• Title/Summary/Keyword: Co and Na addition

Search Result 436, Processing Time 0.033 seconds

The Piezoelectric Properties of (Na0.5K0.5)NbO3-K5.4Cu1.3Ta10O29 Ceramics with Various K5.4Cu1.3Ta10O29 Doping and Sintering Temperatures

  • Yoon, Jung Rag;Lee, Chang-Bae;Lee, Serk Won;Lee, Heun-Young
    • Transactions on Electrical and Electronic Materials
    • /
    • v.13 no.6
    • /
    • pp.283-286
    • /
    • 2012
  • (1-X)$(Na_{0.5}K_{0.5})NbO_3-XK_{5.4}Cu_{1.3}Ta_{10}O_{29}$ (NKN-KCT) lead-free piezoelectric ceramics have been synthesized by the conventional solid state sintering method, and their sinterability and piezoelectric properties were investigated. Typically, this material is sintered between 1,025 and $1,100^{\circ}C$ for 2 hours to achieve the required densification. Crystalline structures and Microstructures were analyzed by X-ray diffraction and scanning electron microscope. The density, dielectric constant (${\varepsilon}_r$), piezoelectric constant $d_{33}$, electromechanical coupling factor $k_p$ and mechanical quality factor $Q_m$ value of the NKN ceramics depended upon the KCT content and the sintering temperature. In particular, the KCT addition to NKN greatly improved the mechanical quality factor $Q_m$ value. The ceramic with X = 1.0 mol% sintered at $1,050^{\circ}C$ exhibited optimum properties (${\varepsilon}_r$=246, $d_{33}$=95, $k_p$=0.38 and $Q_m$=1,826). These results indicate that the ceramic is a promising candidate material for applications in lead free piezoelectric transformer and filter materials.

Chemical Fixation and Sorption of Bentonite for the Removal of Heavy Metals in Acid Mine Drainage (AMD) (광산산성폐수에 함유된 중금속 처리를 위한 Chemical Fixation과 Bentonite의 흡착)

  • Jang, Am;Kim, In-S.
    • Journal of Korea Soil Environment Society
    • /
    • v.5 no.2
    • /
    • pp.33-43
    • /
    • 2000
  • Mining wastes left without any proper treatment are affecting barren or arable lands where are located near and far from source through various pathway Metals are the only hazardous constituents that cannot be destroyed or altered by chemical or thermal methods and must be converted into the most insoluble and harmless form as possible, which have slower leaching rates than the original species, to prevent their reentry into the environment. Three types of chemical additives used in this study to immobilize heavy metals showed high immobilized capacity (q) and the efficiency (k) in the order of CaO, $Na_2$S.$5H_2$O, and $CaCO_3$. In addition, bentonite was considered as a good additive to remedy AM(Acid Mine Drainage) from the results of the physicochemical characteristics and immobilizing capacity. The Freundlich coefficients (n and k) from adsorption isotherm for the heavy metals adsorbed on 50g Benlonite were calculated.

  • PDF

Effects of Added Supercritical Carbon Dioxide (SC-CO2) Extracts from Sweet Potatoes (Ipomoea batatas L.) and Watermelon (Citrullus lantus L.) on Oxidative Stability of Perilla Seed Oil (황색고구마 및 수박 초임계이산화탄소 추출물이 들기름의 산화안정성에 미치는 영향)

