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Chemical Characteristics of Shallow Groundwater in an Agricultural District of Hyogyo-ri Area, Chungnam Province (충남 효교리 농업지역 천부지하수의 화학적 특성)

  • Jeon, Hang-Tak;Hamm, Se-Yeong;Choi, Eun-Gyeong;Kim, HyunKoo;Kim, MoonSu;Park, Ki-Hoon;Lim, Woo-Ri
    • Journal of the Korean earth science society
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    • v.41 no.6
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    • pp.630-646
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    • 2020
  • In rural areas, nitrate-nitrogen (NO3-N) pollution caused by agricultural activities is a major obstacle to the use of shallow groundwater as domestic water or drinking water. In this study, the water quality characteristics of shallow groundwater in Hyogyo-ri agricultural area of Yesan-gun, Chungcheongnam-do province was studied in connection with land use and chemical composition of soil layer. The average NO3-N concentration in groundwater exceeds the domestic and agricultural standard water qualities of Korea and is caused by anthropogenic sources such as fertilizer, livestock wastewater, and domestic sewage. The groundwater type mainly belongs to Ca(Na)-Cl type, unlike Ca-HCO3 type, a general type of shallow groundwater. The average NO3-N concentration (7.7 mg L-1) in groundwater in rice paddy/other (upstream, ranch, and residential) area is lower than the average concentration (22.8 mg L-1) in farm field area, due to a lower permeability in paddy area than that in farm field area. According to the trend analysis by the Mann-Kendall and Sen tests, the NO3-N concentration in the shallow groundwater shows a very weak decreasing trend with ~0.011 mg L-1yr-1 with indicating almost equilibrium state. Meanwhile, SO42- and HCO3- concentrations display annual decreasing trend by 15.48 and 13.15%, respectively. At a zone of 0 to 5 m below the surface, the average hydraulic conductivity is 1.86×10-5 cm s-1, with a greater value (1.03×10-4cm s-1) in sand layer and a smaller value (2.50×10-8 cm s-1) in silt layer.

Antioxidant activity and physiological properties of Moringa (Moringa oleifera Lam.) leaves extracts with different solvents (추출용매에 따른 모링가(Moringa oleifera Lam.) 잎의 항산화 및 생리활성 효과)

  • Kwon, Yu-Ri;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.21 no.6
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    • pp.831-837
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    • 2014
  • This study was conducted to investigate the antioxidant activity and physiological properties of Moringa (Moringa oleifera Lam.) leaves extracted with three different solvents (water, ethanol, and methanol). The extraction yield from water, methanol, and ethanol were 13.17, 9.54, and 7.48%, respectively. The highest total polyphenol content (58.04 mg/100 g) and total flavonoid contents (12.36 mg/100 g) were observed in water extract. The DPPH radical scavenging activity was the highest in the water extract (79.18%) at the 500 mg% level, similar to BHT (77.18%). Additionally the same tendency was observed with DPPH, ABTS radical scavenging ability, and ferreous ion chelating ability. The water extract showed relatively high antioxidant activities. The angiotensin I-converting enzyme (ACE) and the HMG-CoA reductase inhibitory activity of water extract at a concentration of 500 mg% were somewhat higher than those of the other extracts. Additionally, the HMG-CoA reductase inhibitory activity of the water extract was significantly slightly lower than that of the positive control (cholorogenic acid). These results suggest that Moringa leaves extracted with water will be useful as antioxidant-rich and functional natural foods.

Co-occurrence of Deoxynivalenol and Zearalenone in Cereals and their Products (곡류와 그 가공품에서 Deoxynivalenol과 Zearalenone의 분석)

