• Title/Summary/Keyword: CoNiP 합금

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Fabrication of Bulk Metallic Glass Alloys by Warm Processing of Amorphous Powders (비정질 분말의 열간 성형법에 의한 벌크 비정질합금의 제조)

  • 이민하;김도향
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.193-201
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    • 2004
  • 1960년 Au-Si계 합금에서 처음으로 비정질상이 급속 응고법에 의해 보고된 이래/sup 1)/ 지난 40년 간 많은 합금계에서 비정질상이 보고되어졌다. 대표적으로 Fe-, Ni-, Co기 합금 등 많은 합금계에서 비정질상이 보고되었으나, 비정질상의 형성을 위해서는 약 105 K/s이상의 높은 냉각속도를 필요로 하였다. 1980년대 수백 K/s의 낮은 냉각속도 하에서도 비정질상이 형성될 수 있는 다원계 합금(multi-component alloy)이 Mg-Ln-(Ni, Cu, Zn), Ln-Al-TM 합금에서 보고되어 졌으나 많은 관심을 받지 못하다가 1993년 Zr-Ti-Ni-Cu-Be 합금에서 수 ㎝ 크기의 비정질합금 제조가 보고되면서 전 세계적으로 많은 관심을 받게 되었다. Zr-Ti-Ni-Cu-Be계 벌크 비정질 합금이 보고된 후 Zr-(Nb,Pd)-Al-TM, Pd-Cu-Ni-P, Fe-Co-Zr-Mo-W-B, Ti-Zr-Ni-Cu-Sn등 여러 합금계에서 벌크 비정질 합금이 보고되었다. (중략)

Magnetic Properties of (Co-Cr)-P-Ni Alloy Thin Film ((Co-Cr)-P-Ni 합금 박막의 자기적 특성)

  • 박창민;신경호;손홍균;이택동
    • Journal of the Korean Magnetics Society
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    • v.5 no.2
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    • pp.134-139
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    • 1995
  • We produced $(Co_{93}Cr_{7})-P-Ni$ thin films for longitudinal magnetic recording media using OC magnetron sputtering system The variation of magnetic properties of $(Co_{93}Cr_{7})-P-Ni$ pseudo-ternary system with the composition was examined. We obtained the coercivity up to 1500 Oe. The coercivity iocrease could be ascribed to in-plane anisotropy enhaocement, grain size decrease, magnetic decoupling between particles. TEM micrographs showed that the grains were well-decoupled by the addition of phosphorous.

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A Study on the Magnetic Properties of the Co-Ni-P thin Plate by Electroless Plating (무전해도금법에 의한 Co-Ni-P 박막의 자기적특성에 관한 연구)

  • Kim, C.W.;Lee, C.;Yoon, S.R.;Joung, I.
    • Korean Journal of Materials Research
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    • v.5 no.8
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    • pp.1013-1019
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    • 1995
  • The thin plate of Co-Ni-P was deposited on the polyester film by the electroless plating method. Through present experiments, deposition rates and metal compositions of the plates were determined according to compositions of solution, pH and temperature. Also, magnetic properties of plates were examined according to metal compositions. Considering magnetic properties and deposition rates of electroless plating, the best condition was obtained as pH of 8.5 and 90℃. It was observed that metal compositions were evidently varied by the pH of solutions and the concentration of complex agents. However. they were not affected by other factors. At the optimum condition, the composition of the plate was Co(78%), Ni(16%), and P(6%). Also, it was found that the coercive force was 370 Oe, and squareness was 0.65 at this condition. Magnetic properties (hard or soft) of thin plates were determined by metal compositions. Therefore. the plate became soft magnetic plate as the composition of nickel increased over 30 per cents. The crystal structure of the soft magnetic plate was found to be amorphous in which it was strongly oriented to the (111)phahe of nickel. On the ohter hand, the hard magnetic place was found to be hcp crystalline of α-cobalt which was oriented to the (101)phase of cobalt and the (100)phase of cobalt.

