• 제목/요약/키워드: Circulating Fluidized Bed Combustion

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바이오매스 순환유동층 연소에서 CaSO4 환원반응에 의한 파울링 발생 방지 연구 (A Study on Prevention of Fouling Formation by Reduction Reaction of CaSO4 in a Biomass Circulating Fluidized Bed Combustion)

  • 김성주;박성진;조성호;홍세화;문용일;문태영
    • 신재생에너지
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    • 제19권1호
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    • pp.1-11
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    • 2023
  • A large amount of carbon monoxide (CO) is generated in circulating fluidized bed combustion, the process whereby a hot cyclone separates unburned fuel. However, calcium sulfate (CaSO4), when combined with a high CO content, can cause fouling on the surface of the steam tube installed inside the integrated recycle heat exchangers (INTREX). In this study, CaSO4 decomposition was investigated using 0.2-3.2 vol.% CO and 1-3 vol.% oxygen (O2) at 850℃ for 20 min in a lab-scale fluidized bed reactor. The results show that CaSO4 decomposes into CaS and CaO when CO gas is supplied, and SO2 emissions increase from 135 ppm to 1021 ppm with increasing CO concentration. However, the O2 supply delayed SO2 emissions because the reaction between CO and O2 is faster than that of CaSO4; nevertheless, when supplied with CaCO3, the intermediate product, SO2 was significantly released, regardless of the CO and O2 supply. In addition, agglomerated solids and yellow sulfur power were observed after solid recovery, and the reactor distributor was corroded. Consequently, a sufficient O2 supply is important and can prevent fouling formation on the INTREX surface by suppressing CaSO4 degradation.

순환유동층에서 유동매체량에 따른 수력학적 특성 연구 (Effect of Solid Mass Inventory on Hydrodynamics Characteristics in a Circulating Fluidized Bed)

  • 김은경;신동훈;이종민;김재성;황정호
    • 한국연소학회지
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    • 제7권4호
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    • pp.10-20
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    • 2002
  • This paper discusses effect of solid mass inventory on the hydrodynamic characteristics of circulating fluidized bed(CFB). Operating parameters of solid mass inventory and air flow rates were varied to understand their effects on fludization pattern. Experimental measurements were made in a CFB of which height and diameter are 3m and 0.05m respectively. Black SiC particles ranging from $100{\mu}m\;to\;500{\mu}m$ were employed as the bed material. Superficial gas velocity of riser and J-valve fluidizing velocity were in the ranges of $1.39{\sim}3.24m/s\;and\;0.139{\sim}0.232m/s$, respectively. The axial solid fraction and solid circulation rate of CFB were calculated based on the experimental data and compared with modellings through IEA-CFBC Model and commercial CFD code.

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Comparison of Heat Transfer in Both the Riser and Downcomer of a Circulating Fluidized Bed

  • Hassanein, Soubhi A.;Dahab, O.M.
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.24-32
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    • 2004
  • The characteristics of heat transfer from horizontal cylinder immersed in both a riser and downcomer of a circulating fluidized beds were investigated experimentally under different values of solids mass flux, superficial air velocity, particle size diameter, and different bed materials. The test results indicated that local heat transfer coefficients in both riser and downcomer are strongly influenced by angular position, and mass flux, as well as by particle size and bed materials. The local heat transfer coefficients around a circumference of the cylinder inside a riser and downcomer of a CFB exhibited a general tendency to increase with decreasing particle size and increasing solids mass flux and vary with different bed materials. Also the averaged heat transfer coefficient calculated from local heat transfer coefficient exhibited the same trend as a local i.e increase with decrease particle size and increasing solids mass flux and vary with varying bed materials. The general trend for a riser local heat transfer coefficient is decrease with increase angle until ${\Phi}$ = 0.5-0.6 (Where at angle =180$^{\circ}$ ${\Phi}$ =1). Also the general trend for a local heat transfer coefficient in downcomer is to increase with increase the angle until ${\Phi}$= ${\theta}/{\Pi}$ = 0.3-0.5 (Where at angle =180$^{\circ}$ ${\Phi}$ =1). Comparison the results of the heat transfer in the riser and downcomer of a circulating fluidized beds shows that they have approximately the same trend but the values of heat transfer coefficients in riser is higher than in downcomer.

