• Title/Summary/Keyword: Co-product

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Kinetic Studies on the Reaction of the Heterobimetallic Anion, $(OC)_5CrMn(CO)_5{^-}M^+\;(M^+=Na^+,\;PPN^+)$ with Allyl Bromide

  • Park, Yong K.;Kim, Gyu S.;Song, Gwan O.
    • Bulletin of the Korean Chemical Society
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    • v.16 no.4
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    • pp.310-315
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    • 1995
  • The heterobimetallic anion, (OC)5CrMn(CO)5-M+ (M+=Na+, PPN+), which has a donor-acceptor metal-metal bond1, was reacted with allyl bromide to yield BrCr(CO)5- and Mn(CO)5(CH2CHCH2). The reaction mechanism has been proposed in terms of the consecutive reaction pathway in which Cr(CO)5(THF) is an important intermediate leading to the corresponding product. Counterion effect on this reaction was also evaluated and the results were compared with those of the corresponding reaction of the mononuclear carbonyl anion, Mn(CO)5-.

Structural Safety Evaluation for 75,000 TDW Chemical Tanker Applied Common Structural Rules (CSR을 적용한 75,000 TDW 화학제품 운반선의 구조 안전성 평가)

  • Sim, Ye-Eun;Haa, Chung-In;Nam Gung, Mun;Kim, Gi-Jae;Lee, Kyung-Seok;Kim, Man-Soo
    • Special Issue of the Society of Naval Architects of Korea
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    • 2013.12a
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    • pp.1-7
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    • 2013
  • In past decades, a maximum standard vessel size for chemical tankers is not normally larger than 55,000 TDW due to the characteristic of chemical product shipment which is so variable but small quantity unlike single product carries such as crude oil tankers. These days, as demand of very large chemical tanker is rising due to the change of market trend of chemical product shipment, 75,000 TDW class chemical tanker has been developed. The newly developed vessel's structure has been designed based on CSR (Common Structural Rule) for double hull oil tankers (hereafter CSR) published by IACS (International Association of Classification Societies). However, due to the large difference from typical oil tankers, many items should be specially considered such as on deck transverse and corrugated bulkheads. In addition, two longitudinal bulkheads without upper stool have been constructed in order to maximise the number of cargo tanks and the volume of each cargo tanks. In this study, key word of the vessel has been briefly reviewed and the structural reliability of the proposed vessel has been investigated.

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An Investigation of Consumer Product Co-use Patterns - Focusing on air-fresheners and deodorizer - (생활화학제품 동시 사용현황 조사 - 방향제와 탈취제를 중심으로 -)

  • Lee, Daeyeop;Lim, Hyunwoo;Kim, Joo-Hyon;Kim, Taksoo;Hwang, Moonyoung;Seok, Kwangseol;Seo, Jungkwan
    • Journal of Environmental Health Sciences
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    • v.44 no.3
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    • pp.275-282
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    • 2018
  • Objective: Since certain chemicals are widely applied in a variety of consumer products, exposure via simultaneous use of multiple consumer products can put human health at risk. For this reason, use patterns of consumer products are an important factor inhuman health risk assessment. The aim of this study is to investigate co-use patterns of air-fresheners and deodorizers in Korea in order to estimate potential cumulative exposure. Methods: To collect the information on use patterns of air-fresheners and deodorizers, ten air-fresheners and 14 deodorizers were selected. A total of 3,000 participants were recruited and asked through on line questionnaires whether they had simultaneously used the selected air-fresheners and deodorant products in their daily lives. Results: Among the 3,000 participants, 45.6% had used more than two air fresheners and 46.3% used more than two deodorizers. The most common types of air fresheners used concurrently include liquid and candle types for indoor environments, while those of deodorizers were fabric trigger sprays and refrigerator gels. In addition, 73.7% used more than two products without product categories. Fabric trigger sprays were contained in all of the high-ranking product combinations. Conclusions: This study showed that many consumers concurrently used air-fresheners and deodorizers in their daily routines. For accurate exposure assessment, co-use patterns of consumer products should be further investigated.

Case study of riser design using casting simulation in gravity cast method (중력주조 공법에서 주조해석 시뮬레이션을 이용한 압탕설계 사례 연구)

  • Ko, Sang-Bae;Han, Ki-Won;Kim, Hyung-Jun;Han, Tae-Soo;Han, Seong-Ryeol;Kim, kyung-A;Choi, Kye-Kwang;Yun, Jae-Woong;Lee, Chun-Kyu
    • Design & Manufacturing
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    • v.15 no.2
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    • pp.30-35
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    • 2021
  • The casting method uses a mold to solidify a liquid metal to make a solid metal. Since it uses a liquid metal with the least deformation resistance, it has the characteristic that it can easily manufacture even a complex shape. However, the process of solidifying a liquid metal into a solid metal inevitably involves a volume change and contains internal defects such as shrinkage holes. Therefore, in the design of the casting plan, an excess volume called a pressurization compensates for the volume shrinkage. in the product, and it induces the shrinkage hole defects to occur in parts other than the product1). In this study, casting analysis was performed using casting analysis software (anycasting) in order to optimize the design of the tilting gravity casting method for automobile brackets. In particular, the filling and solidification analysis according to the shape and volume of the pressurized metal was conducted, and applied to the actual product to study the effect of the pressurized metal on the shrinkage defect. Through this study, it is possible to understand the effect of the pressure metal on shrinkage defects in the actual product and propose a design of the pressure metal that improves reliability and productivity.

