia removal efficiencies were not much different from the result of lab-scale test at various operation conditions. Furthermore, reaction time and dosage of Fenton reagent in pilot scale experiment reduced by 40 min and 50% rather than in lab-scale test. $BOD_5$, $COD_{Mn}$, SS, T-N and T-P of treated water in the pilot-scale experiment also met the effluent standards.

• 한국지하수토양환경학회지:지하수토양환경
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• 제21권1호
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• pp.86-93
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• 2016

Fenton is the reaction using the OH· radicals generating by interaction between hydrogen peroxide and Fe²⁺ which can oxidize the contaminants. Fe²⁺ ions are oxidized to Fe³⁺ ions by reaction with H₂O₂ and formed OH· radicals. UV-Fenton process includes the additional reaction that generates the OH· radicals by photodegradation of H₂O₂. In methylorange (MO) decolourization experiment with UV-Fenton, optimal Fe²⁺: H₂O₂ ratio was obtained at 1 : 10. Based on the obtained condition (H₂O₂= 10mM, Fe²⁺ = 1 mM) with/without UV-fenton experiment was carried out. Removal efficiency and sludge production were measured at 30 min. The case of w/o UV irradiation and only H₂O₂ was hardly treated and only Fe²⁺ showed 65% removal owing to coagulation. When UV-Fenton process in optimal ratio (Fe²⁺: H₂O₂ = 1 : 10), UV irradiation showed better removal efficiency than of w/o UV irradiation. Also, MO decolourization was a function of the hydrogen peroxide concentration (x₁), Fe²⁺:H₂O₂ ratio (x₂), and numbers of UV lamp (x₃) from the application of the response surface methodology. Statistical results showed the order of significance of the independent variables to be hydrogen peroxide concentration > numbers of UV l amp > Fe²⁺: H₂O₂ ratio.

• 대한환경공학회지
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• 제34권8호
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• pp.549-556
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• 2012

응집제 투입 몰비에 따른 인 제거 효율을 다양한 유입 T-P 농도 및 고형물(SS) 농도에 따라 분석하였으며, 응집제 구입비 및 슬러지 처리비를 기준으로 인 처리 운영비용 분석을 하였다. 2차 침전지 유출수 T-P 농도가 0.5 mg/L 이상에서 고형물(SS) 농도에 따라 응집제 주입 몰비는 상당히 다른 것으로 나타났다. 90% 제거율 기준으로 고형물(SS) 농도 10 mg/L 이하일 경우 Alum (8%)은 약 11 mol Al/mol P, PAC (17%)은 9.6 mol Al/mol 이 요구되었으며, 고형물(SS) 농도가 10 mg/L 초과일 경우 Alum (8%)은 3.9 mol Al/mol P, PAC (17%)은 3.2 mol Al/mol P 로 나타났다. 2차 침전지 유출수 대상으로 응집제 투입비용과 슬러지 처분비용을 기준으로 한 총 운영비를 분석한 결과 대체로 PAC (17%)을 주입한 경우가 Alum (8%)을 주입했을 때 보다 상대적으로 적은 운영비가 드는 것을 확인할 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.251-251
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• 2016

For several decades, industrial processes consume a huge amount of raw water for various objects that consequently results in the generation of large amounts of wastewater. Wastewaters are consisting of complex mixture of different inorganic and organic compounds and some of them can be toxic, hazardous and hard to degrade. These effluents are mainly treated by conventional technologies such are aerobic and anaerobic treatment and chemical coagulation. But, these processes are not suitable for eliminating all hazardous chemical compounds form wastewater and generate a large amount of toxic sludge. Therefore, other processes have been studied and applied together with these techniques to enhance purification results. These include photocatalysis, absorption, advanced oxidation processes, and ozonation, but also have their own drawbacks. In recent years, electrochemical techniques have received attention as wastewater treatment process that could be show higher purification results. Among them, boron doped diamond (BDD) attract attention as electrochemical electrode due to good chemical and electrochemical stability, long lifetime and wide potential window that necessary properties for anode electrode. So, there are many researches about high quality BDD on Nb, Ta, W and Si substrates, but, their application in effluents treatment is not suitable due to high cost of metal and low conductivity of Si. To solve these problems, Ti has been candidate as substrate in consideration of cost and property. But there are adhesion issues that must be overcome to apply Ti as BDD substrate. Al, Cu, Ti and Nb thin films were deposited on Ti substrate to improve adhesion between substrate and BDD thin film. In this paper, BDD films were deposited by hot filament chemical vapor deposition (HF-CVD) method. Prior to deposition, cleaning processes were conducted in acetone, ethanol, and isopropyl alcohol (IPA) using sonification machine for 7 min, respectively. And metal layer with the thickness of 200 nm were deposited by DC magnetron sputtering (DCMS). To analyze microstructure X-ray diffraction (XRD, Bruker gads) and field emission scanning electron microscopy (FE-SEM, Hitachi) were used. It is confirmed that metal layer was effective to adhesion property and improved electrode property. Electrochemical measurements were carried out in a three electrode electrochemical cell containing a 0.5 % H2SO4 in deionized water. As a result, it is confirmed that metal inter layer heavily effect on BDD property by improving adhesion property due to suppressing formation of titanium carbide.