  • Ok, Hyun-Ee;Chang, Hyun-Joo;Choi, Sung-Wook;Lee, Na-Ri;Kim, Hyun-Jung;Koo, Min-Sun;Chun, Hyang-Sook
    • Journal of Food Hygiene and Safety
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    • v.22 no.4
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    • pp.375-381
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    • 2007
  • Deoxynivalenol (DON) and zearalenone (ZEN) are naturally occurring toxins produced by Fusarium species, which may grow on cereals. The aims of this study were to determine the incidence and contamination levels of DON and ZEN in cereal products. Seventy samples of cereal products were randomly selected from retail outlets during 2005 and 2006. DON and ZEN were analyzed by using high performance liquid chromatography with fluorescence and UV-detector, respectively. Detection limits were $4.4{\mu}g\;kg^{-1}$ for DON and $3.4{\mu}g\;kg^{-1}$ for ZEN. DON and ZEN were detected in 37 and 17, respectively, of the 70 samples, but the levels found were very low. In particular, out of 70 samples, 12 samples of corn and barley were co-contaminated with DON and ZEN, with levels ranging from 5.6 to $1842.3{\mu}g\;kg^{-1}$ for DON and 12.1 to $174.9{\mu}g\;kg^{-1}$ for ZEN, respectively. However, DON and ZEN were not detected in breakfast cereals and wheat flour. The highest level was found in dried corn kernel samples that confirmed by LC-MS. This study show that DON and ZEN co-contaminate with low levels in cereal products.

Development of Effective ${\gamma}$-ray and ${\beta}$-ray Detection Methods For Low-Level Radioactive Wastes (극저준위 방사성 폐기물을 위한 효율적인 ${\gamma}$-선 및 ${\beta}$-선 측정 방법 개발)

  • Kwak, Sung-Woo;Yeom, Yu-Sun;Kim, Ho-Kyung;Cho, Gyu-Seong;Park, Joo-Wan;Kim, Chang-Lak;Song, Myung-Jae
    • Journal of Radiation Protection and Research
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    • v.26 no.4
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    • pp.393-398
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    • 2001
  • The non-combustible RI wastes disposed of in hospital every year emit ${\gamma}$-ray or ${\beta}$-ray but their activities are very low to the extent of background. Development of more simple methods is needed because the conventional detection methods are so ineffective and complex. In this study, to solve this problem, detection method using efficiency curve for ${\gamma}$-ray emitting radioactive wastes measurement is proposed and experimental detection efficiency equation is also determined through HPGe's standard specimen measurement. For ${\beta}$-emitting radioisotopes detection, new measurement method using detection efficiency estimated by Monte Carlo simulation and SBD measurements is also proposed. According to the results of this paper, the unknown activity of low-level radioactive wastes without LSC requiring the preparation of standard sample and measurement for standard source detection efficiency could be determined efficiently and simply about ${\pm}17%$ in errors by using the theoretical detection efficiency and the SBD measurement result.

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A Study on the Presence of Murals by Scientific Investigation on the Inner Walls of West Ancient Tomb No.1 and 2 Neungsan-ri, Buyeo (부여 능산리 서고분군 1·2호분 내벽의 과학적 조사를 통한 벽화 존재 유무 연구)

  • Lee, Hanhyoung;Kim, Dongwon;Lee, Hwasoo
    • Conservation Science in Museum
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    • v.22
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    • pp.41-52
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    • 2019
  • Inner walls of the stone chamber of West Ancient Tomb No. 1 and 2 in Neungsan-ri, Buyeo-gun have been inspected for possible trace of murals. Tomb No.1 has a rough surface finish of the stone wall and no traces of murals was observed in any part of the stone walls except the ceiling part of the main chamber. On the ceiling surface, there is black colored area, which showed same visual characteristics for both the surface and interior upon slight scratch of the surface, suggesting that it may not be a painted layer. In addition, this black material is not artificial stuff like black ink but is confirmed as biotite from X-ray diffraction analysis that is one of the constituents of the stone wall. In case of tomb No. 2, white material, that is confirmed as lime(calcite, CaCO3) by X-ray diffraction analysis, was observed on the wall surface of the east, west and north, suggesting possible existence of murals. The lime layers, however, are located mostly on the entrance of east wall of main chamber and the place of passage whereas they are observed only in lower parts on the other walls. It may have been formed by the inflow of soil and lime from the outside as the form of the lime layer in the east wall corresponds to the traces of soil and lime deposited from the thief pit. Furthermore, the filling material found in the gap between the stone slabs of the four directions and the ceiling was confirmed as clay soil, which is different material from the lime present on the stone wall surface. If the lime layer had been artificially constructed for the purpose of creating murals, it would have been more reasonable to use lime as well in the gap between the stone slabs of the four directions and ceiling. In this regard, we conclude that there are no murals in the Tomb No. 2 in the Neungsan-ri.

