• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.06a
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• pp.523-530
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• 2005

In this study, maximum exposure rate at DAW(Dry Active Waste) drum surface which is satisfying regulation limit was calculated for conceptual design of IP(Industrial Package). DAW can be classified as combustible and non-combustible waste and the calculation was conducted for single and mixed radionuclide for each type of waste. In case of combustible waste that mixed radionuclide is uniformly distributed, the maximum exposure rates at drum surface were 3.60E-01, 8.85E-01 and 1.27E+01 mSv/hr for IP Type 1, 2-a and 2-b, respectively. and 3.60E-01, 8.85E-01, 1.27E+01 mSv/hr for single radionuclide(Co-60). In case of non-combustible waste that mixed radionuclide is uniformly distributed, the maximum exposure rates at drum surface were 7.14E-01, 1.83E+00, 2.69E+01 mSv/hr for IP Type 1, 2-a and 2-b, respectively. and 7.13E-01, 1.81E-01, 2.62E+01 mSv/hr for single radionuclide(Co-60). Through this study, the maximum amount of DAW can be transported by IP was suggested as maximum exposure rate at drum surface and the calculation for the other types of waste will be conducted.

• Korean Journal of Materials Research
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• v.7 no.2
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• pp.121-128
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• 1997

Two-types of carbon fiber, anisotropic- and isotropic- pitch based, were expose to isothermal oxidation in air and $CO_{2}$ gas and the weight change rates was measured by TGA apparatus. Thc oxidation rate was laster in air than in $CO_{2}$ gas, and the oxidation rare of isotropic T- 101s liher was over 23 9 times faster than that of anisotropic HM-60 filler at $600^{\circ}C$ in air. The activation energy was 36-56 Kcal/mole at lower temperature range and 6- 13 Kcal/molc at higher temperature range. It was higher that the transition temperalure 01 reaction zone(zone 1. 2, :i) of 11M-GO fiber than that of T-101s fiber, and it was higher in $CO_{2}$ gas than in air. From SEM observation, it Lvas found that the oxidation of carbon fibers was progressed through the imperfection.

• Korean Journal of Food Science and Technology
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• v.37 no.2
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• pp.183-188
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• 2005

Effects of co-solvent polarity, citric acid, pressure, temperature, run time, and co-solvent ratio on extraction of major flavonoids from Lonicera Flos were investigated using supercritical fluid $CO_{2}(SF-CO_{2})$. HPLC analysis revealed addition of pure methanol resulted in low extraction yield of major flavonoids, luteoloin (Lu), Quercetin (Qu), Apigenin (Ap). Under same condition, as co-solvent polarity increased, yields of major flavonoids increased gradually, At optimum co-solvent extraction condirion of 60% aqueous methanol (10%, v/v), yields of Lu, Qu, and Ap were 42.09, 28.18, and 3.49 mg/100 g, respectively. Addition of citric acid to 60% aqueous methanol gave higher, with addition of 1% citrie acid resulting in highest yields of 63.2 (Lu), 39.35 (Qu), and 5.79 (Ap) mg/100 g. Optimum extraction conditions of major flavonoids were 200 bar, $50^{\circ}C$, 60 min, and $CO_{2}$-methanol-water(20: 1.8: 1.2).

• Journal of the Korean Magnetics Society
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• v.13 no.5
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• pp.198-203
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• 2003

To investigate whether the use of hard magnetic film is available to generate bias magnetic field for a magnetoimpedance sensor, the magnetic properties of SmCo hard magnetic films were investigated as a function of their compositions. The saturation magnetization decreased with Sm content increasing in SmCo films. And, the coercive force increased in the extent of Sm content of 28 at%, but decreased as Sm content increased moreover. The bias field effect of SmCo film to amorphous CoZrNb film was investigated with the magnetization corves, permeabilities, and magnetic domain structures of SmCo/CoZrNb multilayers. The bias field of about 60 Oe was observed in the film with 3 mm ${\times}$ 0.5 mm, which can be constructed as a MI sensor, and this result strongly indicates that the bias field generated from a hard magnetic film is adequate to enhance the sensitivity of a MI sensor with hard/soft magnetic multilayer structure.

• Progress in Medical Physics
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• v.13 no.1
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• pp.44-50
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• 2002

CsI(T1) single crystal was grown in a Bridgman growing apparatus, which has the diameter of 11 mm and the mole ratio of 0.001 mol%. Radiation sensors were made with CsITl)crystal and two photodiodes, and measured spectroscopic characteristics and linearity for gamma-ray and X-ray. The energy resolution of CsI(T1) radiation sensor has been measured with $^{22}$ Na, $^{137}$ Cs and $^{60}$ Co gamma standard sources. Also output linearity of CsITl) sensor was measured for diagnostic radiation region. The energy resolutions of CsI(T1) radiation sensor for 0.511MeV gamma-ray from Na-22 source, 0.662MeV from Cs-137 source, and 1.17MeV and 1.332MeV from Co-60 source were 13.2%, 8.3%, 6.7%, and 5.1% respectively. Also the output linearity up to 80mAs current for 60kVp, 80kvp, 100kVp, 120kVp tube voltages has been studied.