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300 MW 급 유동층보일러에서 적정 층 물질량 산정 (Allowable Amount of Bed Inventory in a 300 MW Class Circulating Fluidized Bed Boiler)

  • 김우용;유호선
    • 플랜트 저널
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    • 제14권2호
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    • pp.33-38
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    • 2018
  • 본 연구에서는 순환유동층보일러의 베드가 과열되어 층 물질의 소결이 발생하고 노 내 유동물질에 의해 보일러튜브가 마모 되는 것을 최소화하기 위하여, 노 하부 베드의 층 물질량 조정을 통한 베드 온도 변화를 실험적으로 연구하였다. 실험은 300MW급 순환유동층보일러인 여수화력 2호기를 대상으로 하였으며 터빈출력, 석탄소비량, 공기량 등을 고정한 상태에서 층 물질 양을 감소시켜 베드 압력을 설계값 4.5KPa에서 2.5KPa까지 감소시켰다. 결론적으로 층 물질 양을 적정하게 줄이면 베드 온도가 저하 되나, 지속적으로 저하되지 않는 것을 확인 하였으며, 베드 압력 3.0KPa, 즉 베드 물질량 110 톤을 변곡점으로 하여 베드 온도는 상승하기 시작하였다. 층 물질량이 충분히 많은 상태에서, 층 물질량이 감소되면 베드 온도는 저하되며, 층 물질량이 적정량 보다 적으면 노 내 유동물질의 순환량 감소로 베드 온도는 상승함을 알 수 있었다. 또한 유동층보일러에서 베드 온도 변화는 단순히 층 물질의 양 뿐만 아니라, 보일러 용량 및 연료의 성상 등에 따라 변화 추이가 매우 다양하게 나타난다는 것을 알 수 있었다.

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알칼리 자극제 NaOH의 첨가율에 따른 고로슬래그 기반 경화체의 강도 특성 (Strength Properties of Blast Furnace Slag-based Hardened Materials with Addition Rate of Alkali Stimulant NaOH)

  • 경석현;최병철;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.135-136
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    • 2019
  • Recently, as the interest in environmental issues increases, the construction industry needs to recycle blast furnace slag, circulating fluidized bed Combustion fly ash, etc. to solve industrial by-products, and to develop artificial stone. In this study, the strength characteristics based on blast furnace slag according to the addition rate of alkali stimulant NaOH are investigated. The experimental results showed that the flexural and compressive strengths increased with the addition of alkali stimulants. Based on these results, it will be presented as a basic research data for the manufacture of artificial stone and will be tested later.

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국내 순환유동층보일러(Circulating fluidized bed combustion) 석탄재의 희토류 농축 (Enrichment of Rare Earth Elements Contained in Coal Ashes from Korea Circulating Fluidized Bed Combustion (CFBC))

  • 김영진;최문관;서준형;김병렬;조계홍
    • 자원리싸이클링
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    • 제29권6호
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    • pp.125-132
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    • 2020
  • 국내 순환유동층보일러형 발전소 석탄재의 주요 광물 및 희토류의 이동특성을 분석하여 석탄재 중 희토류 성분의 농축 가능성 검토를 위해 체 분리 및 침출을 통한 주요 광물의 분리 및 제거에 따른 희토류 성분의 이동특성을 평가하였다. 석탄재의 주요 광물로는 경석고, 자철석 및 석영으로 확인되었으며, 세계 석탄재 희토류 평균값(404 ppm)의 30% 수준 함량으로 확인되었다(실험대상: 123 ppm). 석탄재에 포함된 희토류 성분 중 90% 이상은 주로 자철석과 함께 이동하는 특성을 보였고, 10% 이하의 성분이 석영과 함께 이동하는 것으로 확인되었다. 이는 발전소 연소 방식 차이에 따라 발생된 석탄재 특성에 따른 영향으로 판단된다. 이에 국내 순환유동층보일러 석탄재로부터 희토류 성분 농축을 위해서는 자철석 분리가 필요하며, 이와 관련된 선별 기술 개발 및 확보가 요구된다고 판단된다.