Characterization of the scr Gene Cluster Involved! in Sucrose Utilization in Bifidobacterium longum (Bifidobacterium longum의 Sucrose 대사 관련 scr 유전자군의 특성 규명)

  • 권태연;이종훈
    • Microbiology and Biotechnology Letters
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    • v.32 no.3
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    • pp.199-205
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    • 2004
  • The nucleotide sequence of 8.6-kb EcoRI fragment containing sucrose phosphorylase gene isolated from Bifidobacterium longum SJ32 was determined. It was found that the fragment contained five open reading frames including the gene cluster for sucrose utilization such as a sucrose phosphorylase (ScrP), a sucrose transporter (ScrT), and a GalR-LacI-type transcriptional regulator (ScrR) identified by amino acid homology. Each gene showed over 94% amino acid homology among various B. longum strains. Genomic organization of the gene cluster is the same as those of other strains of B. longum but different from that of B. lactis. In spite of high homology of each gene among B. longum strains, the difference of flanking sequences of the gene cluster between strains SJ32 and NCC2705 insinuates the horizontal transfer of scrPTR between B. longum strains. The increase of sucrose phosphorylase activity in heterologous E. coli system by the co-expression of scrT with scrP against the single expression of scrP was measured. It seems to be the result of sucrose uptake increment by scrT in the host and is an indirect evidence that scrT is the gene for sucrose transport. The existence of multiple sucrose uptake systems in B. longum is supposed from the findings of several genes besides scrPTR involved in sucrose uptake in the genome of B. longum NCC2705.

Analysis of Catch and Effort by Diving women in Tonggui-ri, Cheju-do (제주도 동귀 어촌계의 잠수노력량 및 어획량분석)

  • CHUNG Sang-Chul;HONG Young-ja
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.26 no.1
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    • pp.41-48
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    • 1993
  • Using the eight-year-working diaries($1984{\sim}1991$) of the fishing co-operative in Tonggui-ri, Cheju-do, as well as the records of consignment sale in the fish trust market as the corporate body in Aewol-up, the results have been analyzed as follows. 1. The monthly catch of Turbo cornutus was high from September through December, representing $58.2\%$ of the annual total catches. The maximum sustained yield(MSY) of this stock was estimated to be 2.5 tons. 2. The maximum sustained yields of Haliotis spp. and Sulculus sp. were estimated to be 800kg and 750kg, respectively. 3. The maximum sustained yields of Stichopus sp. and Octopus sp. were 500kg and 2, 500kg, respectively. 4. The total yield of Hizikia fusiforme has been decreasing a little and that of Gelidium sp. has been increasing. The total yield of Gelidium sp. in 1984 was about 5 times greater than that in 1990. 5. The daily catchability by divers have been high at thirties, and the individual mean working day of divers was 101 per year. 6. The consignment sale rates were $100\%$ each for Turbo cornutus, Hiziki fusiforme and Gelidium sp., $25.5\%$ and $61.1\%$ for Haliotis sp. and Stichopus sp. respectively, and $0\%$ each for Sulculus sp. and Octopus sp.

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Bronze Production Technology in the Early Iron Age: A comparative study of bronze artifacts recovered from the Hoam-dong site in Chungju and Chongsong-ri in Buyeo (초기철기시대 청동기의 제작기술 - 충주 호암동유적과 부여 청송리유적 출토 청동기의 비교 연구-)

