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Optimum Dumping Rate of Biodegradable Liquid Waste in Ocean Disposal (분해성 액상폐기물의 해양처리시 최적 투기율)

  • LEE Suk-Mo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.3
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    • pp.198-207
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    • 1990
  • Among the biodegradable liquid waste treatment and disposal methods, ocean dumping is a cost-effective and productive manner considering reuse point of view However, when biodegradable liquid waste is dumped in the ocean, oxygen consumption by the decomposition of organic matter must be considered. The purpose of this study is to determine the maximum allowable concentration and dumping rate in the southern waters of the East Sea based on dissolved oxygen level. Streeter and Phelps' model has been used to determine the maximum allowable concentration. Factors in this model, deoxygenation constants and reaeration coefficients, have been determined by appling oxygen consumption method and closed system model. Deoxygenation constants and reaeration coefficients from surface to each standard depth are $0.24\~0.29/day\;and\;0.03\~0.39/day$ in summer, $0.17\~0.20/day\;and\;0.04\~0.56/day$ in winter, respectively. The allowable organic matter concentration($mgBOD/\iota$) to the dissolved oxy-gen sag value of $5mg/{\iota}$ is represented $17.23\times(H)^{-0.37}$ in summer, and $64.96\times(H)^{-0.52}$ in winter by mixing depth(H, m). Csanady's experiment has been applied to estimate the optimum dumping rate. The optimum dumping rate($R,\;m^3/sec$) can be written as a product of the beam(b, m) and the draft(h, m) of vessel, and biochemical oxygen demand of waste($L_n,\;mg/{\iota}$) $R=275{\times}bh^{0.63}L_n^{-1}$ in summer $=745{\times}bh^{0.48}L_n^{-1}$ in winter. The difference of dumping rate between in summer and winter is due to the oxygen distribution.

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Synthesis of Na-A Type of Zeolite from Funnel-Glass Waste (브라운관의 후면유리 폐기물을 이용한 제올라이트 합성)

  • 장영남;배인국;채수천;류경원
    • Economic and Environmental Geology
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    • v.34 no.2
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    • pp.167-173
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    • 2001
  • Through alkaline hydrothermal activation processes, Na-A type zeolite was synthesized as a single phase with funnel-glass waste from a television tube factory. The autoclaving was performed in a closed teflon vessel in the range of 80~95$^{\circ}$C. The silica-rich solution as a starting material was hydrothermally synthesized with quartz in IN NaOH by heating 350uC under the pressure of 1,500 atm. $NaAlO_2$ was made from NaOH and Al(OHh by heating 95$^{\circ}$C for 2-3 hours and the molar ratios of it were $Na_2O/Al_2O_3$ = 1.4 and $H_2O/Na_2O$=8. The equi-dimensional A type zeolite (1-2 11) was formed by the simple mixing of the silica-rich solution, glass waste and $NaAlO_23$ for 1-3 hours-heating at $80^{\circ}C$. The characterization of the reaction product shows Na-A as a single phase. The synthesized zeolite has cuba-dodecahedral form and $Ca^{2+}$ ion exchange capacity of the Na-A was in the range of 215-220 mequiva1entilOO g.

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Surgical Treatment for Common Iliac Arteriovenous Fistula after Lumbar Laminectomy (요추궁절제술 후에 발생한 총장골동맥의 동정맥루에 대한 수술)

  • Ryu, Kyoung-Min;Ryu, Jae-Wook;Park, Seong-Sik;Kim, Seok-Kon;Seo, Pil-Won
    • Journal of Chest Surgery
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    • v.40 no.6 s.275
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    • pp.455-458
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    • 2007
  • A 40 year-old male patient admitted for dyspnea and edema of the lower extremities. A pulsatile abdominal mass with a bruit was palpable in the right lower quadrant. Four months previously, he had underwent left partial lam-inectomy ($L4{\sim}5$) and discectomy at the L4 level due to disc protrusion, Computed tomography showed an ilio-iliac AV fistula with pseudoaneurysm at the L5 level. Because massive bleeding occurred when the aneurysm was entered, we closed the aneurysm and performed resection and suture of the aorta and both iliac arteries very near the aneurysm. After exclusion of the arterial side, we performed reduction angioplasty at the aneurysm and aorto-biiliac reconstruction with an artifcial graft. Twenty-four months after operation, he is doing well and hasn't had any complications on the follow-up.

Hydrothermal Synthesis of Kaolinite (캐올리나이트의 수열합성)

  • Jang, Young-Nam;Ryu, Gyoung-Won;Chae, Soo-Chun;Lee, Sung-Ki;Suh, Yong-Jae;Bae, In-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.3
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    • pp.147-153
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    • 2007
  • Kaolinite [$Al_2Si_2O_5(OH)_4$] was successfully synthesized by a hydrothermal process from amorphous $Al(OH)_3$ and $SiO_2$ at $230^{\circ}C$ under the pressure of $30 kg/cm^2$. The experiments were performed varying temperatures ($180{\sim}280^{\circ}C$), pressure ($10{\sim}60kg/cm^2$), chemistry ($Al_2O_3/SiO_2 = 0.5{\sim}0.38$) and pH ($0.3{\sim}9.5$) of the solution. The autoclaving was carried out in a closed stainless steel vessel. Kaolinite appears from the starting composition of $Al_2O_3/SiO_2= 0.5$ with boehmite and was stable as a single phase with the composition of $Al_2O_3/SiO_2=0.45$. Boehmite was a stable phase below $200^{\circ}C$ for the 240 h period of autoclaving, but kaolinite appeared even in 20 h at $230^{\circ}C$. The single kaolinite phase of a good crystallinity was observed at pH ranging 2 to 6. That indicates that pH is one of the most critical parameters for the successful formation of kaolinite. The optimal molar ratio of $Al_2O_3$ to $SiO_2$ was determined to be 0.45. The XRD pattern of the synthesized kaolinite coincided with that of natural one and its morphology was the cluster type of the kaolinite crystals (diameter = ${\sim}3{\mu}m$), irrespective of starting material, composition and temperature.