• Journal of the Korean Magnetics Society
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• v.18 no.3
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• pp.120-125
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• 2008

In this study, NiCoZn ferrites with the variation of sintering temperature and chemical composition were prepared by the coprecipitation. Microstructures Crystal structure of NiCoZn ferrites were analyzed by XRD and their electric magnetic characteristics were analyzed by LCR meter and their morphology observed by SEM. We identified that these powders have a typical NiCoZn spinel structure and nanoparticles average size of 40 nm. The impurity, the initial permeability and the Q factor value are the lowest of sintered NiCoZn ferrite at $1250^{\circ}C$. Also, we measured S-parameter for $(Ni_{0.4}Co_{0.1}Zn_{0.5})Fe_2O_4$ which showed a maximum reflection loss of -3.1 dB at 6 GHz for the 2 mm thick sample. From this result, we found that the NiCoZn ferrite can be used in ferrite microwave-absorbing application at a higher frequency region (> 6 GHz).

• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.805-809
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• 1995

In order to widen the band-width of ferrite absorber, compositional effect on the complex permeability of Ni-Zn ferrite and the structure of grid absorber were studied. From the experimental results, we could determine the optimum composition composition of Ni-Zn ferrite and the structure of grid absorber. Also, we manufactured grid absorber and investigated its microwave absorbing characteristics. Calculation shows that the ferrite frid absorber suppresses reflection ${\leq}-20dB$ from 30 MHz to 700 MHz and the conventional ferrite tile absorber suppresses reflection ${\leq}20dB$ in the frequency range of 30 MHz-400 MHz. It was found that the microwave absorbing performance of the ferrite grid absorber was superior to the ferrite tile absorber.

• Journal of the Korean Ceramic Society
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• v.40 no.2
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• pp.146-152
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• 2003

The waste ferrites from magnetic core manufacturing process were used to $CO_2$gas decomposition to avoid the greenhouse effects. The waste ferrites are the mixed powder of Ni-Zn and Mn-Zn ferrites core. In the reduction of ferrites by 5% $H_2/Ar$ mixed gas, the weight loss of ferrites was about 14~16wt%. After the$CO_2$gas decomposition reaction, the weight of the reduced ferrites was increased up to 11wt%.$CO_2$gas was decomposed by oxidation of Fe and FeO in reduced compound and the phase of the waste ferrite was changed to spinel structure. A new technique capable of$CO_2$decomposition as low cost process through utilizing waste ferrite was development.

• Transactions of the Korean hydrogen and new energy society
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• v.14 no.3
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• pp.268-275
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• 2003

The water-splitting process by the metal oxides using solar heat is one of the hydrogen production method. The hydrogen production process using the metal oxides (NiFe2O4/NiAl2O4,CoFe2O4/CoAl2O4, CoMnNiFerrite, CoMnSnFerrite, CoMnZnFerrite, CoSnZnFerrite) was carried out by two steps. The first step was carried out by the CH4-reduction to increase activation of metal oxides at operation temperature. And then, it was carried out the water-splitting reaction using the water at operation temperature for the second step. Hydrogen was produced in this step. The production rates of H2 were 110, 160, 72, 29, 17, $21m{\ell}/hr{\cdot}g-_{Metal\;Oxide}$ for NiFe2O4/NiAl2O4, CoFe2O4/CoAl2O4, CoMnNiFerrite, CoMnSnFerrite, CoMnZnFerrite, CoSnZnFerrite respectively in the second step. CoFe2O4/CoAl2O4 had higher H2 production rate than the other metal oxides.

• Journal of the Korean Magnetics Society
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• v.11 no.4
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• pp.168-172
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• 2001

Co-Zn ferrite thin films grown on thermally oxidized silicon wafers were fabricated by a sol-gel method. Magnetic and structural properties of Co-Zn thin films were investigated by using x-ray diffractometer (XRD), atomic force microscopy (AFM), auger electron spectroscopy (AES) and a vibrating sample magnetometer (VSM). Co-Zn ferrite thin films annealed at 400 $^{\circ}C$ presented have only a single phase spinel structure without any preferred crystallite orientation. Their surface roughness of Co-Zn ferrite thin films was shown as less than 3 nm and the grain size was about 40 nm for annealing temperatures over 600 $^{\circ}C$. A moderate saturation magnetization of Co-Zn ferrite thin films for recording media was obtained in this study and there is no significant difference of their magnetic property with those external fields of parallel and perpendicular to planes of the films. The maximum value of the coercivity was obtained as 1,900 Oe for Co-Zn ferrite thin film annealed at 600 $^{\circ}C$.