  • Lee, Kyo-Yeon;Kim, Ah-Na;Lee, Hye Young;Pyo, Min Jeong;Choi, Sung-Gil
    • The Korean Journal of Food And Nutrition
    • /
    • v.34 no.4
    • /
    • pp.356-364
    • /
    • 2021
  • This study was carried out to investigate the effects of supercritical carbon dioxide (SC-CO2) extracts from sweet potatoes (SP) and watermelon (WM) on the oxidative stability of perilla seed oils (POs) over the existing ones. A comparison was done between the oxidative stability of perilla oil (PO) after the addition of 0.1% of SP, and WM extracts and PO without extract. The oxidative stability was measured based on the viscosity, acid value (AV), peroxide value (POV), antioxidant (DPPH) activity, p-anisidine value (p-AV), and fatty acid composition. The viscosities ranges were: PO without extract, from 53.99±0.99 to 74.38±1.61 cps, PO with SP extract, from 53.99±0.10 to 58.73±0.8 cps, and PO with WM extract, from 53.98±0.10 to 56.00±0.70 cps. While the PO containing the SC-CO2 extracts had significantly lower AV, POV, and p-AV, their antioxidant activity was approximately 10 times higher than that of the PO without extract. There were no significant differences in fatty acid composition between SC-CO2 extracts added groups and PO without extract (p<0.05). The findings of this study confirmed that the SC-CO2 extracts from sweet potatoes and watermelon enhanced the oxidative stability of perilla seed oils, and are potential natural antioxidants for use in the food industry.

Comparative Crude Oil Productions on Liquefaction of Crop Residues (액화기술 적용 식물체 잔사별 원유 생산량 비교)

  • Shin, JongDo;Yoon, SunCheol;Paek, Yee;Park, SangWon;Choi, HongLim
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.16 no.4
    • /
    • pp.50-56
    • /
    • 2008
  • Aqueous thermal liquefaction of rice, barley, wheat, and rapeseed straws was investigated to compare the amount of heavy oil with catalysts such as $K_2CO_3$, NaOH and KOH in the reaction temperature at $320^{\circ}C$ for 10 minutes. The reaction was carried out in a 5,000ml liquefaction system with dispenser and external electrical furnace. Raw materials (160g), 2,000ml of distilled water and 10% (wt/wt) of catalyst to plant residue were fed into the reactor. It was observed that the maximum heavy oil yield was about 29% from the feeding stock, barley straw, with addition of KOH. The caloric values of crude oil from different crop residues were ranged from 55% to 66% relative to the raw materials depend on crop residue. It was appeared that its maximum calorific value from wheat straw was approximately 6190 kcal/kg.

  • PDF

Synthesis of Pine Tree Ash and Red Pepper Stem Ash (소나무재와 고추나무대재 합성에 관한 연구)

  • Han, Young-Soon;Lee, Yong-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.7 s.290
    • /
    • pp.393-401
    • /
    • 2006
  • The development of Korean glaze originated from the development of ash glazes. Ash not only has strong solubility but also can shows the glaze a variety of different colors according to what the glaze has in it as the main component. In addition, it gives a feeling of lucidness and softness. For these reasons, there are a lot of needs for ash and many potters want to take advantage of ashes as glaze. But natural ashes have not been widely used as glaze primarily because it is relatively hard to find or manufacture. Considering the difficulty of finding or manufacturing natural ashes, this study aims to formulate synthetic ash which not only is available to the potters in general but also has the sam ε characteristics as the natural ashes. To achieve this aim, this study examines the characteristics of the pine tree ash, the main component of the glaze of celadon porcelains, and the red pepper stem ash, the main component of the brown glaze, both of which have been used by the Korean traditional potters. In this study, the alkaline component of the glaze. A important ingredient when the ashes are synthesized, was supplied by mixing of $Na_2CO_3$, Chungju limestone and rice straw ash. Furthermore, the synthetic ash, when it shows no change of pH in its composition rate of 6:2:2, was found to be usable as the most stable material. In conclusion, the formula which frits some raw $materials-Na_2CO_3$, Chungju limestone and rice straw ash-can duplicate the synthetic ash which is simila to the natural ash.

