• 콘크리트학회지
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• 제10권6호
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• pp.325-333
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• 1998

염화물에 의한 콘크리트 중의 철근부식을 억제하기 위하여 콘크리트 배합시 방청제를 사용하는 방안이 일반적으로 많이 사용되고 있으나. 국내에서는 아직까지 방청제의 방식효과에 대한 연구는 찾아보기 어려운 실정이다. 본 연구에서는 염화물의 영향을 받는 콘크리트 중의 철근부식 억제를 위한 방안으로 방청제를 사용하여 철근의 방청효과를 알아보기 위하여 3종류의 방청제와 각각 사용량을 변화시킨 시험체를 제작하여 부식촉진 실험을 실시하였으며, 철근의 자연전위와 부시면적율을 측정하여 방식효과에 대하여 평가하였다. 그 결과 염화물의 혼입량이 지나치게 많을 경우에는 방청제의 양을 증가시켜도 방청효과가 크게 향상되지 않았으나. 염화물의 혼입량을 동일하게 사용하고 방청제의 양을 증가시켜도 방청효과가 크게 향상되지 않았으나, 염화물의 혼입량을 동일하게 방청제의 양을 증가시킬 경우에는 방청효과가 현저하게 좋아짐을 알 수 있었다.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2006년도 추계학술대회 논문집
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• pp.1385-1390
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• 2006

Concrete structure can be deteriorated by ingress of moisture and aggressive agents. To maintain the sound performance of concrete structure during the service life, it needs to protect concrete from ingress of moisture and aggressive agents before arising deterioration of concrete. Protection of concrete is possible by surface treatment. In this study, durability of the functional nano composite inorganic activated carbon based coatings which can provide a barrier against the ingress of moisture or aggressive ions to concrete is discussed. For the durability evaluation of the coatings, fine void structure evaluation test, chloride penetration acceleration test, accelerated carbonation test, freezing and thawing test, and the accelerated test of chemical erosion are conducted. As the result of this study, the functional nano composite inorganic activated carbon based coatings which became one formed complex compound with adsorption and porosity on concrete surface, had an effect on the function of far infrared radiation, antimicrobial action, air cleaning, airing assurance, and the interception of moisture of deterioration factor, chloride ion, carbon dioxide, sulfate, and so on.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.687-692
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• 2003

In this study, durability of concrete whose surface were treated by nano-composite hybrid polymer type coatings, which can provide a barrier against the ingress of moisture or aggressive ions to concrete, is discussed. For the durability evaluation of the coated concrete, chloride ponding test, accelerating carbonation test, porosity measurement test, and the SEM test are conducted. As the result of this study, it is found that nano-composite hybrid polymer type coated concrete has a much higher resistance to the ingress of chloride ion, carbon dioxide, moisture and aggressive acid than plain concrete has.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2004년도 추계학술대회 논문집
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• pp.1014-1020
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• 2004

In this study, durability of the nano-level inorganic polymer based coatings which can provide a barrier against the ingress of moisture or aggressive ions to concrete is discussed. For the durability evaluation of the coatings, chloride penetration test, accelerating carbonation test, freezing and thawing test, and sulfate ponding test are conducted. As the result of this study, concrete applied nano-level inorganic polymer based coatings has a much higher resistance to the ingress of chloride ion, carbon dioxide, moisture and aggressive acid than plain concrete and epoxy resin based paint by means of crosslinking three-dimensional structure with concrete structure.

• 한국구조물진단유지관리공학회 논문집
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• 제26권2호
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• pp.18-27
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• 2022