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The correlation between Spin Polarized Tunneling and Magnetic Moment in Co-Mn and Co-Fe Alloy Films (Co1-xFex와 Co1-xMnx 강자성 전이 합금 박막의 자기 모멘트와 터널 접합에 의한 스핀 편극치의 상관관계 연구)

  • Choi, Deung-Jang;Jang, Eun-Young;Lee, Nyun-Jong;Kim, Tae-Hee
    • Journal of the Korean Magnetics Society
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    • v.17 no.5
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    • pp.194-197
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    • 2007
  • Understanding the spin polarization (P) has been an ongoing research challenge. The $Co_{1-x}Mn_x$ (x=0.27, 1) and $Co_{1-x}Fe_x$ (x=0, 0.5, 1) films were prepared using UHV-MBE system. For these films, the magnetic properties and spin polarization were investigated using SQUID and Meservey-Tedrow technique, respectively. Although measured P is uncorrelated to the bulk magnetic moment (M) in Co-Fe and Ni-Fe alloy films, it correlates with M in some alloys such as Co-Mn and Ni-Cu. The results can be understood by the tunneling currents made up of the hybridized sp-d electrons near the Fermi-energy level. Our work shows the feasibility to tailor new materials with large P values.

A Study of the Interfacial Reactions between Various Sn-Ag-Cu Solder Balls and ENIG (Electroless Ni Immersion Gold) and Cu-OSP (Organic Solderability Preservative) Metal Pad Finish (다양한 조성의 Sn-Ag-Cu 합금계 무연 솔더볼과 ENIG(Electroless Ni Immersion Gold), Cu-OSP(Oraganic Solderability Preservertive) 금속 패드와의 계면 반응 연구)

  • Park, Yong-Sung;Kwon, Yong-Min;Son, Ho-Young;Moon, Jeong-Tak;Jeong, Byung-Wook;Kang, Kyung-In;Paik, Kyung-Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.4
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    • pp.27-36
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    • 2007
  • In this study, we investigated the interfacial reactions between various Sn-Ag-Cu(SAC) solder alloys and ENIG(Electroless Ni Immersion Gold) and Cu-OSP(Organic Solderability Preservative) pad finish. In the case of the interfacial reaction between Sb added SAC solder and ENlf thinner P-rich Ni layer was formed at the interface. In the case of the interfacial reaction between Ni added SAC solder and Cu-OSP, the uniform $Cu_6Sn_5$, intermetallic compounds(IMCs) were formed and $Cu_6Sn_5$ grain did not grow after multiple reflows. Thinner $Cu_3Sn$ IMCs were farmed at the interface between $Cu_6Sn_5$ and Cu-OSP after $150^{\circ}C$ thermal aging.

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Magnetic Properties of Electrodeposited Co-Ni-P Alloys (Co-Ni-P합금도금층의 자기적 성질에 관한 연구)

  • Paik, M. S.;Kim, Y. K.;Kang, T.;Sohn, H. J.
    • Journal of the Korean institute of surface engineering
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    • v.24 no.2
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    • pp.96-102
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    • 1991
  • Co-Ni-P alloys were electrodeposited from NH4Cl-sulfate-hypophosphite baths under various plating conditions. Their effective anisotropic magnetic field which is one of the important properties for magnetic recording materials were investigated as the function of alloy compositions and c-axis orientation. The preferred orientation and the contents of Ni and P depend on the pH of solutions and also on the current density. It was found that the alloy films deposited from the solutions of pH4 at high current density had c-axis orientation parallel to the growth direction and the effective anisotropic fields sufficient for perpendicular magnetic recording application.

