• Corrosion Science and Technology
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• v.20 no.1
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• pp.26-36
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• 2021

Pipes operating in the seawater environment faces cavitation degradation and corrosion of the metallic component, as well as a negative synergistic effect. Cavitation degradation shows the mechanism by which materials deteriorate by causing rapid change of pressure or high-frequency vibration in the solution, and introducing the formation and explosion of bubbles. In order to rate the cavitation resistance of materials, constant conditions have been used. However, while a dynamic cavitation condition can be generated in a real system, there has been little reported on the effect of ultrasonic amplitude on the cavitation resistance and mechanism of composites. In this work, 3 kinds of epoxy coatings were used, and the cavitation resistance of the epoxy coatings was evaluated in 3.5% NaCl at 15 ℃ using an indirect ultrasonic cavitation method. Eleven kinds of mechanical properties were obtained, namely compressive strength, flexural strength and modulus, tensile strength and elongation, Shore D hardness, water absorptivity, impact test, wear test for coating only and pull-off strength for epoxy coating/carbon steel or epoxy coating/rubber/carbon steel. The cavitation erosion mechanism of epoxy coatings was discussed on the basis of the mechanical properties and the effect of ultrasonic amplitude on the degradation of coatings.

• Corrosion Science and Technology
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• v.21 no.3
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• pp.230-241
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• 2022

Austenitic stainless steel has been widely used because of its good corrosion resistance and mechanical properties. However, intergranular corrosion can occur if the alloy is welded or aged. The objective of this study was to determine intergranular corrosion behaviors of austenitic medium carbon (0.05 wt%) and low carbon (0.02 wt%) stainless steel aged at several conditions. Alloys were evaluated according to ASTM A262 Practice A, ISO 12732 DL-EPR (double loop-electrochemical potentiokinetic reactivation) test, and ASTM A262 Practice C. The degree of sensitization and intergranular corrosion rate were obtained. The relationship between the degree of sensitization and the intergranular corrosion rate showed a very large fluctuation. Such behavior might be related to whether two-dimension tests or three-dimension tests were performed. On the other hand, regardless of carbon content of alloys, when the intergranular corrosion rate increased, the degree of sensitization also increased. However, the DL-EPR test showed a higher sensitivity than the Huey test for differentiating the intergranular corrosion property at a low intergranular corrosion rate, while the Huey test had a higher sensitivity than the DL-EPR test for distinguishing the intergranular corrosion property at a high intergranular corrosion rate.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.335-346
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• 2021

Since epoxy resin coating shows excellent properties in formability, adhesion, and corrosion resistance, they have been extensively used in many industries. However, various types of damages in the epoxy coated tube within a relative short time have been reported due to cavitation erosion, liquid impingement, variation of temperature and pressure. Nevertheless, there has been little research on the effect of temperature on the cavitation degradation of epoxy coatings. Therefore, this work used an ultrasonic cavitation tester to focus on the effect of solution temperature on the cavitation properties of 3 kinds of epoxy coatings in 3.5% NaCl. The cavitation properties were discussed basis on the material properties and environmental aspects. As the solution temperature increased, even though with large fluctuation, the cavitation degradation rates of A and B coatings were reduced rapidly, but the rate of C coating was decreased gradually. In addition to the cushioning effect, the reason that the cavitation degradation rate reduced with solution temperature was partly related to the brittle fracture and water absorptivity of the epoxy coatings, and the water density, but was little related to the shape and composition of the compound in the coatings or the phase transition of the epoxy coating.

• Corrosion Science and Technology
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• v.22 no.6
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• pp.419-428
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• 2023

Seawater has been used to cool devices in nuclear power plants. However, the pipes used to transport seawater are vulnerable to corrosion; hence, the inner side of pipelines is coated with an epoxy layer as prevention. Upon coating damage, the pipe becomes exposed, and corrosion progresses. The major cause is widely known as cavitation corrosion, causing the degradation of mechanical properties. In this study, corroded specimens were prepared using cavitation and immersion methods to clarify the degradation trend of mechanical properties with corrosion. Three different types of epoxy coatings were used, and accelerated cavitation procedures were composed of amplitudes of 15 ㎛, 50 ㎛, and 85 ㎛ for 2 h, 4 h, and 6 h. The immersion periods were 3 and 6 weeks. We conducted instrumented indentation tests on all degradation samples to measure mechanical properties. The results showed that higher cavitation amplitudes and longer cavitation or immersion times led to more degradation in the samples, which, in turn, decreased the yield strength. Of the three samples, the C coating had the highest resistance to cavitation and immersion degradation.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.639-643
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• 2011

