• Title/Summary/Keyword: Co-contaminants

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A Comparative Study of Turbulence Models for Dissolved Air Flotation Flow Analysis (용존공기부상법 유동해석을 위한 난류모델 비교연구)

  • Park, Min A;Lee, Kyun Ho;Chung, Jae Dong;Seo, Seung Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.7
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    • pp.617-624
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    • 2015
  • The dissolved air flotation (DAF) system is a water treatment process that removes contaminants by attaching micro bubbles to them, causing them to float to the water surface. In the present study, two-phase flow of air-water mixture is simulated to investigate changes in the internal flow analysis of DAF systems caused by using different turbulence models. Internal micro bubble distribution, velocity, and computation time are compared between several turbulence models for a given DAF geometry and condition. As a result, it is observed that the standard ${\kappa}-{\varepsilon}$ model, which has been frequently used in previous research, predicts somewhat different behavior than other turbulence models.

Pbotocatalysis decomposition of TCE in water phase with recirculation photoreactor (Recirculation 광촉매 화학 반응기를 이용한 액상 TCE 분해)

  • 이태규;김동형;조덕기;조서현;오정무
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1993.05a
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    • pp.33-41
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    • 1993
  • The objectives of this experiment performed were to determine the potential using of solar radiation to destroy organic contaminants in water by photolysis and to develop the process and improve its performance. We used lab, scale of recirculation photoreactor with 30, 50, 80ppm initial concentration of TCE and Ti $O_2$ anatase, respectively. Adsorption constant, reaction constant were obtained and compared using the Langmuir-Hinshelwood kinetics equation. Ti $O_2$ anatase demonstrated the highest conversion ratio co TCE among Ti $O_2$ anatase, ZnO and F $e_2$ $O_3$ in this experiment. It was shown that in case of two component system, TCE+ phenol, as the concentration of phenol increased in the feed solution, TCE decomposition rate decreased.

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Effect of Basic Oxygen Furnace Slag used as Structural Filling Materials on the Subsurface Environment (성·복토용으로 사용된 전로제강슬래그가 주변 토양환경에 미치는 영향)

  • Lee, Hosub;Nam, Taekwoo;Jho, Eun Hea;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.6-13
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    • 2016
  • The effect of blast oxygen furnace (BOF) slag used as filling materials on the soil environment was studied using column tests that simulated the flow of the BOF slag leachate through the soil layer. The Cu, Mn, Zn, Ni, and F contents of the leachate affected soil were similar to that of the controls (i.e., soils that were not affected by the leachate). The As, Cd, and Pb contents were lower in the leachate affected soils than the controls. The changes in these contaminants contents can be attributed to the interactions between anions such as alkalinity generating anions (e.g., CO32−, HCO3, OH) or calcium ions with heavy metals or F, which consequently affected the fate of heavy metals and F in the leachate affected soils. The germination and growth of Spinapis alba in the soils affected by the leachate and the controls were also similar. However, the proportion of alkalophilic bacteria in the soils affected by the leachate significantly increased, and this can be explained by the increased soil pH due to the alkaline leachate. Overall, this study shows that the alkalinity of the BOF slag leachate, rather than the presence of heavy metals and F in the leachate, needs to be considered when the BOF slag is to be reused as structural filling materials.

Hybrid Barriers of Iron and Modified-bentonite for the Remediation of Multi-contaminated Water (복합오염물질 제거를 위한 철과 개량 벤토나이트의 복합층에 관한 연구)

  • Cho, Hyun-Hee;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.512-519
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    • 2004
  • Hybrid barriers using reduction and immobilization were tested to remediate the groundwater contaminated with multi-pollutants in this study. Iron filings and HDTMA(hexadecyltrimethylammonium)-bentonite were simulated in columns to assess the performance of hybrid barriers for remediation of trichloroethylene(TCE)-contaminated water. TCE reduction rate for the mixture of iron filings and HDTMA-bentonite was about 7 times higher than that for iron filings, only suggesting the reduction of TCE was accelerated when HDTMA-bentonite was mixed with iron filings. TCE reduction rate for the two layers of iron and HDTMA-bentonite was nearly similar to that for iron filings alone, but the partition coefficient($K_d$) for the two layers was 4.5 times higher than for that iron filings only. TCE was immobilized in the first layer with HDTMA-bentonite, and then dechlorinated in the second layer with iron filings. HDTMA-bentonite may contribute to the increase in TCE concentration on iron surface so that more TCE can be reduced. Also, TCE removal in the hybrid barriers was not affected by chromate and naphthalene while the reduction rate of TCE with the co-existing contaminants by iron filings was significantly decreased. Significant TCE removal in this research indicates that the proposed hybrid barrier system has the potential to become the effective remediation alternative during the occurrence of oil shock. Also, if subsurface environments are contaminated with multi-pollutants that contain non-reducible compounds as well as reducible compounds such as TCE, the conventional reactive barriers cannot be applied to this subsurface environment, while the proposed hybrid system can be applied successfully.