Machine Learning Model for Recommending Products and Estimating Sales Prices of Reverse Direct Purchase (역직구 상품 추천 및 판매가 추정을 위한 머신러닝 모델)

  • Kyu Ik Kim;Berdibayev Yergali;Soo Hyung Kim;Jin Suk Kim
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.46 no.2
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    • pp.176-182
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    • 2023
  • With about 80% of the global economy expected to shift to the global market by 2030, exports of reverse direct purchase products, in which foreign consumers purchase products from online shopping malls in Korea, are growing 55% annually. As of 2021, sales of reverse direct purchases in South Korea increased 50.6% from the previous year, surpassing 40 million. In order for domestic SMEs(Small and medium sized enterprises) to enter overseas markets, it is important to come up with export strategies based on various market analysis information, but for domestic small and medium-sized sellers, entry barriers are high, such as lack of information on overseas markets and difficulty in selecting local preferred products and determining competitive sales prices. This study develops an AI-based product recommendation and sales price estimation model to collect and analyze global shopping malls and product trends to provide marketing information that presents promising and appropriate product sales prices to small and medium-sized sellers who have difficulty collecting global market information. The product recommendation model is based on the LTR (Learning To Rank) methodology. As a result of comparing performance with nDCG, the Pair-wise-based XGBoost-LambdaMART Model was measured to be excellent. The sales price estimation model uses a regression algorithm. According to the R-Squared value, the Light Gradient Boosting Machine performs best in this model.

Backward estimation of precipitation from high spatial resolution SAR Sentinel-1 soil moisture: a case study for central South Korea

  • Nguyen, Hoang Hai;Han, Byungjoo;Oh, Yeontaek;Jung, Woosung;Shin, Daeyun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.329-329
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    • 2022
  • Accurate characterization of terrestrial precipitation variation from high spatial resolution satellite sensors is beneficial for urban hydrology and microscale agriculture modeling, as well as natural disasters (e.g., urban flooding) early warning. However, the widely-used top-down approach for precipitation retrieval from microwave satellites is limited in several hydrological and agricultural applications due to their coarse spatial resolution. In this research, we aim to apply a novel bottom-up method, the parameterized SM2RAIN, where precipitation can be estimated from soil moisture signals based on an inversion of water balance model, to generate high spatial resolution terrestrial precipitation estimates at 0.01º grid (roughly 1-km) from the C-band SAR Sentinel-1. This product was then tested against a common reanalysis-based precipitation data and a domestic rain gauge network from the Korean Meteorological Administration (KMA) over central South Korea, since a clear difference between climatic types (coasts and mainlands) and land covers (croplands and mixed forests) was reported in this area. The results showed that seasonal precipitation variability strongly affected the SM2RAIN performances, and the product derived from separated parameters (rainy and non-rainy seasons) outperformed that estimated considering the entire year. In addition, the product retrieved over the mainland mixed forest region showed slightly superior performance compared to that over the coastal cropland region, suggesting that the 6-day time resolution of S1 data is suitable for capturing the stable precipitation pattern in mainland mixed forests rather than the highly variable precipitation pattern in coastal croplands. Future studies suggest comparing this product to the traditional top-down products, as well as evaluating their integration for enhancing high spatial resolution precipitation over entire South Korea.

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Development of a Solubilization Product Containing Oleanolic Acid with Hydrogenated Lecithin (천연 유래 수첨 레시틴을 이용한 올레아놀릭산 가용화 제형 개발)

  • Pi, Bong-Soo;Choi, Dong-Won;Park, Sung-Il;Nam, Jin;Kim, Youn-Joon;Han, Sang-Hoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.4
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    • pp.289-295
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    • 2011
  • Recently, the number of customers who want natural cosmetics without petroleum originated cosmetic ingredients is increasing over the world, however, there are few natural cosmetics that claim functionality in the products. Because there are few functional cosmetic ingredients from nature and though so, it is very difficult to stabilize the final products manufactured by using those functional cosmetic ingredients in the long period. This study is on stabilization of oleanolic acid, insoluble anti-wrinkle cosmetic ingredients from nature, with hydrogenated lecithin in the solubilization product, aiming for developing a formulation of solubilization products which can be certified as organic cosmetics. In case of other synthetic solubilizers, they showed unstability at $45^{\circ}C$ within 2 ~ 3 days, however, for natural origin hydrogenated lecithin a stable product was made without particle size change during 4 weeks. The stability of oleanolic acid in the solubilization product was measured for 24 weeks at $25^{\circ}C$ and $40^{\circ}C$, both samples showed over 90 wt% value of the initial one, which can prove that oleanolic acid was stabilized in the product without any degradation. Also through clinical tests, the effect of moisturizing, anti-wrinkle, safety were confirmed.

A Method for Forecasting Demand of High Touch Product Using Matrix Analysis of Target Populations and Product Functions (Target Population과 Product Function의 Matrix 분석을 이용한 High Touch 신제품의 판매예측 방법)

  • Park, Won-Hui;Kim, Dae-Gap;Kim, Ki-Sun;Lee, Sang-Won;Lee, Myun-Woo
    • Journal of the Ergonomics Society of Korea
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    • v.26 no.1
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    • pp.79-85
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    • 2007
  • Demand forecasting methods for a consumer product such as TV or refrigerator are widely known. However, sales forecast for a brand new product cannot be estimated using conventional forecasting methods. This study proposes a five-step procedure in forecasting a newly developed product. Step one defines functions in a High Touch product in order to estimate relative attraction of the product to consumer group. In step two, for a comparison purpose, a compatible product that is successfully penetrated into market is selected. Step three breaks a target population into many segments based on demography. Step four calculates relative attraction between the High Touch product and the compatible product. Finally, market penetration rate of the High Touch product is estimated using a bell-shaped diffusion curve of the compatible product. The process offers a method to estimate potential demand and growth pattern of the new High Touch product.