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Ni-Co Alloy Electroforming for Micro Mold Fabrication (마이크로 금형 제작을 위한 니켈-코발트 합금 전주기술개발)

  • Shin S. H.;Jeong M. K.;Kim Y. S.;Han S. H.;Hur Y. M.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.276-279
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    • 2004
  • The factors affecting Ni-Co alloy electroforming were investigated to determine the optimum bath composition and electroplating parameters, like pH, temperature, and current density, suitable for high speed fabrication of a micro mold with longer lifetime. To obtain alloy deposits having uniform thickness and composition, electroplating parameters were finely tuned with home-made electroforming apparatus. Ni-Co alloy deposits had linearly increased Co with $Co^{2+}$ ion concentration in electroplating bath, and showing $412H_v$ of Victors hardness at $23wt\%$ of Co content. For Ni-Co alloy, sulfonate and diol related organic additives were very effective to alleviate its residual stress and surface roughness. The maximum deposition rate was $106{\mu}m/hr$ at 10ASD and the tensile strength of alloy deposit was 2 times larger than that of Ni only case.

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Comparison of Shear Bond Strength of Ceramic Fused to Ni-Cr and Co-Cr Alloy by Heat Treatment (도재용착용 Ni-Cr 합금과 Co-Cr 합금의 열처리에 따른 전단결합강도 비교)

  • Ahn, Jae-Seok;Ko, Eun-Kyung;Joo, Kyu-Ji
    • Journal of Technologic Dentistry
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    • v.33 no.3
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    • pp.185-192
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    • 2011
  • Purpose: This study was to evaluate the shear bond strength of the ceramic fused to Ni-Cr alloy(Bellabond plus) and Co-Cr alloy(Wirobond C) by heat treatment. Methods: Metal specimens were divided into 5 groups for each alloy according to heat treatment conditions prior to porcelain application. Fifteen specimens from each group were subjected to a shear load a universal testing machine using a 0.1mm/min cross-head speed and one specimen from each group was observed with EDX line profile. Results: The diffusion of metal oxide observed far in the specimen heat treated than no heat treated in the opaque layer. The shear bond strength measured highest to BP3(50.50MPa), WC2(50.49MPa) groups and measured lowest from BP1(35.1MPaa), WC1(39.66MPa) groups which were not treated with heat, and there was a significant difference (p<0.05). Conclusion: The shear bond strength of Ni-Cr alloy(Bellabond plus) and Co-Cr alloy(Wirobond C) measured similar 5 groups all.

Comparison of the marginal and internal fit of cores fabricated by Ni-Cr alloy(non-beryllium) and Co-Cr alloy (베릴륨이 함유되지 않은 니켈-크롬 합금 코어와 코발트-크롬 합금 코어의 적합도 비교평가)

  • Kim, Ki-Baek;Kim, Jae-Hong;Kim, Woong-Chul;Kim, Ji-Hwan
    • Journal of Technologic Dentistry
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    • v.34 no.4
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    • pp.353-359
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    • 2012
  • Purpose: The aim of this study measured and compared the marginal and internal fit of metal cores with two base metal alloy (Ni-Cr alloy(non-beryllium), Co-Cr alloy). Methods: Maxillary right first molar abutment fabricated by titanium was prepared for this study. Impressions(10ea) were made from titanium model, and study models were poured with improved dental stone. Wax cores of twenty were prepared for burn-out and casting. Ten wax cores cast Ni-Cr alloy(non-Be), and finally ten cast Co-Cr alloy. Marginal and internal fit of cores was evaluated using silicone replica technique and digital microscope(x160). The data were statistically analyzed with the independent samples t-test (${\alpha}$ <.05). Results: Mean(standard deviation, SD) marginal and internal fit total size of Ni-Cr alloy(non-Be) group was $73.3(14.4){\mu}m$ and of Co-Cr alloy group $65.6(17.4){\mu}m$. The marginal and internal fit total size of Ni-Cr alloy group(non-Be) was statistically significantly greater than that of Co-Cr alloy group (P=.004). Conclusion: Co-Cr alloy cores in this study had a better marginal fit than Ni-Cr alloy(non-Be) cores.