• Title/Summary/Keyword: Co-contamination

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Performance Degradation of Mea with Cation Contamination in Polymer Electrolyte Membrane Water Electrolysis (고분자 전해질막 수전해 막전극접합체의 양이온 오염에 따른 성능 저하)

  • JUNG, HYEYOUNG;CHOI, NAKHEON;IM, SUHYUN;YOON, DAEJIN;MOON, SANGBONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.331-337
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    • 2017
  • Proton Exchange Membrane Water Electrolysis (PEMWE) is one of the most popular and widely used methods for hydrogen production. PEMWE contributes to eco-friendly system via its energy storage system application, hence making it environmentally friendly to use. However, its main drawback is contamination of proton exchange membrane during water electrolysis. Existing cation such as magnesium, calcium and the likes are the cause for membrane contamination. As a result, the cation contamination give rise to degradation of performance of electrolysis and the reverse electrolysis is effective method to remove cation.

Research and development of advanced COS for anti-contamination (염진해 특성이 향상된 COS의 개발에 관한 연구)

  • Kim, L.S.;Han, D.H.;Ahn, M.S.;Cho, H.G.;Kang, D.P.;Hwang, D.S.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1599-1602
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    • 1994
  • Recently, failure of COS(cut out switch) due to contamination has been increased. This paper is on the development of the contamination COS. 1 We designed a porcelain insulator of alternate shed for anti-contamination COS. 2 The COS was coated with HVIC(silicone) to improve resistivity to contamination. 3 The FOV characteristics of COS were examined to obtain dry FOV, wet FOV and contamination FOV.

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Contamination of an Alcyon Co-60 Gamma rays by Electrons (Alcyon Co-60 감마선의 전자오염)

  • Yoo Meong-Jin;Kim Dong-Won;Kim Chul-Soo;Chung Woon-Hyuk
    • Radiation Oncology Journal
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    • v.6 no.1
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    • pp.109-116
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    • 1988
  • The Alcyon Co-60 gamma rays was studied for electron contamination. The surface dose, attributable almost entirely to contamination electrons, has a linear dependence on field width for square fields and an inverse square dependence on distance from the bottom of the fixed head assembly Build-up and surface dose measurements were taken with and without an acrylic blocking tray in place. Further measurements were made with a copper filter designed to reduce secondary electrons emitted by photon interactions with the acrylic tray. The results are discussed in relation to skin sparing effect for radiation therapy Patients. And to achieve the maximum skin sparing effect, the selection of the optimum SSD and TSD is needed.

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Spatial assessment of soil contamination by heavy metals from informal electronic waste recycling in Agbogbloshie, Ghana

  • Kyere, Vincent Nartey;Greve, Klaus;Atiemo, Sampson M.
    • Environmental Analysis Health and Toxicology
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    • v.31
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    • pp.6.1-6.10
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    • 2016
  • Objectives This study examined the spatial distribution and the extent of soil contamination by heavy metals resulting from primitive, unconventional informal electronic waste recycling in the Agbogbloshie e-waste processing site (AEPS) in Ghana. Methods A total of 132 samples were collected at 100 m intervals, with a handheld global position system used in taking the location data of the soil sample points. Observing all procedural and quality assurance measures, the samples were analyzed for barium (Ba), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), and zinc (Zn), using X-ray fluorescence. Using environmental risk indices of contamination factor and degree of contamination ($C_{deg}$), we analyzed the individual contribution of each heavy metal contamination and the overall $C_{deg}$. We further used geostatistical techniques of spatial autocorrelation and variability to examine spatial distribution and extent of heavy metal contamination. Results Results from soil analysis showed that heavy metal concentrations were significantly higher than the Canadian Environmental Protection Agency and Dutch environmental standards. In an increasing order, Pb>Cd>Hg>Cu>Zn>Cr>Co>Ba>Ni contributed significantly to the overall $C_{deg}$. Contamination was highest in the main working areas of burning and dismantling sites, indicating the influence of recycling activities. Geostatistical analysis also revealed that heavy metal contamination spreads beyond the main working areas to residential, recreational, farming, and commercial areas. Conclusions Our results show that the studied heavy metals are ubiquitous within AEPS and the significantly high concentration of these metals reflect the contamination factor and $C_{deg}$, indicating soil contamination in AEPS with the nine heavy metals studied.

