• Ocean and Polar Research
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• v.40 no.4
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• pp.281-288
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• 2018

The transmission of solar light according to the distribution of chromophoric dissolved organic matter (CDOM) was measured in the Pacific Arctic Ocean. The Research Vessel Araon visited the ice-covered East Siberian and Chukchi Seas in August 2016. In the Arctic, solar [ultraviolet-A (UV-A), ultraviolet-B (UV-B), and photosynthetically active radiation (PAR)] radiation reaching the surface of the ocean is primarily protected by the distribution of sea ice. The transmission of solar light in the ocean is controlled by sea ice and dissolved organic matter, such as CDOM. The concentration of CDOM is the major factor controlling the penetration depth of UV radiation into the ocean. The relative CDOM concentration of surface sea water was higher in the East Siberian Sea than in the Chukchi Sea. Due to the distribution of CDOM, the penetration depth of solar light in the East Siberian Sea (UV-B, $9{\pm}2m$; UV-A, $13{\pm}2m$; PAR, $36{\pm}4m$) was lower than in the Chukchi Sea (UV-B, $15{\pm}3m$; UV-A, $22{\pm}3m$; PAR, $49{\pm}3m$). Accelerated global warming and the rapid decrease of sea ice in the Arctic have resulted in marine organisms being exposed to increased harmful UV radiation. With changes in sea ice covered areas and concentrations of dissolved organic matter in the Arctic Ocean, marine ecosystems that consist of a variety of species from primary producers to high-trophic-level organisms will be directly or indirectly affected by solar UV radiation.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.898-905
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• 2019

As the positive feedback between the absorption of chromophoric dissolved organic matter (CDOM) and acceleration of ice melt can impact the aquatic biota and dynamic heat budget, long-term monitoring of the CDOM variation in the polar ocean is necessary. However, the monitoring of CDOM is not easy because of harsh weather and difficult access, especially in the Antarctic Ocean. Therefore, the purpose of this study was to find a suitable long-term monitoring site for CDOM variation; we selected Maxwell Bay and Marian Cove at Sejong Base and horizontal and vertical distributions of CDOM were measured. After a 72 hr time-series measurement test of the CDOM variation at Sejong Dock and Sejong Cape in Maxwell Bay, Sejong Dock was selected, as it does not haveland discharge effects. The seasonal variation of CDOM was evident and the average CDOM concentration of Maxwell Bay was comparable with the adjacent sea. The CDOM at Sejong Dock from February to November 2010 was the highest in the fall and winter and the lowest during spring and summer. Thus, based on our one-year CDOM data, we suggest that Sejong Dock in Maxwell Bay is suitable for long-term monitoring of CDOM as an indicator of photochemical and biological environmental change and an important factor in determining the heating budget in the Antarctic Ocean.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.5
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• pp.712-720
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• 2022

In this study, we evaluated the production and photoreactivity of CDOM of two polar phytoplanktons - Phaeocystis antarctica and Phaeocystis pouchetii, in order to find out UV effects on phytoplanktons. In visible region, CDOM in media of both phytoplanktons under UV-R decreased during 48hrs incubation period. However, in UV region CDOM decreased 30 % in the media of P. antarctica, but increased 10% in media of P. pouchetii, compared to CDOM concentrations of control after 48 hr incubation. This result indicates that biota in polar environment would not well protected from UV-R harmful effect when P. antarctica is dominant because of loss of CDOM, but when P. pouchetii is dominant species, production of UV absorbing organic matter could play more efficiently for UV screening for marine biota. Also we confirmed that FDOM of humic substance (C-peak) produced by these phtoplanktons under UV-R stress were well matched with fluorescence characteristics of the UV-protecting compound, MAAs. This finding shows that Phaeocystis pouchetti with low photoreactivity would contribute to DOM pool of polar marine environment under stratification by global warming.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.85-85
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• 2021

CDOM(Colored or Chromophoric Dissolved Organic Matter)은 바다, 호수 및 강에서 담수, 오수, 퇴적물 등으로부터 공급된 유기물질의 일종으로 가시광선에서 빛을 흡수하는 성질을 가지며, 2016년부터 환경부에서 선정한 하천, 호수 등 방류수의 수질오염 표준인 TOC(Total Organic Carbon)를 간접 추정할 수 있는 매개변수가 될 수 있다. 따라서, 본 연구에서는 백제보 상류 23 km 구간을 대상으로 2개년(2016~2017) 중 7일의 초분광영상 자료를 활용하여 내륙지역의 CDOM에 대한 적정 반사도 밴드값(R_rs)과 CDOM을 추정하는 알고리즘을 개발하고자 한다. CDOM은 흡수계수(α_CDOM)를 통해 간접 추정되며, 흡수계수의 기준 파장값(λ)은 연구별로 350 nm, 375 nm, 400 nm, 412 nm 및 440 nm 등 다르게 나타난다. 초분광영상은 AsaFENIX 초분광 센서에서 관측된 380~970 nm까지 4 nm 간격, 127개 대역의 분광해상도와 2 m의 공간해상도를 가진 영상을 활용하였으며, 자료의 연속성을 위해 smoothing 기법을 활용하여 가공하였다. 추정 알고리즘은 Random forest를 활용하였으며, 70%의 trainning과 30%의 test로 구분하여 적용하였다. 산출된 CDOM은 결정계수(R²), Nash-Sutcliffe efficiency(NSE)를 이용하여 실측 CDOM과 비교하였다. 흡수계수별 CDOM의 산정 결과 α_CDOM(350 nm)의 trainning, test에서 각각 R²가 0.71, 0.74, NSE가 0.25, 0.49로 가장 높았으며, 적정 반사도 밴드값은 R_rs(466), R_rs(493), R_rs(548), R_rs(641)를 사용하였을 때 trainning, test에서 각각 R²가 0.93, 0.90, NSE가 0.85, 0.69로 가장 높게 나타났다.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.46-46
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• 2022

