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A Study on Soil Cementation and Calcite Precipitation with Clay as a Medium (점토를 매개체로 한 탄산칼슘 석출 및 흙의 고결에 관한 연구)

  • Park, Sung-Sik;Suh, Eun-Hee;Chae, Kyung-Hyeon;Jang, Sang Kyu;Kim, Jin-Ho
    • Journal of the Korean Geotechnical Society
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    • v.31 no.12
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    • pp.17-27
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    • 2015
  • In this study, we tried to precipitate calcium carbonate with carbonate ions decomposed from urea by plant extract and calcium ions dissolved in water. The clay particles carry a net negative charge on their surfaces. Such clay mineral was additionally mixed as a medium to improve soil strength and durability with environmentally-friendly way. The $1^{st}$ solution (plant extracts and urea) and the $2^{nd}$ solution (calcium chloride and clay) were mixed together with clean Nakdong River sand. Then, this mixed soil was compacted into a small cylindrical specimen and then air cured for 7 days in laboratory. The molar concentration of urea and calcium chloride was tested for three different conditions, 1, 5, and 7 mol. Three different clay contents (0, 1, and 3% per total weight) were mixed with sand. For each specimen, a series of unconfined compression test, a durability test, SEM, EDX and XRD analyses were carried out to evaluate its cementation and structure. As the molar concentration of the solution and clay content increased, the unconfined compressive strength and durability increased. The results of SEM, EDX and XRD analyses showed that calcite was precipitated around clay mineral. The thermogravimetry analysis indicated that calcium carbonate precipitated about 1~2% per total weight of the sample.

A Regional Source-Receptor Analysis for Air Pollutants in Seoul Metropolitan Area (수도권지역에서의 권역간 대기오염물질 상호영향 연구)

  • Lee, Yong-Mi;Hong, Sung-Chul;Yoo, Chul;Kim, Jeong-Soo;Hong, Ji-Hyung;Park, Il-Su
    • Journal of Environmental Science International
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    • v.19 no.5
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    • pp.591-605
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    • 2010
  • This study were to simulate major criteria air pollutants and estimate regional source-receptor relationship using air quality prediction model (TAPM ; The Air Pollution Model) in the Seoul Metropolitan area. Source-receptor relationship was estimated by contribution of each region to other regions and region itself through dividing the Seoul metropolitan area into five regions. According to administrative boundary, region I and region II were Seoul and Incheon in order. Gyeonggi was divided into three regions by directions like southern(region III), northern(IV) and eastern(V) area. Gridded emissions ($1km{\times}1km$) by Clean Air Pollicy Support System (CAPSS) of National Institute of Environmental Research (NIER) was prepared for TAPM simulation. The operational weather prediction system, Regional Data Assimilation and Prediction System (RDAPS) operated by the Korean Meteorology Administration (KMA) was used for the regional weather forecasting with 30km grid resolution. Modeling period was 5 continuous days for each season with non-precipitation. The results showed that region I was the most air-polluted area and it was 3~4 times more polluted region than other regions for $NO_2$, $SO_2$ and PM10. Contributions of $SO_2$ $NO_2$ and PM10 to region I, II and III were more than 50 percent for their own sources. However region IV and V were mostly affected by sources of region I, II and III. When emissions of all regions were assumed to reduce 10 and 20 percent separately, air pollution of each region was reduced linearly and the contributions of reduction scenario were similar to those of base case. As input emissions were reduced according to different ratio - region I 40 percent, region II and III 20 percent, region IV and V 10 percent, air pollutions of region I and III were decreased remarkably. The contributions to region I, II, III were also reduced for their own sources. However, region I, II and III affected more regions IV and V. Shortly, graded reduction of emission could be more effective to control air pollution in emission imbalanced area.

