• Title/Summary/Keyword: Chloride ion diffusion

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Finite Element Analysis of Chloride Ion Intrusion into Coastal Concrete Structure

  • Kim, Eun-Kyum;Shin, Chee-Bur;Yeau, Kyong-Yun
    • KCI Concrete Journal
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    • v.11 no.3
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    • pp.175-180
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    • 1999
  • In order to predict the onset of the corrosion of steel bars in concrete, a mathematical model was presented to observe the diffusion of chloride ion in aqueous phase, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete, and the chemical reaction or chloride ions with solid phase. The finite element method was employed to carry out the numerical analysis. The chlorides enetrating through the wall of the concrete structure from the external environment and the chlorides contained in the concrete admixture were confirmed to be two important factors to determine the onset of the corrosion of steel bars.

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Evaluation on the Chloride Ion Diffusion of Cement Matrix Replaced with Ground Calcium Carbonate (중질탄산칼슘을 혼합한 시멘트 경화체의 염소이온 확산특성 평가)

  • Jung, Ho-Seop;Lee, Seung-Tae;Kim, Jong-Pil;Park, Kwang-Pil;Kim, Seong-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.553-556
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    • 2006
  • Generally, concrete is one of the most widely used construction materials, because of its good durability to cost ratio. However, when subjected to severe environments its durability can significantly decline due to various harmful conditions. In this article, we would like to investigate a chloride ion diffusion of cement matrix with inert filler, which ground calcium carbonate(GCC). For the experimental results of the chloride ion diffusion, as the addition of GCC makes decreasing the permeability by micro-filler effect, the matrix of 5-15% ratio of replacement are superior to the GCC0 mortar matrix with respect to durability of cement matrix in this scope.

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Field Application of the Corrosion Protection Method for Marine Concrete with Nano-Silica (Nano-Sillica를 이용한 해양콘크리트 방식공법 현장 적용)

  • Kim, Kyoung-Min;Ryu, Dong-Woo;Park, Sang-Joon;Kim, Jong-Baek;Jo, Sung-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.399-400
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    • 2009
  • This study arranged the result corrosion inhibition using Nano-silica for efficient prevention to diffusion of chloride ion. For the results, significant difference was not found on slump and air content, and there were superior effect to preventing diffusion of chloride ion on hardened concrete. It seemed to be Nano-silica prevented diffusion of chloride ion.

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Chloride Ion Diffusion Coefficient and Compressive Strength of the Concrete Produced by Ready Mixed Concrete Company in Busan (부산지역 레미콘사의 콘크리트의 압축강도와 염소이온 확산계수)

  • Park, Dong-Cheon;Bang, Jung-Suk;Kim, Yong-Ro;Lee, Tae-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.11-12
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    • 2017
  • The properties of concrete produced by ready mixed concrete company in Busan were tested. Because the concrete was mixed with blast furnace slag and fly ash, the compressive strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design.

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Multi-dimensional models for predicting the chloride diffusion in concrete exposed to marine tidal zone: Methodology, Numerical Simulation and Application

  • Yang Ding;Zi-Xi He;Shuang-Xi Zhou
    • Computers and Concrete
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    • v.34 no.2
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    • pp.169-178
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    • 2024
  • To circumvent the constraints of time-consuming experimental methods, numerical simulation can be one of the most effective approaches to investigating chloride diffusion behaviors in concrete. However, except for the effect of the external environments, the transport direction of the chloride cannot be neglected when the concrete is exposed to the marine tidal zone, especially in certain areas of concrete members. In this study, based on Fick's second law, considering the effects of timevarying, chloride binding capacity, concrete stress state, ambient temperature, and relative humidity on chloride diffusion coefficient, the modified one-dimensional, two-dimensional, and three-dimensional novel modified chloride diffusion theoretical models were established through defining the current boundary conditions. The simulated results based on the novel modified multi-dimensional model were compared with the experimental results obtained from some previous pieces of literature. The comparing results showed that the modified multi-dimensional model was well-fitted with experimental data, confirming the high accuracy of the novel modified model. The experimental results in literature showed that the chloride diffusion in the corner area of the concrete structure cannot be simulated by a simple one-dimensional diffusion model, where it is necessary to select a suitable multi-dimensional chloride diffusion model for simulation calculation. Therefore, the novel modified multi-dimensional model established in this study has a stronger applicability for practical engineering.