본 연구에서는 해양 폭로 조건과 배합 사항을 고려하여 GGBFS 콘크리트의 시간의존적 염화물 확산 거동을 분석하였다. 사용 콘크리트 배합은 3 수준의 물-결합재 비 및 고로슬래그 미분말 치환률을 고려한 콘크리트 배합이며 노출 조건으로는 침지대, 간만대, 비말대 총 3 수준을 고려하여 옥외 폭로 시험을 수행하였다. 겉보기 염화물 확산계수 평가 결과, 고로슬래그 미분말의 치환률이 증가할수록 노출 기간 730일(2년)을 기준으로 평가한 확산계수의 감소율이 감소하였다. 또한 노출 조건에 따른 확산거동을 평가한 결과, 침지대, 간만대, 비말대 순으로 확산계수가 평가되었다. 비말대에서는 해수의 건습 반복으로 인해 비교적 높은 확산계수가 평가되었다. 본 연구에서는 고로슬래그 미분말 치환률이 겉보기 염화물 확산계수 감소 거동에 미치는 영향을 노출 조건 및 기간을 고려하여 분석하였다. 확산계수를 출력 값으로, 고로슬래그를 입력 값으로 설정한 선형 회귀분석을 수행하였으며, 노출 기간 730일 이후 고로슬래그 미분말이 확산계수에 미치는 영향이 크게 감소하였다. OPC 콘크리트라 할지라도 730일 이후 GGBFS 콘크리트 만큼 낮은 확산계수를 나타냈기 때문이며 고로슬래그 미분말의 사용을 통해 730일 이전에 뛰어난 초기 염해 내구성능 확보가 가능하다고 사료된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.699-704
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• 2003

Corrosion of reforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing method on the coefficient of chloride diffusion. Also, it is compared that the relationship between total chloride and free chloride in concrete. According to this experiment results, w/c ratio and testing method effect on chloride diffusion coefficient of concrete. As w/c ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different value, respectively. Also, the content of free chloride in 7days curing concrete is increased as w/c ratio is increased.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.229-232
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• 1998

Recently it has become general to use the inhibitor with a view to protecting corrosion of rebars in concrete. As the inhibitors used in construction works are almost made in America or Japan, we immediately need to begin home production of inhibitors. In this paper, to estimate the domestic anodic inhibitor of nitrite in comparison with foreign made inhibitor we made some fundamental experiments of setting time, slump and compressive strength. Besides, we analysed the effect of corrosion protection of inhibitor on the ground of corrosion current, resistance to chloride penetration and diffusion of chloride ingress in concrete.

• 한국안전학회지
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• 제19권3호
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• pp.89-94
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• 2004

Most reinforcements in concrete are constructed by steel. Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly professed by the chloride ingress. In general, chloride in concrete can be discriminated by two components, total chloride and fire chloride. This paper provides a testing method on the coefficient of chloride diffusion in concrete and the relationship between total chloride and free chloride in concrete for the composition of predicting model on diffusion rate of chloride. In order to complete this predicting model, this study will use chloride penetration characteristic, diffusion coefficient and experiment of color change on silver nitrate solution. This predicting model is going to help that grasp special quality on salt content inclusion of concrete structure that is exposed in chloride environment. Accurate predicting model can be effectively used not only in selecting of repair time but also in preventing from various deteriorations.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.281-284
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• 2003

When concrete structures are exposed under marine condition for a long time, the steel in concrete is corroded due to the ingression of chlorides in the sea water. Because the damages of corrosion resulting from the chloride ion are very serious, many research have been performed. In this study, it was experimentally investigated that the mechanical and diffusion characteristics of concrete substituted with ordinary portland cement, silica fume and blast furnace slag to investigate the chloride ingress characteristics with concrete quality. Chloride diffusion coefficients in concrete shows increasing tendency as w/c ratio increase. Also test results indicate that blend of admixture become lower chloride diffusion coefficients in concrete as compared with normal concrete.

• Computers and Concrete
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• 제3권6호
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• pp.401-422
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• 2006

A multi-species model based on the Nernst-Planck equation has been developed by using a finite volume method. The model makes it possible to simulate transport due to an electrical field or by diffusion and to predict chloride penetration through water saturated concrete. The model is used in this paper to assess and analyse chloride diffusion coefficients and chloride binding isotherms. The experimental assessment of the effective chloride diffusion coefficient consists in measuring the chloride penetration depth by using a colorimetric method. The effective diffusion coefficient determined numerically allows to correctly reproduce the chloride penetration depth measured experimentally. Then, a new approach for the determination of chloride binding, based on non-steady state diffusion tests, is proposed. The binding isotherm is identified by a numerical inverse method from a single experimental total chloride concentration profile obtained at a given exposure time and from Freundlich's formula. In order to determine the initial pore solution composition (required as initial conditions for the model), the method of Taylor that describes the release of alkalis from cement and alkali sorption by the hydration products is used here. Finally, with these input data, prediction of total and water-soluble chloride concentration profiles has been performed. The method is validated by comparing the results of numerical simulations to experimental results obtained on various types of concretes and under different exposure conditions.