Co-contamination of Aflatoxins with Ochratoxin A and Zearalenone in Thuja orientalis Semen

  • Cho, So-Yean;Kang, Shin-Jung;Jung, Joo-Hee;Jeong, Byeong-Ok;Jeong, Choon-Sik
    • Toxicological Research
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    • v.25 no.3
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    • pp.125-131
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    • 2009
  • Korea is representative of a country that consumes herbal medicines; most of the herbal medicines circulating in South Korea have been imported from developing countries in Southeast Asia, such as China and Indonesia. Recently, domestic hygiene and safety are issues that have come to the forefront, because herbal medicines currently in circulation could possibly contain contaminants or residues. Furthermore, the appearance or discovery of harmful new species due to environmental and industrial developments is becoming a social problem. Therefore, it may be necessary to consider and investigate these matters on a continual basis. Recently, mycotoxin contaminations in such foods as cereals, nuts, and powdered red pepper have been reported. They have become a problematic issue; the possibility of contamination in herbal medicines has also been considered. Nevertheless, recognition of and research into mycotoxin contamination in herbal medicines has been scarce because herbal medicine is used in only a few nations. In this research, we identified contamination by aflatoxin which is known to be the most potent mutagenic, carcinogenic, and teratogenic mycotoxin in Thujae Semen, a herbal medicine. We also found co-contaminations involving other mycotoxins, including ochratoxin A and zeraleanone.

Application of the Detection of External Contamination on Radiation Workers for Bed Type Whole Body Counting Using Monte Carlo Method (몬테카를로 방법을 적용한 bed type 전신계측기의 방사선작업종사자 외부오염 검출 응용)

  • Kim, Jeong-In;Lee, Byoung-Il
    • Journal of Radiation Protection and Research
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    • v.38 no.4
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    • pp.242-245
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    • 2013
  • Monte Carlo method was applied to discriminate the external contamination on radiation workers in nuclear power plants for internal dose assessment generally used with a bed type scanning detector whole body counter. Korean voxel model with internal contamination was used to estimate the detection patterns of whole body scanning. Also, the BOMAB model with various external contamination was assumed to compare with detection of radionuclides inside the human body. From the comparison of detection efficiency between front and back side up, external contamination was easily distinguished.

Contamination structure and process on SUS 316 under UHV, HV and air (초고진공, 고진공, 대기압에서 SUS 316의 오염 구조와 오염 과정 연구)

  • 서지근;이규장;신용현;홍승수;정광화
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.1-8
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    • 1997
  • The contamination structure and process on SUS 316 under various exposure conditions were investigated using x-ray photoelectron spectroscopy. The metal-oxide, metal-H-oxides, CO, COH, and $C_xH_y$ are the main components of contaminants on the SUS surface. The compositional profiles of the contaminants are shown to be $C_xH_y$/CO(COH)/metal-oxide on SUS. The contamination proceeds in two steps. The oxidation of the metallic constituents followed by adsorption of hydrocarbons. Under UHV conditions the contamination is mainly due to the oxidation, and, as the exposure time increases, the oxidation continues. In HV or higher pressure, most of the oxides are formed almost immediately after exposure and as the exposure time increases the contamination of hydrocarbons continues to grow. For the SUS sample exposed to atmosphere, the metal oxide is distributed deep inside the surface with an exponentially decreasing concentration, and its thickness is nearly in the order of photoelectron mean free path. It is also seen that the Fe oxide is segregated over Cr oxide in the highly oxidized samples.