• 유기물자원화
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• 제14권3호
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• pp.91-100
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• 2006

본 연구에서는 돼지 분 뇨 및 폐수의 오염물 부하를 조사 및 분석함으로써 다양한 형태의 돼지 돈사로부터 발생 및 배출되는 오염물 부하 원단위를 산정한 결과는 다음과 같다. 오염물질의 발생부하 원단위는 돼지의 성장단계에 비례하여 증가하였으나, 돈사의 형태에 따른 발생부하 원단위는 각 돈사별 평균값을 고려할 때 큰 차이를 보이지 않았다. 3계절과 생체 중량을 고려한 평균 분뇨 발생량은 분이 1.49kg/head/d, 뇨가 3.08kg/head/d로서 총 4.57kg/head/d가 발생하였다. 돈사의 형태와 계절을 고려한 최종적인 평균 오염물질 발생부하 원단위는 BOD 199.5g/head/d, $COD_{cr}\;413.5g/head/d$, T-N 27.8g/head/d, T-P가 5.3g/head/d로 나타났다. 시멘트 돈사에서 배출되는 폐수의 배출부하 원단위는 BOD 31.3g/head/d, $COD_{cr}\;95.6g/head/d$, T-N 8.9g/head/d, T-P가 3.1g/head/d로 조사되었다. 분의 수거율(80%, 90%)을 고려한 분의 발생부하 원단위와 시멘트 돈사의 폐수발생 원단위의 합을 슬러리 돈사의 배출부하 원단위와 비교 시, 오염물질과 항목별로 다소의 차이는 있으나 거의 유사하였다.

• 한국콘텐츠학회논문지
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• 제18권8호
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• pp.469-482
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• 2018

본 연구에서는 델파이 기법과 AHP분석을 이용하여 경인 아라뱃길의 수질에 영향을 미치는 다양한 인자를 설정하고 하천의 수질을 체계적이고 객관적으로 평가할 수 있는 평가 항목 및 지표를 개발하였다. 분석결과, 최상위 평가항목에서의 중요도는 물리 환경적 요인 28%, 관리적 요인 26%, 자연 고정적 요인 26%, 사회 문화적 요인이 20% 순으로 나타났다. 3계층 평가항목인 물리 환경적 요인의 내적 요인에서는 자정능력의 손실, 외적 요인에서는 귤현보 및 교량에 의한 오니토 퇴적이 중요도가 가장 높은 것으로 나타났으며, 관리적 요인의 시설요인에서는 축산 및 폐수처리시설의 영향, 정책/제도적 요인에서는 규제권역상의 문제로 나타났다. 또한 자연 고정적 요인의 수생태/점오염원에서는 굴포천의 오염수, 생활환경/비점오염원은 기타하천의 유입수로 나타났으며, 사회 문화적 요인에서 경제적 요인에서는 화물 및 여객운항, 외적 요인에서는 하수처리시설 부족에 따른 영향이 중요도가 가장 높은 것으로 나타났다. 이러한 결과들은 향후 경인 아라뱃길의 수질개선 사업의 우선순위를 산정할 수 있는 논리적 근거와 객관성을 마련하기 위하여 각각의 평가지표들을 측정할 수 있는 구체적인 방법론과 기법에 대한 연구가 지속되어야 할 것이다.

• 대한환경공학회지
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• 제33권10호
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• pp.774-781
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• 2011

지르코늄합금 튜브 제조공정은 튜브 산세 시 질산과 불산을 사용하고 있어 세척 시 발생되는 폐수의 주요 오염물질인 질산성질소와 불소성분을 제거하기 위한 폐수처리는, 1차 화학응집처리에 의한 불소성분 제거공정, 황산화탈질반응을 이용한 SOD (Sulfur Oxidation Denitrification)공법에 의한 독립영양탈질공정, 그리고 2차 화학응집처리공정으로 구성되어 있다. 본 연구에서는, 처리공정에서 불소의 농도가 황산화탈질공정(SOD)의 탈질반응에 미치는 영향과 황산화탈질반응을 유지하기 위한 최적 운전조건을 검토하였다. 황산화탈질 반응은 불소농도 20 ppm 이하에서 거의 영향을 주지 않았으며, NaOH로 pH를 조절하는 것보다 NaOH와 $NaHCO_3$를 혼합하여 pH와 알칼리도를 조절해주는 것이 질소제거당량을 높여주는 효과가 있는 것으로 나타났다. 또한, 황산화탈질미생물에 필요한 미량원소와 알칼리성분이 혼합된 미생물활성화제가 알칼리도를 보충해줄 뿐만 아니라 황산화탈질미생물의 성장과 증식에도 영향을 주었으며, 그 결과 무기계 산업폐수처리 시 필요한 주기적인 미생물 식종 없이 운전이 가능한 결과를 얻었다. 이상의 결과를 통해, 황산화탈질공법(SOD공법)이 산업폐수의 질산성질소제거에 매우 유용한 공법임이 확인되었으며, 미생물활성화제가 황산화탈질미생물의 활성화에 기여함이 밝혀졌다.