Preparation of Zinc Oxide Thin Film by CFR Method and its Electrical Property for Detection of Sulfur Compounds (CFR 법에 의한 산화아연 박막의 제조 및 황 화합물 검출을 위한 전기적 특성)

  • Lee, Sun Yi;Park, No-Kuk;Yoon, Suk Hoon;Lee, Tae Jin
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.218-223
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    • 2010
  • The zinc oxide thin film, which can be applied as the gas sensor of a semiconductor type, was grown on the silicon substrate by CFR(continuous flow reaction) method in this study. The growth property and the electrical property of the zinc oxide thin films synthesized by CFR method were also investigated. Zinc acetate solutions of 0.005~0.02 M were used as the precursor for the preparation of zinc oxide thin films. The size of ZnO particles consisted on the zinc oxide thin film increased not only with increasing concentration of precursor, but also the thickness of thin film increased. The growth rate of zinc oxide thin film by CFR method was proportionably depend on the concentration of precursor and the uniform ZnO thin film was prepared when zinc acetate of 0.01 M is used as the precursor. The charged currents on the zinc oxide thin films were obtained as its electrical property by I-V meter, and increased agree with increasing the thickness of zinc oxide thin film. Thus, it was concluded that the charged current on the zinc oxide thin film can be controlled with changing concentration of precursor solution in CFR method. The charged currents on the zinc oxide thin films also decreased when ZnO thin film is exposed under hydrogen sulfide of 500 ppmv at $300^{\circ}C$ for 5 min. From these results, it could be confirmed that the zinc oxide thin film prepared by CFR method can be used for the detection of sulfur compounds.

Direct Bonding of SillSiO2/Si3N4llSi Wafer Fairs with a Fast Linear Annealing (선형가열기를 이용한 SillSiO2/Si3N4llSi 이종기판쌍의 직접접합)

  • 이상현;이상돈;송오성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.301-307
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    • 2002
  • Direct bonded SOI wafer pairs with $Si ll SiO_2/Si_3N_4 ll Si$ the heterogeneous insulating layers of SiO$_2$-Si$_3$N$_4$are able to apply to the micropumps and MEMS applications. Direct bonding should be executed at low temperature to avoid the warpage of the wafer pairs and inter-diffusion of materials at the interface. 10 cm diameter 2000 ${\AA}-SiO_2/Si(100}$ and 560 $\AA$- ${\AA}-Si_3N_4/Si(100}$ wafers were prepared, and wet cleaned to activate the surface as hydrophilic and hydrophobic states, respectively. Cleaned wafers were pre- mated with facing the mirror planes by a specially designed aligner in class-100 clean room immediately. We employed a heat treatment equipment so called fast linear annealing(FLA) with a halogen lamp to enhance the bonding of pre mated wafers We kept the scan velocity of 0.08 mm/sec, which implied bonding process time of 125 sec/wafer pairs, by varying the heat input at the range of 320~550 W. We measured the bonding area by using the infrared camera and the bonding strength by the razor blade clack opening method, respective1y. It was confirmed that the bonding area was between 80% and to 95% as FLA heat input increased. The bonding strength became the equal of $1000^{\circ}C$ heat treated $Si ll SiO_2/Si_3N_4 ll Si$ pair by an electric furnace. Bonding strength increased to 2500 mJ/$\textrm{m}^2$as heat input increased, which is identical value of annealing at $1000^{\circ}C$-2 hr with an electric furnace. Our results implies that we obtained the enough bonding strength using the FLA, in less process time of 125 seconds and at lowed annealing temperature of $400^{\circ}C$, comparing with the conventional electric furnace annealing.

A Comparative Study of Housing Culture of Korean Immigrants through Analysis of Living Arrangement in Australia and Canada (해외거주 한인의 주공간 사용 및 주생활 분석을 통해 본 주거문화의 비교 고찰 - 호주(Australia)와 캐나다(Canada)를 중심으로 -)

