• 제목/요약/키워드: Chromium alloys

검색결과 103건 처리시간 0.02초

상이(霜異)한 Ceramometal System에 있어서 Nickel-Chromium합금과 도재(陶材)와의 결합강도(結合强度)에 관(關)한 비교실험연구(比較實驗硏究) (A Study of Bond Strength of Nickel-Chromium Alloys with Porcelain in Ceramometal System)

  • 김치영
    • 대한치과기공학회지
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    • 제7권1호
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    • pp.19-25
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    • 1985
  • In oder to compare and measure bond strength of ceramometal system with use of ceramco porcelain powder including SnO2 and uni metal, Rexillium III, Vera Bond as non precious alloys manufactured for porecelain-metal restorations. Total 24 test sample were constructed. All Test sample were measured with a Mitutoyo micrometer graduated to 0.01mm. It is as follows measured of thickness 3.3mm(metal : 1.1mm, porcelain: 2.2mm), width 12mm, length 30mm(porcelain 12mm x 12mm), Compared maximum bending stress test. The results obtained were as follows: 1. Bond strength of each metal with ceramco porcelain powder showed statistical significance.(P<0.05) 2. Vera Bond and uni metal, uni metal and Rexillium III revealed no statistical Significance.(P>0.05) Vera Bond and Rexillium III showed statistical significance.(P<0.05) 3. The order of maximum bending stress was Rexillium III, uni metal, vera Bond. The order of bond strength ratio making bending stress was Vera bond, uni metal, Rexillium III.

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크롬탄화물형 크롬백철 오버레이 용착금속에서의 $(Cr,\;Fe)_7C_3$의 경도특성 (Characteristics of Hardness of $(Cr,\;Fe)_7C_3$ in the Chromium-Carbide-Type Chromium White Iron Hardfacing Weld Deposits)

  • 백응률
    • Journal of Welding and Joining
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    • 제23권2호
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    • pp.75-80
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    • 2005
  • The effect of chemical constituents of $(Cr,\;Fe)_7C_3$ carbide phase on its hardness in the chromium-carbide type Cr white iron hardfacing weld deposits has been investigated. In order to examine $(Cr,\;Fe)_7C_3$ carbide phase, a series of filler metals with varying chromium contents was used. The alloys were deposited once or twice on a mild steel plate using the self?shielding flux cored arc welding process. The hardness of $(Cr,\;Fe)_7C_3$ carbide phase was measured by the micro-Vickers hardness test. It was shown that hardness of $(Cr,\;Fe)_7C_3$ carbide phase increased with increasing Cr content in $(Cr,\;Fe)_7C_3$ carbide phase. This behavior of the hardness of $(Cr,\;Fe)_7C_3$ carbide phase was explained by the types of chemical bonds that hold atoms together in $(Cr,\;Fe)_7C_3$ carbide phase.

티타늄 지대주와 비귀금속 합금사이의 갈바닉 부식에 의한 표면 거칠기 변화 평가 (Surface roughness changes caused by the galvanic corrosion between a titanium abutment and base metal alloy)

  • 이정진;송광엽;안승근;박주미
    • 대한치과보철학회지
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    • 제49권1호
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    • pp.65-72
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    • 2011
  • 연구 목적: 이 연구의 목적은 티타늄 지대주와 비귀금속 보철물이 접촉한 경우를 가정하여 이종 금속간 접촉에 의한 갈바닉 부식으로 인해 발생하는 표면 거칠기 변화를 비교, 평가하고자 하였다. 연구 재료 및 방법: 성분과 조성이 다른 3종의 Ni-Cr합금 (T3, Bella bond plus, Tilite)과 cp 티타늄 Grade 2를 이용하여 $13{\times}13{\times}1.5\;mm$의 크기로 시편을 각 군당 6개씩 제작하였다. 연마과정 후 절연 테이프로 직경 6 mm만을 노출시켜 potentiostat (Parastat 2273A)를 이용하여 동전위 분극 시험과 갈바닉 부식 시험을 시행하였으며, 표면 거칠기 측정기(Surftester SV-3000)를 이용하여 부식 전 후 거칠기를 평가하였다. 측정값을 paired t-test와 One-way ANOVA로 분석하였다. 결과: 티타늄과 접촉한 모든 Ni-Cr 시편의 표면 거칠기는 통계적으로 유의하게 증가하였다. 증가량은 베릴륨을 포함한 T3합금 ($0.016{\pm}.007\;{\mu}m$)이 가장 컸으며, 베릴륨을 포함하지 않은 Bella bond plus ($0.012{\pm}.003\;{\mu}m$), 티타늄을 첨가한 Tilite ($0.012{\pm}.002\;{\mu}m$)는 큰 차이를 보이지 않았다. 금속 종류에 따른 거칠기 증가는 유의한 차이를 보이지 않았다. 결론: 티타늄과 접촉한 비귀금속 합금은 갈바닉 부식에 의해 표면 거칠기가 증가하였다.

