• 한국산업안전학회:학술대회논문집
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• 한국안전학회 1998년도 추계 학술논문발표회 논문집
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• pp.329-334
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• 1998

난연성을 지닌 고분자 물질중 Chlorosulfonated Polyethylene(CSPE; Hypalon)은 Polyethylene에 염소와 황을 첨가한 것으로 염소를 첨가함으로써 기름과 화염에 대한 저항성을 향상시키고, 황 또한 기름, 화염에 대한 저항을 향상시킬 뿐 아니라 인장강도를 크게 해서 기계적 강도를 향상시킨 것이다. CSPE는 염소량의 등급에 따라 Coating재료, 호스 구조재, Wire와 Cable의 피복재료등 여러 가지 용도로 많이 쓰이고 있으며 특히 염소함량이 35%인 CSPE(Hypalon-40)의 경우 열저항과 압출 특성이 우수하기 때문에 Cable의 피복재료로 많이 쓰이고 있다.

• Elastomers and Composites
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• 제27권4호
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• pp.255-261
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• 1992

Chlorosulfonated polyethylene(CSM) was moisture-cure after treating them with silane coupling agents such as ${\gamma}-mercapto$ propyl trimethoxy silane, ${\gamma}-glycidoxy$ propyl triethoxy silane and methyl triethoxy silane, 3-(trimethoxy silyl) propyl methacrylate and 3-thiocyanopropyl triethoxy silane. The cure reaction is composed two steps. The first is the reaction between chlorosulfonyl groups of CSM and silane coupling agents. The second is the formation of cross-links which are siloxane linkage. The linkage is formed by the condensation of silanol groups which are produced by the hydrolysis of alkoxysilyl groups. CSM was mixed with MPS etc., and dilaurate dilaurate as catalyst on two open mill and the compounds were lured in hot water at $70^{\circ}C$ Physical properties of moisture-cured CSM was measured. CSM was effectively moisture-cured and r-mercapto propyl trimethoxy silane and r-glycidoxy propyl trimethoxy silane were capable of the vulcanizing agents.

• Elastomers and Composites
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• 제10권1호
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• pp.33-55
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• 1975

• Elastomers and Composites
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• 제36권4호
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• pp.246-254
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• 2001

본 연구에서는 CSM 고무를 유화하기 위하여 계면화학적 성질을 이용한 반전유화법과 계면활성제로서 비이온 및 음이온 계면활성제를 혼합 사용하였다. 단독계면활성제를 사용하였을 때에는 에멀젼의 분리가 발생하였고, 비이온 계면활성제 Span 60과 음이온 계면활성제 SLS를 혼합 사용하는 경우에는 상의 분리가 발생하지 않았다. 그러므로 혼합계면활성제를 사용하여 제조한 에멀젼의 droplet size, 전단속도에 따른 점도 및 전단응력과 같은 유변학적 거동을 통하여 에멀젼의 안정성을 규명하였다. 혼합계면활성제의 양에 따라 droplet size는 감소하였고, 이에 점도는 증가하였으며, 전단속도에 따른 점도 및 전단응력 측정결과 각각 non-Newtonian 흐름인 shear thinning 거동과 항복응력 값을 보였다. 이러한 실험결과인 유변학적 거동으로부터 CSM 고무를 유화하기 위해서는 반전유화법과 혼합계면활성제를 사용함으로써 에멀젼의 안정성을 향상시켰음을 확인할 수 있었다.

• 공업화학
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• 제5권2호
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• pp.215-222
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• 1994

Chlorosulfonated polyethylene(CSM)은 수지의 toughness modifier로서 사용할 수 있다. CSM는 산소와 오존에 대해서 저항성이 클 뿐 아니라 가교 가능한 기능기인 sulfonyl chloride를 가졌기 때문에 금속 산화물에 의해 가교 될 수 있다. Polyvlnylchloride(PVC)는 물성이 좋을 뿐 아니라 값이 싼 plastic이기 때문에 널리 사용되는 범용수지이나 저온에서 충격강도가 약하고 빛과 산소 그리고 오존에 의해서 분해되어 물성을 떨어뜨리는 결점이 있다. 이런 결점을 개선하고저 PVC/CSM블렌드를 연구하였다. CSM함량 10~30%에서 현저한 toughening효과를 나타내었다. CSM을 블렌드함으로써 PVC의 내후성, 내오존성 및 기계적 성질이 개선되었으며 toughening효과를 SEM을 통하여 관찰하고 확인하였다.