  • Lee, Young-Shim
    • Journal of the Korean Home Economics Association
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    • v.46 no.1
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    • pp.47-61
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    • 2008
  • The purpose of this study is to provide information about domestic living of Korean immigrants in Australia and Canada who have the same cultural background for comparative study. For this, usage of domestic space and living style in housing of 52 Korean households in Melbourne of Australia and 32 Korean households in the region of Waterloo of Canada were analyzed. Ethnographic research with questionnaire were used. Results of the research were as follows. 1. Korean immigrants in each countries were living in houses which was built by company of Australia and Canada. 44.2% of Korean immigrants in Australia were using L+D K and 53.1% of Korean immigrants in Canada were using L D K. 2. Laundry was indispensable for Korean immigrants in both countries and they all wanted to use the laundry as a utility room which could dry, ironing and so on. 3. Drain hole on the floor of the bathroom was not indispensable for most Korean immigrants in both countries for hygienic reason. 4. Korean immigrants in both countries were ironing in master bedroom and they all wanted to separate it from there through renovation and extension and so on. 5. Korean immigrants in Canada were more active to use the formal lounge which has been planned as a traditional element of western house. 6. The seating style of Korean immigrants in both countries belong to chair-seating style mostly. But it was clear that they were making Kimchi with floor seating style in both countries. 7. A level of satisfaction about using carpet was not high for Korean immigrants in both countries cause of uneasiness to clean and it was considered to relate to the floor seating style of them. 8. Almost Korean immigrants were took off the shoes inside of the house and they had shoes cabinet beside the entrance or basement usually. 9. The most popular heating system was ducted heating in both countries. The level of satisfaction about this was different for Korean immigrants in Australia and Canada but most desirable heating system was Ondol for them in both countries commonly.

A Study on KSNP Environmental Color Design (개선형 한국 표준 원자력 발전소의 친환경 색채디자인 연구)

  • Kim, Yeon-Jung
    • Archives of design research
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    • v.17 no.4
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    • pp.233-240
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    • 2004
  • Living in the modern age with well-developed scientific technologies, all of us are enjoying convenient lives because of 'energy'. Korea, poor in resources, is importing a large portion of its energy sources from abroad but energy consumption shows an upward tendency due to the continuing economic growth and the improvement of living conditions. The atomic energy is considered a self-reliant, alternative energy source like our country. However, it is necessary to educate the people on and publicize atomic power generation in the face of the widespread negative recognition that the atomic power plant is a hazardous facility. The study approaches to these matters with a human-friendly and environment-friendly coloring plan in the perspective of environment coloring plan. The study aims to minimize negative images of the atomic power, while highlighting its friendly and positive images so as to enhance the confidence of the people on the atomic power and to create a clean image for the atomic power. For this goal, the study examined and analyzed cases of Japanese nuclear power plants and domestic nuclear power plants, and also carried out an on-site survey in the sites in which nuclear power plants would be constructed to extract concrete colors through the analyses of their natural environment and actual conditions. The study also carried out a survey of residents in the regions to induce their participation, and reflected the survey results to the coloring plan. The study is expected to create a stable and friendly image of the nuclear power plant through materializing its environment-friendly image and remove negative recognition that the people have on the nuclear power plant. It also attempted an external environment-coloring plan a s a strategic means for positive publicity and through this, is expected to ultimately contribute to the creation of the new images of nuclear ower plants.

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Analysis of Flumeqnine in Meats (식육 중 항생제 flumequine의 분석)

  • Kuk, Ju-Hee;Ko, Yong-Seok;Kim, Yong-Hoon;Yoon, Chang-Yong;Sun, Nam-Kyu;Kim, Eun-Jung;Seo, Jee-Woo;Park, Ji-Won;Kang, Kil-Jin
    • Korean Journal of Food Science and Technology
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    • v.41 no.1
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    • pp.7-10
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    • 2009
  • An analytical method for the determination of flumequine in meats was developed and validated using high-performance liquid chromatography with fluorescence detection. The samples were mixed with sodium sulfate and extracted with ethyl acetate. After clean-up, the residues were dissolved in mobile phase. The calibration curves showed high linearity ($r^2$=0.9979) within the concentration range of 0.1-1.0 mg/kg. The limit of detection and limit of quantification were validated at 0.005 and 0.017 mg/kg, respectively. The recoveries in fortified meats ranged from 90.8 to 101.1%. The method was then validated in correspondence with the CODEX guidelines for flumequine residue in meats. Herein we monitored 150 samples of meats that were purchased in Korea (Seoul, Busan, Daegu, Daejeon, and Gwangju). Among the tested samples, flumequine was detected in 1 of beef and 1 of pork at levels in the range of 0.048-0.080 mg/kg. Overall, the flumequine residues in the tested samples were within the Maximun residue limit.