Fabrication of wide-bandgap β-Cu(In,Ga)3Se5 thin films and their application to solar cells

  • Kim, Ji Hye;Shin, Young Min;Kim, Seung Tae;Kwon, HyukSang;Ahn, Byung Tae
    • Current Photovoltaic Research
    • /
    • v.1 no.1
    • /
    • pp.38-43
    • /
    • 2013
  • $Cu(In,Ga)_3Se_5$ is a candidate material for the top cell of $Cu(In,Ga)Se_2$ tandem cells. This phase is often found at the surface of the $Cu(In,Ga)Se_2$ film during $Cu(In,Ga)Se_2$ cell fabrication, and plays a positive role in $Cu(In,Ga)Se_2$ cell performance. However, the exact properties of the $Cu(In,Ga)_3Se_5$ film have not been extensively studied yet. In this work, $Cu(In,Ga)_3Se_5$ films were fabricated on Mo-coated soda-lime glass substrates by a three-stage co-evaporation process. The Cu content in the film was controlled by varying the deposition time of each stage. X-ray diffraction and Raman spectroscopy analyses showed that, even though the stoichiometric Cu/(In+Ga) ratio is 0.25, $Cu(In,Ga)_3Se_5$ is easily formed in a wide range of Cu content as long as the Cu/(In+Ga) ratio is held below 0.5. The optical band gap of $Cu_{0.3}(In_{0.65}Ga_{0.35})_3Se_5$ composition was found to be 1.35eV. As the Cu/(In+Ga) ratio was decreased further below 0.5, the grain size became smaller and the band gap increased. Unlike the $Cu(In,Ga)Se_2$ solar cell, an external supply of Na with $Na_2S$ deposition further increased the cell efficiency of the $Cu(In,Ga)_3Se_5$ solar cell, indicating that more Na is necessary, in addition to the Na supply from the soda lime glass, to suppress deep level defects in the $Cu(In,Ga)_3Se_5$ film. The cell efficiency of $CdS/Cu(In,Ga)_3Se_5$ was improved from 8.8 to 11.2% by incorporating Na with $Na_2S$ deposition on the CIGS film. The fill factor was significantly improved by the Na incorporation, due to a decrease of deep-level defects.

Acute and 28-Day Subacute Toxicity Studies of Hexane Extracts of the Roots of Lithospermum erythrorhizon in Sprague-Dawley Rats

  • Han, Chung-Tack;Kim, Myoung-Jun;Moon, Seol-Hee;Jeon, Yu-Rim;Hwang, Jae-Sik;Nam, Chunja;Park, Chong-Woo;Lee, Sun-Ho;Na, Jae-Bum;Park, Chan-Sung;Park, Hee-Won;Lee, Jung-Min;Jang, Ho-Song;Park, Sun-Hee;Han, Kyoung-Goo;Choi, Young Whan;Lee, Hye-Yeong;Kang, Jong-Koo
    • Toxicological Research
    • /
    • v.31 no.4
    • /
    • pp.403-414
    • /
    • 2015
  • Lithospermum erythrorhizon has long been used as a traditional oriental medicine. In this study, the acute and 28-day subacute oral dose toxicity studies of hexane extracts of the roots of L. erythrorhizon (LEH) were performed in Sprague-Dawley rats. In the acute toxicity study, LEH was administered once orally to 5 male and 5 female rats at dose levels of 500, 1,000, and 2,000 mg/kg. Mortality, clinical signs, and body weight changes were monitored for 14 days. Salivation, soft stool, soiled perineal region, compound-colored stool, chromaturia and a decrease in body weight were observed in the extract-treated groups, and no deaths occurred during the study. Therefore, the approximate lethal dose (ALD) of LEH in male and female rats was higher than 2,000 mg/kg. In the subacute toxicity study, LEH was administered orally to male and female rats for 28 days at dose levels of 25, 100, and 400 mg/kg/day. There was no LEH-related toxic effect in the body weight, food consumption, ophthalmology, hematology, clinical chemistry and organ weights. Compound-colored (black) stool, chromaturia and increased protein, ketone bodies, bilirubin and occult blood in urine were observed in the male and female rats treated with the test substance. In addition, the necropsy revealed dark red discoloration of the kidneys, and the histopathological examination showed presence of red brown pigment or increased hyaline droplets in the renal tubules of the renal cortex. However, there were no test substance-related toxic effects in the hematology and clinical chemistry, and no morphological changes were observed in the histopathological examination of the kidneys. Therefore, it was determined that there was no significant toxicity because the changes observed were caused by the intrinsic color of the test substance. These results suggest that the no-observed-adverse-effect Level (NOAEL) of LEH is greater than 400 mg/kg/day in both sexes.