Fry-drying of coal slurry is one of the upgrading low rank coal processes. It consists of slurry mixing, slurry dewatering, solvent recovery and briquetting. Cost estimation and economic feasibility are examined for the upgrading low rank coal process based on capacity of 1 million ton/yr. In case that investment costs are $100,000,000, discount rate is 12%, and service life is 20 years, the results of economic analysis are enough to satisfy the evaluation criteria of investment such as IRR, B/C ratio, NPV and discounted payback period. According to sensitivity analysis, investment value are very sensitive to raw material cost and product price. Since the bituminous coal price is currently soaring, it is expected that the investment value will increase more and more.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.8
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• pp.797-802
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• 2012

In this study, the potential performance enhancement in a dual heat pump system through series operation was investigated by a comparison between the performance for parallel and series operation for a heating supply temperature of $60^{\circ}C$. To compare the performance of each configuration fairly, the heat transfer surface area of the heat exchangers was fixed. The inlet temperatures and the flow rates of the heat source and the load were also fixed. In addition, the heat transfer and pressure drop characteristics of the working fluids were considered to achieve a more realistic comparison. The results show that the heating coefficient of performance (COP) of the series configuration is approximately 5% higher than that of the parallel configuration under the simulation conditions considered in the present study.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.623-635
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• 2022

As global warming accelerates, clean hydrogen production becomes more important to mitigate it. However, importing hydrogen is necessary for countries that have high energy demands but insufficient resources to produce clean hydrogen. In line with the trend, this study investigated both the economic and environmental viability of an overseas hydrogen supply chain between Australia and the Republic of Korea. Several possible methods of water electrolysis and hydrogen carriers are compared and effect of renewable electricity price on the cost of hydrogen production is evaluated.

• Journal of Physiology & Pathology in Korean Medicine
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• v.18 no.6
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• pp.1548-1551
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• 2004

studied on the physicochemistrical property of the clean active water depositting on the ceramic stone by the mineral-Oriental medicine. The results are as follows. The cluster of the clean active water is observed 53-66.5㎐ for contral water. The clean active water is observed 7.2 ph and 1.3330 refractive index for contral water. In the chemical experimental test by ICP, the clean active water is observed 102℃ in boiling point and 4.8㎎/100g V.E for 0㎎g/100g of contral water. In the antibiotic experimentation, an anion, the dimintion index of bacilli, radiation degree and radiate energy of the clean active water increased for contral water. And in the deodorization experimentation, the clean active water is observed 95% deodorization index.

• Clean Technology
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• v.14 no.2
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• pp.71-86
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• 2008

In this review we discussed the effective ways to catalytically derive value-added chemicals from propane which has been utilized only as an energy source so far. Among various propane-derived products, the most valuable chemicals such as propylene and acrylonitrile were mainly focused herein. Propylene could be manufactured through oxidative dehydrogenation of propane using $O_2,\;CO_2$, etc. as an oxidant for the purpose of overcoming thermodynamic limitations of propane dehydrogenation. On the other hand, propane ammoxidation would be an alternative to propylene ammoxidation for producing acrylonitrile since propane is much cheaper than propylene as a starting material. Although effective $MoVTeNbO_x$ catalysts have been developed fur propane ammoxidation in recent years, more detailed studies should be thoroughly performed. In carrying out both oxidative dehydrogenation and ammoxidation of propane fur a long period, the most critical issue is definitely considered to find out the most active and selective catalysts, which makes it possible to commercialize both reactions into economically viable processes.

• Applied Chemistry for Engineering
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• v.20 no.4
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• pp.391-395
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• 2009

For the conversion of domestic waste-wood into energy, a fixed bed gasifier ($0.9 m{\times}2.4 m$) having the capacity of 2 ton/day was designed and constructed. The dual knife valve was used to feed waste-wood of which size was 3~5 cm and a rotary stoker system was installed in the bottom of gasifier. The pilot gasification system consisted of feeding system, fixed bed gasifier, gravity fine particle collector, heat exchanger for syngas cooling, ID fan, and cooling tower. The operation temperatures of gasifier were $700{\sim}1000^{\circ}C$ and the concentrations of syngas were CO: 25~40 vol%, $H_2$: 7~12 vol%, $CH_4$: 2~4 vol%, $CO_2$: 12~24 vol%. The calorific value of syngas was $1100{\sim}1500kcal/Nm^3$ and was enough to be applied in the industrial combustor. Also the gas engine was operated by using syngas from biomass gasifier and produced 1~4 kW of power.