Dynamic Behavior of Offshore Waste Landfill Revetment with Geosynthethic-Soil Interface (토목섬유 접촉면을 포함한 해상 폐기물처분장 호안구조물의 동적 거동)

  • Kwak, Chang Won;Oh, Myoung Hak;Park, Inn Joon;Jang, Dong In
    • Journal of the Korean Geotechnical Society
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    • v.33 no.12
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    • pp.141-150
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    • 2017
  • Geosynthetics are generally utilized to restrain the leakage of leachate and other contaminants during the construction of offshore waste landfill. Therefore, geosynthetic-soil interface is formed inevitably. In this study, 2 dimensional numerical analysis is performed to assess the dynamic behaviour of the offshore waste landfill including geosynthetic-soil interface. Offshore waste landfill can be divided into rubble mound revetment and retaining wall types and analyzed on each type. Effective stress analysis is conducted to consider the variation of pore water pressure and axial force and shear displacement of the interface are compared based on the characteristics of seismic frequency. Consequently, retaining wall type demonstrates more stable behavior against liquefaction potential and favorable forces and shear displacement.

Development of Road Tunnel Ventilation System with Electrostatic Precipitator (도로터널용 전기집진시스템 개발)

  • Kim, Jong-Ryul;Weon, Jong-Oung
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.80-83
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    • 2008
  • As SOC (Social Overhead Capital) has been expanded, the highway road construction has been accelerated and city road system has been more complicated. So, long road tunnels have been increased and traffic flow rate also has been raised. Accordingly, the exhausting gas of vehicle cars seriously deteriorates the tunnel inside air quality and driving view. In order to improve tunnel inside air quality, we may need to introduce a compulsory ventilation system as well as natural ventilation mechanism. The natural ventilation mechanism is enough for short tunnels, meanwhile longer tunnels require a specific compulsory ventilation facility. Many foreign countries already have been devoting on development of effective tunnel ventilation system and especially, some European nations and Japan have already applied their developed tunnel ventilation system for longer road tunnels. More recently, as the quality of life improved, our concerns about safety of driving and better driving environment have been increased. In order to obtain clearer and longer driving view, we are more interested in EP tunnel ventilation system in order to remove floating contaminants and automobile exhaust gas. Evan though it's been a long time since many European countries and Japan applied more economical and environment-friendly tunnel ventilation system with their self-developed Electrostatic Precipitator, we are still dependant on imported system from foreign nations. Therefore, we need to develop our unique technical know-how for optimum design tools through validity investigation and continuous possibility examination, eventually in order to localize the tunnel ventilation system technology. In this project, we will manufacture test-run products to examine the performance of system in order to develop main parts of tunnel ventilation system such as electrostatic precipitator, high voltage power generator, water treatment system, etc.

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The Characteristics of the Appearance and Health Risks of Volatile Organic Compounds in Industrial (Pohang, Ulsan) and Non-Industrial (Gyeongju) Areas

  • Jung, Jong-Hyeon;Choi, Bong-Wook;Kim, Mi-Hyun;Baek, Sung-Ok;Lee, Gang-Woo;Shon, Byung-Hyun
    • Environmental Analysis Health and Toxicology
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    • v.27
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    • pp.12.1-12.8
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    • 2012
  • Objectives: The aim of this study was to identify the health and environmental risk factors of air contaminants that influence environmental and respiratory diseases in Gyeongju, Pohang and Ulsan in South Korea, with a focus on volatile organic compounds (VOCs). Methods: Samples were collected by instantaneous negative pressure by opening the injection valve in the canister at a fixed height of 1 to 1.5 m. The sample that was condensed in $-150^{\circ}C$ was heated to $180^{\circ}C$ in sample pre-concentration trap using a 6-port switching valve and it was injected to a gas chromatography column. The injection quantity of samples was precisely controlled using an electronic flow controller equipped in the gas chromatography-mass spectrometer. Results: The quantity of the VOC emissions in the industrial area was 1.5 to 2 times higher than that in the non-industrial area. With regards to the aromatic hydrocarbons, toluene was detected at the highest level of 22.01 ppb in Ulsan, and chloroform was the halogenated hydrocarbons with the highest level of 10.19 ppb in Pohang. The emission of toluene was shown to be very important, as it accounted for more than 30% of the total aromatic hydrocarbon concentration. Conclusions: It was considered that benzene in terms of the cancer-causing grade standard, toluene in terms of the emission quantity, and chloroform and styrene in terms of their grades and emission quantities should be selected for priority measurement substances.