• Elastomers and Composites
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• 제40권1호
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• pp.12-21
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• 2005

본 연구에서는 CSM 에멀젼의 물성을 향상시키고자 금속성 가교제인 magnesium carbonate 및 calcium hydroxide를 첨가하여 가교밀도, 열적특성, 표면자유에너지 그리고 인장강도, 파단신율 및 인열강도 특성을 고찰하였다, 금속성 가교제인 magnesium carbonate 및 calcium hyroxide 양이 증가함에 따라 CSM 에멀젼 필름은 가교밀도는 증가하였고, 이에 내수성과 $T_g$ 값도 증가하였다. 금속성 가교제로 magnesium carbonate를 첨가하였을 때 calcium hydroxide에 비해서 다소 높은 가교밀도와 $T_g$ 값을 보였다. 하지만 CSM 에멀젼 필름의 표면에너지 및 기계적 특성들은 다소 다른 거동을 보였다. Magnesium carbonate 0.75% 그리고 calcium hydroxide 1.0% 첨가한 경우가 가장 높은 표면 자유에너지 값과 인장강도 및 인열강도를 보였으나, 그 이상의 양을 첨가하였을 경우에는 오히려 감소함을 확인하였다. 그러므로 본 연구에서 CSM 에멀젼의 물성을 향상시키는데 적용되는 금속성 가교제로서 calcium hydroxide 보다 magnesium carbonate가 더 적당하며, 0.75% 첨가하였을 때 보다 향상된 물성을 얻을 수 있었다.

• Macromolecular Research
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• 제11권6호
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• pp.506-510
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• 2003

A Zn ion-coated nanosilica filler has been developed and tested, in chlorosulfonated polyethylene (CSPE) and polychloroprene (CR), as a vulcanizing activator, cum was reinforcing filler. In this study, ZnO was replaced by the Zn ion-coated nanosilica filler with an aim of studying the dual role of this nanofiller in CSPE and CR. In the case of CSPE vulcanizates, the presence of MgO deteriorated the state and rate of cure when the Zn ion-coated nanosilica filler was used, but in the case of CR it improved the state of cure and enhanced the modulus and tensile strength. The Zn ion-coated filler proved to be a better reinforcing-cum-curing agent than was externally added ZnO and NA-22 also proved to be a better curative in the presence of the Zn ion-coated nanosilica filler for both CSPE and CR.

• 방사선산업학회지
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• 제5권3호
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• pp.237-242
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• 2011

In this research, the radiation resistance of ethylene propylene rubber (EPR) and chlorosulfonated polyethylene (CSPE) which can be used as a insulating materials of for electrical cable in the nuclear power plant were investigated. EPR and CSPE were irradiated by ${\gamma}$-ray at various doses ranging from 50 to 500 kGy at room temperature in air. The irradiated EPR and CSPE was investigated in terms of activation energy, mechanical properties, and oxidation stability. The experimental results revealed that CSPE exhibited the higher radiation resistance in comparison to that of EPR.

• 전기학회논문지
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• 제66권5호
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• pp.800-805
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• 2017

The accelerated thermal ageing of CSPE (chlorosulfonated polyethylene) was carried out for 16.82, 50.45, and 84.09 days at $110^{\circ}C$, equivalent to 20, 60, and 100 years of ageing at $50^{\circ}C$ in nuclear power plants, respectively. As the accelerated thermally aged years increase, the insulation resistance and resistivity of the CSPE decrease, and the capacitance, relative permittivity and dissipation factor of those increase at the measured frequency, respectively. As the accelerated thermally aged years and the measured frequency increase, the phase degree of response voltage vs excitation voltage of the CSPE increase but the phase degree of response current vs excitation voltage decrease, respectively. As the accelerated thermally aged years increase, the apparent density, glass transition temperature and the melting temperature of the CSPE increase but the percent elongation and % crystallinity decrease, respectively. The differential temperatures of those are $0.013-0.037^{\circ}C$ and, $0.034-0.061^{\circ}C$ after the AC and DC voltages are applied to CSPE-0y and CSPE-20y, respectively; the differential temperatures of those are $0.011-0.038^{\circ}C$ and $0.002-0.028^{\circ}C$ after the AC and DC voltages are applied to CSPE-60y and CSPE-100y, respectively. The variations in temperature for the AC voltage are higher than those for the DC voltage when an AC voltage is applied to CSPE. It is found that the dielectric loss owing to the dissipation factor($tan{\delta}$) is related to the electric dipole conduction current. It is ascertained that the ionic (electron or hole) leakage current is increased by the partial separation of the branch chain of CSPE polymer as a result of thermal stress due to accelerated thermal ageing.

• 한국전기전자재료학회논문지
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• 제32권6호
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• pp.490-495
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• 2019

This study performs the thermal aging of chlorosulfonated polyethylene (CSPE) for 807.36 and 1,614.48 hours at $110^{\circ}C$, which is equivalent to 40 and 80 years of aging at $50^{\circ}C$ in nuclear power plants, respectively. Flat-type CSPEs were soaked in seawater for five days and then dried for five days at room temperature. Furthermore, the soaked CSPEs were cleaned for 5 days with fresh water and dried for 1,100 days at room temperature. Through this process, the log IV of the CSPEs decreases, whereas the dissipation factor of the CSPEs increases as thermally accelerated aged years increase at the measured frequency. Although the phase degree of the response voltage versus excitation voltage of the CSPEs increases, that of the response current versus excitation voltage decreases with the thermally accelerated aging. The thermal conductivity of the CSPEs increases slightly, but the thermal diffusivity does not vary with the thermally accelerated aged year increase. The displacement of the compressive strength of the CSPEs decreases gradually as the thermally accelerated aged years increase.