• Journal of the Korean Chemical Society
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• v.14 no.3
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• pp.201-206
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• 1970

Furfuryl acetate was chlorinated in presence of acetic acid using carbontetrachloride as the solvent. When the chlorination proceeded at the low concentration of acetic acid, the formation of the tetrachloride was more efficient than that of higher concentration. The chlorination done in presence of various Lewis acids such as aluminum chloride, hydrogen fluoride, and borontrifluoride could not give high yield of tetrachloride, but trichloride. In case of borontrifluoride and hydrogen fluoride, the decomposition of the reaction mixture was apparent. The results were discussed in terms of the stability of furfuryl nucleus towards an electron acceptor and the convenient procedure of preparing trichloro furfuryl acetate was described.

• Water for future
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• v.23 no.3
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• pp.363-371
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• 1990

Foundational experiments are conducted to examine the applicability of redox control in brak-point chlorination of ammonia on drinking water purification. Through the research, the behauial affects by ph and temperature to a chloromine forming reactions are evaluated. The possibility of redox control in breakpoint chlorination is recoguized by drawing up the titration curve in terms of redox potential and $C{\ell}_2$/N ratios.

• Textile Coloration and Finishing
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• v.13 no.4
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• pp.272-281
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• 2001

Shrink resist finishing of wool fabric was carried out with MONAMIN BTN shrink resist agent after chlorination with D.C.C.A.(dichloro isocyanuric acid). The purpose of this study is to investigate the effect of treating conditions, such as concentrations of D.C.C.A and MONAMIN BTN, pH of treating bath, dying times, curing times and temperatures, on shrink resist finishing. Mechanical properties of the treated fabric were measured by KES-FB system. The optimum chlorination of wool corresponds to 2∼3%(o.w.f.) of D.C.C.A. without rendering the damage on surface of wool fiber. Also it seems likely that the shirink resist finishing carried out at 2 ∼3%(o.w.f.) of MONAMIN BTN and pH 7∼8 of treating bath is effective in increasing a softness of hand.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.1
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• pp.55-61
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• 2013

The recovery of Zr from Zircaloy-4 (Zry-4) cladding hulls using a chlorination method was demonstrated for complete conversion of Zr into $ZrCl_4$. A chlorination reaction was performed by reacting Zry-4 hulls for 8 h under a 70 cc/min $Cl_2$ + 70 cc/min Ar flow at $380^{\circ}C$. The initial weight of the reactant (51.7 g) decreased to 0.49 g after 8 h of operation, which is only 0.95wt% of the initial weight. The weight of the total reaction products was 121.7 g with a high Zr purity of 99.80wt%. Fe and Sn were identified as major (0.18wt%) and minor (0.02wt%) impurities of the reaction products, respectively. It was also shown that Zr exhibited a high recovery ratio of 96.95wt% with a relatively small experimental loss of 2.34wt%. Observation of the reaction residues revealed that the chlorination reaction was dominant along the longitudinal direction, and surface oxide layers remained as reaction residues. The high purity and recovery ratio of Zr proposed the feasibility of the chlorination technique as an effective hull waste treatment method.

• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.121-126
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• 1997

Carbochlorination of fly ash with phosgene and mixture CO, $Cl_{2}$ were investigated. The results obtained with pure chlorine, and/or chlorination mixtures were presented.

• YAKHAK HOEJI
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• v.18 no.2
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• pp.145-156
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• 1974

P, P'-Hexachiorobitolyl, p, p-hexachlorobitolylketone and p, p' hexachlorobitolylthiourea were synthesized by the radical chlorination method of Hass and McBeer. Among these comppounds, l wormicidal activity of p.p'-hexachlorobitolythiourea was much most potent against Clonorchis sinensis than Hetol in vitro. In the process of the p, p'-biolyl chlorination, ${\alpha, \alpha, \alpha}$-trichlorobitolyl was not detected, but small amount of ${\alpha, \alpha, \alpha}$-dichlorobitolyl was detected. This compound was immediately converted bitolyl compounds were analyzed, linear relationship was observed between retention indices and number of chlorine in two series of odd and even numbered chlorine compounds.

• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1357-1359
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• 2012

• Advances in environmental research
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• v.4 no.3
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• pp.155-172
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• 2015

In this study, a complete set of recirculating cooling water system and the required instruments were built in a semi-industrial-scale and a 50 g/h ozone generation plant and a chlorine system were designed for cooling water treatment. Both chlorination and ozonation treatment methods were studied and the results were analyzed during two 45-days periods. The concentrations of ozone and chlorine in recirculating water were constant at 0.1 mg/lit and 0.6 mg/lit, respectively. In ozone treatment, by increasing the concentration cycle to 33%, the total water consumption decreased by 26% while 11.5% higher energy efficiency achieved thanks to a better elimination of bio-films. In case of Carbon Steel, the corrosion rate reached to 0.012 mm/yr and 0.025 mm/yr for the ozonation and chlorination processes, respectively. Furthermore, consumptions of the anti-corrosion and anti-sedimentation materials in the ozone cooling water treatment were reduced about 60% without using any oxidant and non-oxidant biocides. No significant changes in sediment load were seen in ozonation compared to chlorination. The Chemical Oxygen Demand of the blow-down in ozonation method decreased to one-sixth of that in the chlorination method. Moreover, the soluble iron and water turbidity in the ozonation method were reduced by 97.5% and 70%, respectively. Although no anaerobic bacteria were seen in the cooling water at the proper concentration range of ozone and chlorine, the aerobic bacteria in chlorine and ozone treatment methods were 900 and 200 CFU/ml, respectively. The results showed that the payback time for the ozone treatment is about 2.6 years.

• Korean Journal of Microbiology
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• v.31 no.3
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• pp.255-260
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• 1993

The Enterobacter cloacae biofilms developed on slide glasses and galvanized-iron coupons were applied to test the attached bacterial resistance to chlorination. The chlorine resistances of biofilm bacteria grown on the slide glasses and galvanized-iron coupons were 14 and 480 times that of the suspended bacteria, respectively. The chlorine resistance of particleattached bacterial populations was 48 times that of suspended bacterial populations. The biofilm bacterial densities developed on the slide glasses and galvanized-iron coupons which were immersed in the flowing tap water for 75 days were $4.75 {\times} 10^{4}$ and $1.12 {\times} 10^5 cfu/cm^{2}$ It is concluded that main mechanisms of enteric or HPC bacterial resistance to chlorination in tap waters are bacterial attachment or . adsorption to particles or bacterial aggregations and formation of biofilms on the inner wall of distribution systems by escaped bacteria from chlorination in water treatment processes, which results in bacterial regrowth in water distribution systems.

• Journal of Environmental Health Sciences
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• v.48 no.3
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• pp.167-175
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• 2022

Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.