유기물의 복잡한 혼합물인 CDOM(Colored or Chromophoric Dissolved Organic Matter)은 하천 내 BOD(Biological Oxygen Demand), COD(Chemical Oxygen Demand) 및 유기 오염물질과 상당한 관련이 있다. CDOM은 가시광선 영역에서 빛을 흡수하는 성질을 가지고 있으며, 최근 원격감지 기술로 CDOM을 모니터링하기 위한 연구가 진행되고 있다. 본 연구에서는 백제보 상류 23km 구간에서 3년(2016~2018) 중 13일의 초분광영상을 활용하여 머신러닝 기반 CDOM을 추정 알고리즘을 개발하고자 한다. 초분광영상은 400~970 nm의 범위의 4 nm 간격 127개 대역의 분광해상도와 2 m의 공간해상도를 가진 항공기 탑재 AsiaFENIX 초분광 센서를 통해 수집하였으며 CDOM은 Millipore polycarbonate filter (𝚽47, 0.2 ㎛)에서 여과된 CDOM 샘플 자료를 200~800 nm의 흡수계수 스펙트럼으로 추출하여 사용하였다. CDOM 값은 전체기간 동안 2.0~11.0 m^-1의 값 분포를 보였으며 5 m^-1이상의 고농도 구간 자료개수가 전체 153개 샘플자료 중 21개로 불균형하다. 따라서 ADASYN(Adaptive Synthesis Sampling Approach)의 oversampling 방법으로 생성된 합성 데이터를 사용하여 원본 데이터의 소수계층 데이터 불균형을 해결하고 모델 예측 성능을 개선하고자 하였다. 생성된 합성 데이터를 입력변수로 하여 ANN(Artificial Neural Netowk)을 활용한 CDOM 예측 알고리즘을 구축하였다. ADASYN 기법을 통한 합성 데이터는 관측된 데이터의 불균형을 해결하여 기계학습 모델의 CDOM 탐지 성능을 향상시킬 수 있으며, 저수지 내 유기 오염물질 관리를 위한 설계를 지원하는데 사용할 수 있을 것으로 판단된다.

• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.5
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• pp.553-568
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• 2018

Chromophoric Dissolved Organic Matter (CDOM) plays a dominant role in absorbing UV-VIS light and is also important in the biogeochemical carbon cycle due to the production of carbon dioxide from photo-oxidation at the sea surface in marine environments. Since absorption by CDOM was recently found to be responsible for increasing the energy absorbed in the mixed layer by 40 % over pure seawater, the importance of CDOM absorption in seawater for increasing sea surface temperature has come to be well recognized. We measured aCDOM and the absorption characteristics of CDOM during spring 2012 and 2014 in the southwestern East Sea. Distribution of CDOM in spring 2012 and 2014 was compared and S value was used to find the source of CDOM in the study area. As a result, the average $a_{CDOM}$ was $0.237m^{-1}$ ($0.009{\sim}0.988m^{-1}$) and the average S value was $16{\mu}m^{-1}$,which shows coastal properties. Also a positive correlation between Chl a and CDOM was observed ($r^2=0.34$), with an especially strong correlation near coastal stations. aCDOM in 2014 was about 40 % higher than aCDOM in 2012 during spring in the study area. This difference in aCDOM concentration resulted not only from annual variation but also from stratification and photobleaching in late spring 2012. This observation implies the possibility of flux of carbon dioxide into the atmosphere as a result of photo-oxidation in the East Sea.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.4
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• pp.362-371
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• 2016

The distribution patterns of Chromophoric Dissolved Organic Matter (CDOM) and the chemical characteristics of CDOM in the Seomjin river estuary were investigated in March, June and July 2012 in order to determine the spatial and temporal variability of CDOM along the salinity gradient considering the effects of mixing, nutrients and Chl a. The average CDOM values were $1.0{\pm}0.3m^{-1}$, $1.3{\pm}0.4m^{-1}$, and $1.4{\pm}0.3m^{-1}$ in March, June and July, respectively. A high concentration of CDOM (greater than $1.5m^{-1}$) was found at the head of the river which decreased towards the river mouth to as low as less than $0.5m^{-1}$. The average concentrations of CDOM increased from the dry season (March and June) to the wet season (July), and the average slope values ($S_{300-500}$), which were used as indicators of CDOM characteristics and sources, were in the range of $0.013-0.018m^{-1}$. The CDOM and $S_{300-50}$ values showed that not only the concentration of CDOM but also the chemical properties of DOM clearly changed between upstream and downstream in the Seomjin river. CDOM and FDOM showed a negative correlation with salinity ($R^2$ > 0.8), and CDOM was positively correlated with FDOM. Furthermore, the mixing pattern of CDOM was confirmed as conservative for all seasons. The main environmental factors influencing the concentration of CDOM was confirmed as conservative for all seasons. The main environmental factors influencing the concentration of CDOM were salinity (mixing) and water temperature, which meant the dilution of low CDOM seawater, was the controlling factor for the spatial distribution of CDOM. Increases in water temperature seemed to induce the production of CDOM during summer (June and July) through the biological degradation of DOM either by microbial activity or photo-degradation.