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A Study on the Contamination of D.I. Water and its Effect on Semiconductor Device Manufacturing (초순수의 오염과 반도체 제조에 미치는 영향에 대한 연구)

  • Kim, Heung-Sik;Yoo, Hyung-Won;Youn Chul;Kim, Tae-Gak;Choi, Min-Sung
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.11
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    • pp.99-104
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    • 1993
  • We analyzed the D.I. water used in wet cleaning process of semiconductor device manufacturing both at the D.I. water plant and at the wafer cleaning bath to detect the impurity source of D.I. water contamination. This shows that the quantity of impurity is related to the resistivity of D.I. water, and we found that the cleanliness of the wafer surface processed in D.I. water bath was affected by the degree of the ionic impurity contamination. So we evaluated the cleaning effect as different method for Fe ion, having the best adsoptivity on wafer surface. Moreover the temperature effect of the D.I. water is investigated in case of anion in order to remove the chemical residue after wet process. In addition to the control of D.I. water resistivity, chemical analysis of impurity control in D.I. water should be included and a suitable cleaning an drinsing method needs to be investigated for a high yielding semiconductor device.

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Effect of CO in Anode Fuel on the Performance of Polymer Electrolyte Membrane Fuel Cell (수소연료 중 일산화탄소의 고분자전해질 연료전지에 대한 영향)

  • Kwon, Jun-Taek;Kim, Jun-Bum
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.291-298
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    • 2008
  • Carbon monoxide(CO) is one of the contamination source in reformed hydrogen fuel with an influence on performance of polymer electrolyte membrane fuel cell(PEMFC). The studies of CO injection presented here give information about poisoning and recovery processes. The aim of this research is to investigate cell performance decline due to carbon monoxide impurity in hydrogen. Performance of PEM fuel cell was investigated using current vs. potential experiment, long time(10 hours) test, cyclic feeding test and electrochemical impedance spectra. The concentrations of carbon monoxide were changed up to 10 ppm. Performance degradation due to carbon monoxide contamination in anode fuel was observed at high concentration of carbon monoxide. The CO gas showed influence on the charge transfer reaction. The performance recovery was confirmed in long time test when pure hydrogen was provided for 1 hour after carbon monoxide had been supplied. The result of this study could be used as a basis of various reformation process design and fuel quality determination.

Clean Room Structure, Air Conditioning and Contamination Control Systems in the Semiconductor Fabrication Process (반도체 웨이퍼 제조공정 클린룸 구조, 공기조화 및 오염제어시스템)

  • Choi, Kwang-Min;Lee, Ji-Eun;Cho, Kwi-Young;Kim, Kwan-Sick;Cho, Soo-Hun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.2
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    • pp.202-210
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    • 2015
  • Objectives: The purpose of this study was to examine clean room(C/R) structure, air conditioning and contamination control systems and to provide basic information for identifying a correlation between the semiconductor work environment and workers' disease. Methods: This study was conducted at 200 mm and 300 mm semiconductor wafer fabrication facilities. The C/R structure and air conditioning method were investigated using basic engineering data from documentation for C/R construction. Furthermore, contamination parameters such as airborne particles, temperature, humidity, acids, ammonia, organic compounds, and vibration in the C/R were based on the International Technology Roadmap for Semiconductors(ITRS). The properties of contamination control systems and the current status of monitoring of various contaminants in the C/R were investigated. Results: 200 mm and 300 mm wafer fabrication facilities were divided into fab(C/R) and sub fab(Plenum), and fab, clean sub fab and facility sub fab, respectively. Fresh air(FA) is supplied in the plenum or clean sub fab by the outdoor air handling unit system which purifies outdoor air. FA supply or contaminated indoor air ventilation rates in the 200 mm and 300 mm wafer fabrication facilities are approximately 10-25%. Furthermore, semiconductor clean rooms strictly controlled airborne particles(${\leq}1,000{\sharp}/ft^3$), temperature($23{\pm}0.5^{\circ}C$), humidity($45{\pm}5%$), air velocity(0.4 m/s), air change(60-80 cycles/hr), vibration(${\leq}1cm/s^2$), and differential pressure(atmospheric pressure$+1.0-2.5mmH_2O$) through air handling and contamination control systems. In addition, acids, alkali and ozone are managed at less than internal criteria by chemical filters. Conclusions: Semiconductor clean rooms can be a pleasant environment for workers as well as semiconductor devices. However, based on the precautionary principle, it may be necessary to continuously improve semiconductor processes and the work environment.