Experimental Study of Chlorides Ion Diffusion Characteristics under Combined Condition of Chlorides and Sulfates (염해 및 황산염의 복합작용에 따른 염소이온 확산특성의 실험적 연구)

  • 오병환;김선우;정상화;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.413-418
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    • 2000
  • The test results on the deterioration process of concrete under single and combined action of chloride penetration have been obtained. Within the test period of 15 weeks, it is seen that the internally penetrated chloride ion contents are slightly less in the combined action of NaCI and $Na_2SO_4$ than the single action of NaCI. Also the theoretical prediction of chloride penetration based on measured diffusion coefficient agress well with the test data of single deterioration process but disagress with that of combined process. Therefore it should be needed that improved chloride diffusion model for the combined deterioration process.

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Effects of Carbonation on Chloride Diffusion Properties of Concrete (중성화가 콘크리트의 염소이온 확산특성에 미치는 영향에 관한 실험연구)

  • 오병환;강의영;정상화;김선우;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.429-432
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    • 2000
  • The studies on chloride diffusion of concrete have been done so far by many researchers. However, there are few studies on the effects of other attacks, like carbonation, on chloride diffusion properties. In this study, the experiments are carried out focusing on this by varying cement type, water to cement ratio and replacement of fly ash of concrete. The results show that carbonation attacks do not affect greatly chloride diffusion properties of plain concrete, while the different tendencies are exhibited for fly ash concrete. Therefore, it is desirable to consider the effects of carbonation attacks on the chloride diffusion model to predict accurately the penetration of chloride ion fly ash is partially replaced for cement.

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A Study on Chloride ion Diffusion in Cracked Concrete (균열이 발생한 콘크리트에서의 염화물 이온 확산에 관한 연구)

  • 배상운;박상순;변근주;송하원
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.677-682
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    • 2001
  • In this study, a method to evaluate diffusion coefficient of chloride ion in cracked concrete is proposed. For cracked concrete having either anisotropic or isotropic crack network, each crack of saturated concrete is considered as a V shape crack, and an effective diffusion coefficient is expressed with diffusion coefficients of cracked part and noncracked part and a so-called crack spacing factor. A comparison with experimental results shows that the diffusion coefficient for cracked concrete is accurately predicted by the effective diffusion coefficient. Prediction results also show that the cracks in concrete markedly change the diffusion properties and accelerate penetration of drifting species. The method in this paper can be effectively used to consider the effect of cracks on concrete diffusion coefficient of cracked concrete.

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Prediction of Corrosion Threshold Reached at Steel Reinforcement Embedded in Latex Modified Concrete with Mix Proportion Factor (배합변수에 따른 라텍스 개질 콘크리트 내에 정착된 보강철근의 부식개시시기 예측)

  • Park, Seung-Ki;Won, Jong-Pil;Park, Chan-Gi;Kim, Jong-Ok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.6
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    • pp.49-60
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    • 2008
  • This study were predicted the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC) which were applied the agricultural hydraulic concrete structures. Accelerated testing was accomplished to the evaluate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, the average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC were effected on the mix proportion factor including cement contents, latex content, and water-cement ratio. Especially, the average chloride diffusion coefficient, the corrosion threshold reached at reinforcement in LMC were affected by the all mix proportion factor.

Influence of Carbonation and Freezing-thawing on the Chloride Diffusion in Concrete (탄산화 및 동결융해 현상이 콘크리트 중의 염소이온 확산에 미치는 영향 연구)

  • Kim, Dong-Baek;Kwon, Ki-Jun;Jung, Sang-Hwa;Bok, Hoon
    • Journal of the Korean Society of Safety
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    • v.22 no.3 s.81
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    • pp.57-64
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    • 2007
  • Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.