  • Han, Woorim;Hwang, Jinju;Kim, Sojin
    • Korean Journal of Heritage: History & Science
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    • v.51 no.4
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    • pp.224-233
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    • 2018
  • Thirty-three Early Iron Age bronzes at the sites of Hoam-dong in Chungju and Cheongsong-ri in Buyeo were investigated in order to study the manufacturing technique and the provenance of lead. Chemical analysis using X-ray fluorescence showed that 33 bronzes consist of copper(Cu), tin(Sn) and lead(Pb) served as major elements. Major and minor elemental analyses by EPMA were performed on two mirrors and 2 weapons of the bronzes investigated. The results shows that bronze mirrors from Chungju and Buyeo were high-tin bronzes(> 30 wt%). And 20% of tin and 5% of lead were founded in bronze weapons. Iron, zinc, arsenic, silver, nickel, sulfur and cobalt detected in four bronzes as minor and trace elements. The four bronzes were alloyed considering their function and were not heat treated after casting due to their high tin content. Lead isotope analysis using TIMS indicates that thirty-three bronzes were distributed southern Korea peninsula except Zone 1. As a result, lead raw materials came from various regions in Korean Peninsula not from Gyeongsang-do regions. The manufacturing techniques of bronze ware generalized at this age, and bronze was produced in various sites using raw materials from various sources.

Groundwater Recharge Evaluation on Yangok-ri Area of Hongseong Using a Distributed Hydrologic Model (VELAS) (분포형 수문모형(VELAS)을 이용한 홍성 양곡리 일대 지하수 함양량 평가)

  • Ha, Kyoochul;Park, Changhui;Kim, Sunghyun;Shin, Esther;Lee, Eunhee
    • Economic and Environmental Geology
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    • v.54 no.2
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    • pp.161-176
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    • 2021
  • In this study, one of the distributed hydrologic models, VELAS, was used to analyze the variation of hydrologic elements based on water balance analysis to evaluate the groundwater recharge in more detail than the annual time scale for the past and future. The study area is located in Yanggok-ri, Seobu-myeon, Hongseong-gun, Chungnam-do, which is very vulnerable to drought. To implement the VELAS model, spatial characteristic data such as digital elevation model (DEM), vegetation, and slope were established, and GIS data were constructed through spatial interpolation on the daily air temperature, precipitation, average wind speed, and relative humidity of the Korea Meteorological Stations. The results of the analysis showed that annual precipitation was 799.1-1750.8 mm, average 1210.7 mm, groundwater recharge of 28.8-492.9 mm, and average 196.9 mm over the past 18 years from 2001 to 2018 in the study area. Annual groundwater recharge rate compared to annual precipitation was from 3.6 to 28.2% with a very large variation and average 14.9%. By the climate change RCP 8.5 scenario, the annual precipitation from 2019 to 2100 was 572.8-1996.5 mm (average 1078.4 mm) and groundwater recharge of 26.7-432.5 mm (average precipitation 16.2%). The annual groundwater recharge rates in the future were projected from 2.8% to 45.1%, 18.2% on average. The components that make up the water balance were well correlated with precipitation, especially in the annual data rather than the daily data. However, the amount of evapotranspiration seems to be more affected by other climatic factors such as temperature. Groundwater recharge in more detailed time scale rather than annual scale is expected to provide basic data that can be used for groundwater development and management if precipitation are severely varied by time, such as droughts or floods.

Development of bio-fusion materials with skin penetrating property derived from Aurelia aurita (경피 침투율이 높은 보름달 물해파리 유래 바이오 융합 소재 개발)

  • Kim, Hyoung Sik;Seo, Hyo Hyun;Lee, Seo-Hui;Lim, Hyun Jung;Shin, Jeong Won;Kim, Seop Ri;Moh, Sang Hyun;Kim, Kwang-Hwan
    • Journal of the Korea Convergence Society
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    • v.8 no.1
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    • pp.35-42
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    • 2017
  • Previously, we reported LVH peptiede derived from Aurelia aurita as cosmecetuticals with anti-winkle activity. In this study, we synthesized pal-LVH using palmitic acid to enhance skin permeability of LVH and examined the effects as cosmeceuticals of pal-LVH. To evaluate these effects, we performed cell toxicity, wound healing, and patch test for skin irritation with LVH and pal-LVH and compared these results for their effects. As a result. pal-LVH was not showed in cytotoxicity and allergenic effect like as LVH. Besides, pal-LVH had almost same excellent anti-ageing properties in high concentration and anti-winkle effect in low concentrationwas as LVH. These results suggested synthesis of palimitic acid and LVH did not affect any functions as cosmeceuticals with increasing skin permeability. Therefore, pal-LVH can be adaptable as new cosmecetuticals with anti-winkle and anti-ageing materials and applied in the development of medicine through various convergence study.