Influence of Polycyclic Aromatic Hydrocarbons Formation in Sesame Oils with Different Roasting Conditions (참깨의 볶음 조건이 참기름 중 polycyclic aromatic hydrocarbons 생성에 미치는 영향)

  • Seo, Il-Won;Nam, He-Jung;Shin, Han-Seung
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.355-361
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    • 2009
  • Polycyclic aromatic hydrocarbons (PAHs) are environmental carcinogenic compounds that arise by several means including food processing methods such as smoking and direct drying and cooking. This study examined the concentration of PAHs in sesame oils with various roasting temperatures (190, 220 and $250^{\circ}C$), methods (direct heating vs. indirect hot air heating), and times (5, 10, 15, 20 and 25 min). The PAHs in the sesame oils were analyzed using liquid-liquid extraction and solid-phase clean up (Florisil), followed by HPLC with fluorescence detection. According to the results, mean levels of total PAHs increased when the sesame oils were roasted at increasing temperatures and times. The sesame oil roasted at $250^{\circ}C$ for 25 min had the highest mean value of total PAHs (4.66 ${\mu}g$/kg). The results of this study suggest that the indirect hot air roasting method decreased PAH formation during sesame oil processing.

A Study on the Emissions Characteristics of a LPG Vehicle According to Various Test Modes and Ambient Conditions (다양한 시험모드와 환경조건에 따른 LPG 차량의 배출특성 연구)

  • Lee, Min-Ho;Ha, Jong-Han
    • Journal of the Korean Institute of Gas
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    • v.19 no.4
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    • pp.1-7
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    • 2015
  • As the interest on the air pollution is gradually rising up at home and abroad, automotive and fuel researchers have been working on the exhaust emission reduction from vehicles through a lot of approaches, which consist of new engine design, innovative after-treatment systems, using clean (eco-friendly alternative) fuels and fuel quality improvement. This research has brought forward various main issues : whether PM emissions should be regulated for diesel and gasoline vehicles and whether gasoline and LPG powered vehicles can be further neglected from PM emission inventories. Finally, the greenhouse gas regulation has been discussed including automotive emission regulation. The greenhouse gas and emissions of automotive had many problem that cause of ambient pollution, health effects. Based on various test modes and ambient conditions, this paper discusses the characteristics of LPG on exhaust emissions and greenhouse gases. Also, this paper assessed emission characteristics due to the test temperature. These test temperature were performed by dividing the temperature of the test mode and the lowest local temperature in winter. Through this study, the correlation of vehicle test mode and ambient condition, exhaust emission, greenhouse gas emission was analyzed.

Comparing Exhaust Gas Emission and PN in LPG and CNG Vehicle under FTP-75 and WLTC Test Mode (FTP-75, WLTC 시험 모드에서 LPG, CNG 자동차의 배출가스 및 PN 비교)

  • Jang, Jinyoung;Lee, Youngjae;Kwon, Ohseok;Kim, Jeonghwan
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.9-15
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    • 2016
  • Liquefied petroleum gas (LPG) and compressed natural gas (CNG) are often used as fuel for vehicles because they are clean alternative gas fuels. CNG, as a low-carbon fuel, can contribute to the reduction of greenhouse gas emissions. LPG is often used as fuel for taxis because the performance is almost the same as that of gasoline but the price is lower. In the present study, the exhaust gas and the particle number (PN) of particulate matter, which is a recent environmental issue, were compared between LPG and CNG for the same vehicle. A chassis dynamometer was used to conduct the test according to the Federal Test Procedure (FTP)-75 and Worldwide harmonized Light-duty vehicle Test Procedure (WLTC) modes. The PN values of discharged particles having sizes of 5 nm or larger and 23 nm or larger were measured using two condensation particle counters (CPC). The ratio of carbon dioxide was high in the exhaust gas from the LPG vehicle; the ratio of methane was high in the exhaust gas from the CNG vehicle. The PN values of the emitted particles from the two fuels were similar. The PN values of particles having sizes of 23 nm or smaller were high in the high-speed WLTC mode.