Durability Assessment of High Strength Concrete with High Volume Mineral Admixture (다량의 광물질 혼화재를 사용한 고강도 콘크리트의 내구성 평가)

  • Baek, Chul-Woo;Kim, Hoon-Sang;Choi, Sung-Woo;Jo, Hyun-Tae;Ryu, Deug-Hyun
    • Journal of the Korea Concrete Institute
    • /
    • v.27 no.6
    • /
    • pp.641-649
    • /
    • 2015
  • The purpose of this study was to assess the durability of high-strength concrete with high volume mineral admixture (HVMAC) derived from previous studies within ternary blended concrete (TBC) and normal concrete (NC). Four durability evaluation types such as chloride penetration resistance, freezing and thawing resistance, carbonation resistance in two pre-treatment conditions, and sulfuric acid and sulfate resistance using 5% sulfuric acid ($H_2SO_4$), 10% sodium sulfate ($Na_2SO_4$), and 10% magnesium sulfate ($MgSO_4$) solution were selected and performed in this study. HVMAC showed the excellent chloride penetration resistance in any age and the freezing and thawing durability close to 100%. In addition, HVMAC affected more reduction in carbonation resistance than TBC. When the curing time was increased, to create a concrete internal organization densely improved resistance to carbonation. HVMAC also showed the most superior in sulfuric acid and sulfate resistance. As the reduction of calcium hydroxide and $C_3A$ to apply a large amount of admixture reduced the swelling and cracking of concrete, the strength reduction and mass change of concrete was found to be small indicated.

Effects of Cow에s Milk Addition on the Quality of Soybean Curd (우유 첨가가 두부 품질에 미치는 영향)

  • 김중만;김형태;최용배;황호선;김태영
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.22 no.4
    • /
    • pp.437-442
    • /
    • 1993
  • Soybean curds were made from the mixture of soybean milk and cow's milk (raw milk) at the ratio of 10, 20, 30, 40, 50% (v/v), and then the general composition and mineral content, pH, yield, firmness by sensory evaluation and amino acid composition were investigated. As cow's milk addition increased, total sugar crude fat, crude protein, ash content, firmness, weight and volume of the soybean curd were increased. Whereas moisture content decreased, $Ca^{++}$, $K^{+}$, and Na$^{+}$ were increased, but $Mg^{++}$ and Fe$^{++}$ decreased. In sensory evaluation, color (white), firmness, flavor, and taste were higher than those of control as cow's milk increased. By adding cow's milk at the ratio of 10, 20, 30, 40%, and 50%, sulfur containing amino acid content such as methionine and cystine were enriched 1.31, 1.58, 1.67, 1.85, and 1.95 times, respectively.

  • PDF

Photodegradation of Safranin-O Dye by Au Metal Colloid in Cosmetics (화장품에서 금 콜로이드 입자에 의한 사프라닌 염료의 분해 연구)

  • Han, Moon-Suk;Lee, Yong-Geun;Lee, Young-Ho;Kim, Dae-Wook;Oh, Seong-Geun
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.34 no.2
    • /
    • pp.75-82
    • /
    • 2008
  • In this study, the photocatalysed degradation of safranin-O was investigated using Au colloids. Au metal nanoparticle wasused to eliminate safranin-O fast in solution. Au nanoparticles were prepared reduction method using $Na_2CO_3$ and PVP in aqueous solution. The degradation of safranin-O was examined using a variety of condition such as concentration of Au colloid or Au salt, reaction pH, and reaction time in the presence of UV light and $H_2O_2$. As the concentration of Au colloid increases, the rate of dye degradation increases. The photo-oxidation of the safranin-O was monitored spectrophotometrically. The properties of Au nanoparticles were characterized by UV-Vis spectroscopy. In addition, catalytic capacities of Au nanoparticles were also determined by UV-Vis spectroscopy.