• Journal of the Korean Magnetics Society
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• v.1 no.2
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• pp.60-68
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• 1991

In compacting the melt-spun $Nd_{14}Fe_{76}Co_{4}B_{6}$ and $Nd_{10.5}Fe_{79}Co_{2}Zr_{15}B_{7}$ magnetic powders. the difference in composition induces a different behavior of closed packing rate as a function of aspect ratio of the powders. The $Nd_{10.5}Fe_{79}Co_{2}Zr_{1.5}B_{7}$ alloy having a low Co/Fe ratio (low density) shows the better green density to have an enhanced closed packing rate. An empirical power equation relating the green density with the compacting pressure was obtained such as ${\phi}(g/cm^{2})=5.2~5.6{\times}P^{0.045~0.065}(ton/cm^{2})$. The $Nd_{14}Fe_{76}Co_{4}B_{6}$ alloy having a high Nd/Fe ratio possesses much finer grain size(50~60 nm) than that of $Nd_{10.5}Fe_{79}Co_{2}Zr_{1.5}B_{7}$ alloy and shows the higher coercivity($iH_{c}=14~15kOe$). The higher Nd/Fe ratio in the melt-spun Nd-Fe-Co-B alloy, where the domain wall pinning mechanism was found to be predominant, assists the formation of Nd-rich grain boundary phase acting as a pinning site. The grain boundary ranges over $12~16\;{\AA}$ thick in the Nd-Fe-Co-B alloy while it ranges over $8~12\;{\AA}$ thick in the Nd-Fe-Co-Zr-B alloy.

• Journal of Hydrogen and New Energy
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• v.29 no.1
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• pp.1-10
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• 2018

The amount of biogas increases as the amount of organic waste increases. Recently, biogas from organic waste have been made much efforts to utilize as a energy. In particular, the concentration of $CH_4$ and $CO_2$ generated from sewage sludge and livestock manure treatment are 60-70% and 30-35%, and $CH_4$ and $CO_2$ generated from food wastes are 60-80% and 20-40%. In case of landfill gas, $CH_4$ and $CO_2$ have a concentration of 40-60% and 40-60% respectively. Therefore, in order to use the biogas more widely, it is necessary to convert the biogas to methanol, LNG or DME. In this study, experiments were conducted to produce hydrogen and carbon monoxide through various biogas reforming reactions on $Ni/Ce-ZrO_2/Al2O3$ catalysts. The experiment of synthetic gas synthesis was carried out on a wide concentrations of methane and carbon dioxide, which were the major constituents of biogas from various organic wastes. The effect of $(O_2+CO_2)/CH_4$ (=R') on the yields of hydrogen and carbon monoxide, the conversion rate of methane and carbon dioxide was investigated. Also simulation for syngas synthesis on the $CO_2$ reforming of $CH_4$ was computed by employing total Gibbs free energy minimization method using PRO/II simulator, and compared with the experimental results on wet and dry reforming reaction of biogas.

• Journal of Life Science
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• v.13 no.5
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• pp.569-575
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• 2003

Supercritical $CO_2$ extraction was applied to extraction of the valuable compound for benign prostatic hyperplasia from saw palmitto. Three levels of parameters, temperature $(35^{\circ}C,\; 60^<\circ}C)$, pressure 22∼30 Mpa and ethanol modified solvent concentration, were used as the independent variables of central composite to rotate the design. The extracting pressure and temperature interaction was significantly affected the extraction of valuable compounds. The ethanol was an efficient modifier to extract valuable compound by supercritical carbon dioxide. The optimal processing conditions were extracting pressure, 30 Mpa, extracting temperature, $60^<\circ}C$, ethanol modifier, 15% for extracts of the valuable compounds from saw palmitto. In conclusion, it was found that supercritical $CO_2$ extraction can successfully be applied to extract high quality extracts from saw palmitto.

• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.1958-1962
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• 2007

The title complex, Ir(H)(CO)(PEt3)2(η 2-C60) (2), has been prepared by the reaction of excess C60 (4 equiv) with a tetrairidium complex Ir4(CO)8(PEt3)4 (1) in refluxing chlorobenzene in 40% yield as green crystals. Compound 2 has been characterized by cyclic voltammetry (CV), spectroscopic methods (mass, IR, 1H and 31P NMR), and a single crystal X-ray diffraction study. The molecular structure reveals that the iridium atom of 2 is coordinated by two axial ligands of a hydrogen atom and a carbonyl group, and three equatorial ligands of two phosphorus atoms and an η 2-C60 moiety. The CV study exhibits three reversible one-electron redox waves for the successive reductions of 2, together with additional four redox waves due to free C60 reductions, which was formed by decomposition of 2 in the reduced states. The three reversible redox waves of 2 are shifted to more negative potentials by ca. 270 mV compared to free C60, reflecting both metal-to-C60 π-back-donation and the electron-donating nature of the two phosphorus ligands.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.05b
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• pp.82-85
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• 2000

We introduce pulsed $CO_2$ laser power supply excited by half-wave rectified 60Hz AC discharge some advantage of cost and size compared to a typical pulsed power supply. AC frequency is adjusted from 10Hz to 60Hz to control laser output. In this laser, a low voltage open loop control for high voltage AC discharge circuits is employed to avoid the HV sampling or switching. The control is achieved by using a ZCS circuit and a PIC one-chip microprocessor that control the gate signal of SCR precisely. The pulse repetition rate is limited by 60Hz due to a high leakage inductance. The maximum laser output was obtained about 20W at the condition of total pressure, 18Torr and pulse repetition rate,60Hz.