Corrosion and Sliding Properties of the Nickel-Based Alloys for the Valve Seats Application

  • Honda, Tadashi
    • Corrosion Science and Technology
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    • 제7권2호
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    • pp.92-98
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    • 2008
  • This paper describes the experiments of the corrosion and the sliding tests of the nickel-based alloys for the gate valve seating materials used at high pressure and temperature. The general corrosion rates and IGC susceptibility are tested in pressurized water at 533 K and 575 K and in Strauss test solution. The sliding tests have been done in pressurized water at 293 k, 473 K and 573 k. The alloys containing above 10% chromium may have the anti-corrosion properties that could be applied to the valve seats for the power plants. The good sliding performance and the good pressure tightness are obtained when the disc specimens that have hardness 500 to 600 Hv combined with the seat specimens that have hardness 250 to 410 Hv containing about 40 percent of iron. The large size gate valves sliding tests have certified the test results. The anti-wear properties of the seat alloy and the anti-IGC susceptibility of the disc alloy could be improved by the addition of silicon and niobium, respectively.

The Electrochemical Behavior of Ni-base Metallic Glasses Containing Cr in H2SO4 Solutions

  • Arab, Sanaa.T.;Emran, Khadijah.M.;Al-Turaif, Hamad A.
    • 대한화학회지
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    • 제56권4호
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    • pp.448-458
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    • 2012
  • In order to develop alloy resistance in aggressive sulphat ion, the corrosion behavior of metallic glasses $Ni_{92{\cdot}3}Si_{4.5}B_{32}$, $Ni_{82,3}Cr_7Fe_3Si_{4.5}B_{3.2}$ and $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$ (at %) at different concentrations of $H_2SO_4$ solutions was examined by electrochemical methods and Scanning Electron Microscope (SEM) and X-ray Photoelectron Microscopy (XPS) analyses. The corrosion kinetics and passivation behavior was studied. A direct proportion was observed between the corrosion rate and acid concentration in the case of $Ni_{92{\cdot}3}Si_{4.5}B_{32}$ and $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$ alloys. Critical concentration was observed in the case of $Ni_{82,3}Cr_7Fe_3Si_{4.5}B_{3.2}$ alloy. The influence of the alloying element is reflected in the increasing resistance of the protective film. XPS analysis confirms that the protection film on the $Ni_{92{\cdot}3}Si_{4.5}B_{32}$ alloy was NiS which is less protective than that formed on Cr containing alloys. The corrosion rate of $Ni_{82,3}Cr_7Fe_3Si_{4.5}B_{3.2}$ and $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$. alloys containing 7% and 13% Cr are $7.90-26.1{\times}10^{-3}$ mm/y which is lower about 43-54 times of the alloy $Ni_{92{\cdot}3}Si_{4.5}B_{32}$ (free of Cr). The high resistance of $Ni_{75.5}Cr_{13}Fe_{4.2}Si_{4.5}B_{2.8}$ alloy at the very aggressive media may due to thicker passive film of $Cr_2O_3$ which hydrated to hydrated chromium oxyhydroxide.

급속냉각한 Al-(1, 3, 5)Cr 합금의 조직에 미치는 기계적 합금화의 영향 (Effects of Mechanical Alloying on the Structure of Rapid Solidified Al-(1, 3, 5 )Cr Alloys)

  • 지태구;김완철
    • 열처리공학회지
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    • 제6권4호
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    • pp.194-203
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    • 1993
  • Rapid solidified splats Al-(1, 3, 5Cr) Alloys were produced by atomization-splat quenching method. Effects of mechanical alloying on the structure and mechanical properties of rapidly solidified Al-(1, 3, 5)Cr alloys were studied. Degree of mechanical alloying of Al-(1, 3, 5)Cr alloys can be determined by observing the microstructural refinement, microhardness and microstructure of Al-(l, 3, 5)Cr splats during processing. In the initial stage of mechanical alloying of the Al-(1, 3, 5)Cr splats fracturing of the grain boundaries occured first, followed after fracturing of zone A regions. Saturation hardness of Al-(1, 3, 5)Cr alloys increased proportionally with increasing concentration of the solute (Cr). Age hardening was not observed in these alloys. Decomposition temperature of Al-1Cr splats after mechanical alloying was higher than that of Al-5Cr splats. The density of $Al_7$ Cr precipitates increased proportionally with increasing chromium content, as a result, there was a transition to finely and spherically dispersed phase after mechanical alloying.

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Effect of Precipitate on the Electrochemical Potentiokinetic Reactivation Behaviors of Stainless Steels and Nickel Base Alloys

  • Wu, Tsung-Feng;Chen, Tzu-Sheng;Tsai, Wen-Ta
    • Corrosion Science and Technology
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    • 제2권2호
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    • pp.59-67
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    • 2003
  • Electrochemical potentiokinetic reactivation (EPR) tests are used to evaluate the degree of sensitization (DOS) of stainless steels and nickel base alloys. The validity of EPR test to detect DOS of these alloys, however, depends all the electrolyte composition employed. The existence of precipitates such as NbC, and TiC, etc. in the alloys also affects the reactivation behaviors of these alloys. In this investigation, the reactions involved during EPR processes are analyzed. In 0.5 M $H_2SO_4$+ 0.01 M KSCN electrolyte, a reactivation peak associated with the localized attack around NbC, different from that of intergranular corrosion, is observed for the solution annealed 347 SS. For solution annealed Alloy 600, matrix corrosion and localized attack around TiC with distinct anodic peaks appeared in the EPR curves are seen in the $H_2SO_4$+ KSCN electrolyte. With proper adjustment of elect rolyte composition, the contribution from intergranular corrosion, as a result of chromium carbide precipitation along the grain boundaries, can be distingui shed from the matrix and localized corrosion for the sensitized Alloy 600.