Deterioration Diagnosis and Conservation Treatment of the Three-storied Stone Pagoda in Seungansaji Temple Site, Hamyang, Korea (함양 승안사지 삼층석탑의 풍화훼손도 진단과 보존처리)

  • Lee, Myeong Seong;Choi, Hee Su;Kim, Ji Young;Lee, Chan Hee;Kim, Sun Duk
    • 보존과학연구
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    • s.32
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    • pp.99-112
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    • 2011
  • The three-storied stone pagoda located in Seungansaji temple site consists mainly of medium to fine-grained biotite granite and granitic gneiss, and partly macrocrystalline gneiss, muscovite gneiss and gabbro. The surface of the stone pagoda is extensively colonized by lichen and moss due to surrounding trees and lawns, and severly deteriorated. Therefore, a comprehensive deterioration diagnosis has been carried out and conservation treatment was conducted in this study. For the conservation treatment, dry cleaning is performed throughout all the surface of the pagoda for naturally grown lichen and biological contaminants using a soft brush and wooden knife. Crustose lichen strongly adhere to the surface was removed by wet cleaning using distilled water. Also, protective railings were reinstalled to an appropriate height with taking the distance from the stone pagoda into account. Finally, the ground around the stone pagoda was repaired with clay sand, and dike was installed with a natural gradient to facilitate water drainage.

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A Simple Method for Extraction of High Molecular Weight DNA fromPorphyra Tenera (Rhodophyta) Using Diatomaceous Earth

  • Kim, Tae-Hoon;Hwang, Mi-Sook;Song, Ju-Dong;Oh, Min-Hyuk;Moon, Yong-Hwan;Chung, Ik-Kyo;Rhew, Tae-Hyoung;Lee, Choon-Hwan
    • ALGAE
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    • v.21 no.2
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    • pp.261-266
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    • 2006
  • The innate soluble polysaccharides and phenolic compounds of marine macroalgae are serious contaminants which interfere with experimental procedures such as restriction enzyme digestion, polymerase chain reaction (PCR) and other enzymatic reactions using extracted DNA samples. The viscous polysaccharides are co-precipitated with DNA samples by isopropanol or ethanol precipitation in conventional experiment. To overcome the problem, a method for the isolation of high molecular weight DNA from Porphyra tenera is developed with the application of diatomaceous earth column. The isolated DNAs by this method were about 50-100 kb in size and could be digested well with restriction enzymes. The nuclease activity seemed to be minimal, and high reproducibility in the arbitrary primed PCR for RAPD analyses was a distinctive feature. These results suggest that this method is very efficient in isolating nucleic acid from macroalgae including Porphyra.

Effect of Pretreatment of Biogenic Titanium Dioxide on Photocatalytic Transformation of Chloroform (Biogenic TiO2 나노입자 전처리가 클로로포름 광분해에 미치는 영향)

  • Kwon, Sooyoul;Rorrer, Greg;Semprini, Lewis;Kim, Young
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.98-103
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    • 2011
  • Photocatalysis using UV light and catalysts is an attractive low temperature and non-energy- intensive method for remediation of a wide range of chemical contaminants like chloroform (CF). Recently development of environmental friendly and sustainable catalytic systems is needed before such catalysts can be routinely applied to large-scale remediation or drinking water treatment. Titanium dioxide is a candidate material, since it is stable, highly reactive, and inexpensive. Diatoms are photosynthetic, single-celled algae that make a microscale silica shell with nano scale features. These diatoms have an ability to biologically fabricate $TiO_2$ nanoparticles into this shell in a process that parallels nanoscale silica mineralization. We cultivated diatoms, metabolically deposited titanium into the shell by using a two-stage photobioreactor and used this biogenic $TiO_2$ to this study. In this study we evaluated how effectively biogenic $TiO_2$ nanoparticles transform CF compared with chemically-synthesized $TiO_2$ nanoparticlesthe and effect of pretreatment of diatom-produced $TiO_2$ nanoparticles on photocatalytic transformation of CF. The rate of CF transformation by diatom-$TiO_2$ particles is a factor of 3 slower than chemically-synthesized one and chloride ion production was also co-related with CF transformation, and 79~91% of CF mineralization was observed in two $TiO_2$ particles. And the period of sonication and mass transfer due to particle size, evaluated by difference of oxygen tention does not affect on the CF transformation. Based on the XRD analysis we conclude that slower CF transformation by diatom-$TiO_2$ might be due to incomplete annealing to the anatase form.