• Journal of Magnetics
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• v.11 no.3
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• pp.123-125
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• 2006

Co-ferrite nanoparticles have been synthesized by the decomposition of iron(III) acetylacetonate, $Fe(acac)_3$ and Co acetylacetonate, $Co(acac)_2$ in benzyl/phenyl ether in the presence of oleic acid and oleyl amine at the refluxing temperature of $295^{\circ}C$/$265^{\circ}C$ for 30 min. before cooling to room temperature. Particle diameter detected by PSA can be turned from 4 nm to 20 nm by seed-mediated growth and reaction conditions. Structural and magnetic characterization of Co-ferrite were measured by use of HRTEM, SAED (selected area electron diffraction), XRD and SQUID. The as-synthesized Co-ferrite nanoparticles have a cubic spinel structure and coercivity of 20 nm $CoFe_{2}O_{4} nanoparticles reached 1 kOe at room temperature and 18 kOe at 10 K.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.49-52
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• 1998

Preparation of hexagonal strontium-ferrite by modified spray co-roasting(MSC:H) which is expected to shorkn the length of the process and to elevate the magnetic properties of hard ferrite was studied. We prapared $Fe_2O_3/SrCO_3$ mixture powders by MSCR after stirring ionized $FeCI_2$ in distilled water with solid state $SrCO_3$. And then calcined the mixture powders up to $1150^{\circ}C$ for Sr-ferrite powders It is possible to prepare hexaferrite powders with high saturation magnetization (Ms > 69 emu/g) , coercivity (Hc > 4000 Oe) The nlagnetic values of saturation magnetization iire higher than those achieved by the conventional technique.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.309-316
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• 2006

Co-ferrite was synthesized by HEBM (High Energy Ball Milling) with a stoichiometric (Co/Fe=0.5/2.5) mixture of CoO and $Fe_2O_3$ powders. The effect of milling time on the phase transformation of the mixture was investigated by XRD. Mono-phase solid solution of Co-ferrite, which was milled for 4 h and then calcined at $900^{\circ}C$ in the Ar atmosphere, was confirmed by XRD analysis. The composition and thermal reduction behavior of Co-ferrite were analyzed by TGA and XRF. As a result, oxygen deficient Co-ferrite was synthesized by HEBM and the weight decrease of the Co-ferrite, which was oxidized at $600^{\circ}C$ for 10h by $H_2O$ vapor, was 2.41 wt% during thermal reduction at $1300^{\circ}C$.

• Journal of Magnetics
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• v.8 no.3
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• pp.118-120
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• 2003

As an alternative promising way of producing high coercivity Sr-ferrite for a permanent magnet application, intensive mechanical milling process was applied to the raw materials of the Sr-ferrite with different composition. Synthesising reactivity for the Sr-ferrite of the mechanically milled raw material containing $SrCO_3$, $La_2O_3$, $Fe_2O_3$, $Co_3O_4$, and $SiO_2$ was inferior to that of the raw material containing $SrCO_3$ and $Fe_2O_3$, The Sr-ferrite prepared from mechanically milled raw materials had profoundly improved magnetic properties compared to the Sr-ferrite prepared by conventional method. Beneficial effect of the substituting ($La_2O_3$, $Co_3O_4$) and additive ($SiO_2$) oxides for improving the magnetic properties was not exploited in the Sr-ferrite prepared from the mechanically milled raw material. The Sr-ferrite powder prepared from the mechanically milled raw materials was magnetically isotropic in nature.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.43-46
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• 2006

본 연구는 페라이트의 Fe 양이온 일부를 Ni, Mn, Co등으로 치환하여 M-ferrites를 제조하여 열화학적 2단계 물 분해 반응의 특성을 비교 평가하였고, XRD, SEM, GC등의 분석으로 각 금속산화물의 특성을 확인하였다. M-ferrites는 고상법으로 제조하였다. 각각의 M-ferrites에 대한 열적환원은 1573K에서 진행하였고 물 분해 반응은 1273K에서 실시하였다. 이 반응에서 생성된 가스는 전량 포집하여 GC를 통해 분석하였다. 반응 전후의 시료에 대하여 SEM, XRD를 분석하여 GC결과와 함께 금속산화물의 산화환원반응 특성을 고찰하였다. 그 결과로서 물 분해 반응 후 M-ferrite (M=Co, Ni, Mn)의 생성을 XRD를 통하여 확인할 수 있었고, 물 분해 반응과의 비교결과 격자상수의 증대가 M-ferrite내의 산소의 환원에 영향을 미치는 것을 알 수 있었다. SEM결과에서는 4cycle의 물 분해 반응 후 Mn-ferrite의 심한 sintering 현상을 확인 할 수 있었다.