• Title/Summary/Keyword: Chloride diffusion

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Studies on the Effect of Diffusion Process to Decay Resistance of Mine Props (간이처리법(簡易處理法)에 의한 갱목(坑木)의 내부효력(耐腐効力)에 관한 연구(硏究))

  • Shim, Chong Supp;Shin, Dong So;Jung, Hee Suk
    • Journal of Korean Society of Forest Science
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    • v.29 no.1
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    • pp.1-19
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    • 1976
  • This study has been made to make an observation regarding present status of the coal mine props which is desperately needed for coal production, despite of great shortage of the timber resources in this country, and investigate the effects of diffusion process on the decay resistances of the mine props as applied preservatives of Malenit and chromated zinc chloride. The results are as follows. 1. Present status of the coal mine props Total demand of coal mine props in the year of 1975 was approximately 456 thousand cubic meters. The main species used for mine props are conifer (mainly Pinus densiflora) and hardwood (mainly Quercus). Portions between them are half and half. With non fixed specification, wide varieties of timber in size and form are used. And volume of wood used per ton-of coal production shows also wide range from 0.017 cubic meter to 0.03 cubic meter. 2. Decay resistance test a) The oven dry weight decreased between untreated specimen and treated specimen has not shown any significantly, although it has shown some differences in average values between them. It may be caused by the shorter length of the test. b) The strength of compression test between untreated specimen and treated specimen has also shown the same results as shown in case of weight decrease. Reasons assumed are the same. c) The amounts of the extractives in one percent of sodium hydroxide (NaOH) between untreated and treated specimen have shown the large value in case of untreated specimen than that of treated. 3. The economical benifit between untreated and treated wood when applied in field has seen better in long term base in case of treated wood, although the primary cost of treated wood add a little bit more cost than that of the untreated wood.

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Durability Characteristics of Concrete Containing Lightly Burnt MgO Powder (저온 소성한 MgO 분말을 혼입한 콘크리트의 내구 특성)

  • Choi, Seul-Woo;Kim, Joo-Hyung;Lee, Kwang-Myong;Kwon, Yong-Gil;Jang, Bong-Seok
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.609-615
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    • 2011
  • MgO concrete containing lightly burnt MgO powder at $850{\sim}1,000^{\circ}C$ may have a long-term expansibility characteristic. Such expansibility of MgO concrete can compensate the shrinkage at later ages since the hydration of the MgO is very slow. However, the addition of MgO delays the initial hydration of cement and increases the setting time of cement. Also, the porosity and pore-size distribution of the MgO concrete are different from OPC concrete. Therefore, in order to use MgO in practice, both mechanical and durability properties of MgO concrete should be carefully examined. In this study, durability tests on carbonation, freezing-thawing, and diffusion of chloride were carried out after 56 days of underwater curing at $20^{\circ}C$ to compare durability characteristics of 5% MgO-mixed concrete with those of OPC concrete. The results showed that MgO concrete shows a greater durability than the concrete with no MgO, because the micro structure in the MgO concrete is much denser due to its expansibility characteristic.

Surface Mmodification of Poly(DL-lactide-co-glycolide) Nanoparticle (Poly(DL-lactide-co-glycolide) 나노입자의 표면 수식)

  • Oh, Yu-Mi;Jung, Taek-Kyu;Chi, Sang-Cheol;Shin, Byung-Cheol
    • Journal of the Korean Chemical Society
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    • v.47 no.6
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    • pp.601-607
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    • 2003
  • We studied on preparation of nanoparticles modified surface using biodegradable polymer, poly(DL-lactide-co-glycolide) (PLGA). Two kinds of PLGA nanoparticles were prepared by a spontaneous emulsification solvent diffusion (SESD) method using cetyltrimethylammonium chloride (CTAC) and tetradecyltrimethylammonium bromide (TTAB) as a cationic surfactant and polyethylene glycol-block-polypropylene glycol copolymer (Lutrol F68) as a nonionic surfactant. Model protein was coated on the surface of nanoparticles by the ionic complexation. The model protein was that influenza vaccine ($H_3N_2,\;H_1N_1$, B strain) labeled with NHS-fluorescein. The sizes of cationic nanoparticles were 140-160 nm and the surface charges were 50-60 mV. The sizes of nonionic nanoprticles were 80-90 nm and the surface charge was -10 mV. After coating vaccine on the surface of nanoparticles, the sizes of cationic nanoparticles were increased to 380-400 nm and the size of nonionic nanoparticles was not increased. The amount of coated vaccine on the cationic nanoparticles was 22.73 ${\mu}g$/mg.

The Property Evaluation of the Marine Concrete Structure Constructed in the Period of Japanese Occupancy (YoungDo Bridge) (일제시대 건설된 해양 콘크리트구조물의 물성 평가(영도대교))

  • Park, Dong-Cheon;Ahn, Jae-Cheol
    • Journal of Navigation and Port Research
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    • v.37 no.2
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    • pp.165-171
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    • 2013
  • YoungDo bridge is the first suspension bridge in Busan which experienced several times repair and reinforcement after completion in 1934. The bridge is under demolition for extension and restoration work since 2011. The purpose of this research is to establish data base about modern concrete. The mix design of the concrete is like that cement : fine aggregate : coarse aggregate = 1 : 2 : 4 or 1 : 3 : 6 by the parts. The compressive strength is in the ranges from 50 to 55 MPa and the elastic modulus is in the ranges from 25 to 35 GPa. From the fact that the deviation is less than 10 %, considerably high quality control was conducted in those days. The carbonation depth is 5.92 cm at the bridge post and 14.3 cm at the machine room. That is why ocean environment keeps the high humidity. The diffusion coefficient of chloride ion through the pores in concrete is 1.052e-12 $m^2/s$ from the regression analysis using the experiment data. The water cement ration is estimated at approximately 35 % in case if the concrete using ordinary Portland cement.

Characterization of Durability and Deterioration Eroded by Chemical Attack on the Concrete Lining in Conventional Tunnel (화학적 침식을 받은 재래식 터널 콘크리트 라이닝의 내구성능 및 열화특성)

  • Kim, Dong-Gyou;Lee, Seung-Tae;Jung, Ho-Seop
    • Journal of the Korean Geotechnical Society
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    • v.23 no.12
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    • pp.25-32
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    • 2007
  • This study is to evaluate the effect of chemical attack on durability and deterioration of lining concrete in tunnel. Surface examination, nondestructive inspection, uniaxial compressive strength test, carbonation test, chloride diffusion test, micro-structural analysis were performed to analyze the deterioration of lining concrete in tunnel constructed 70 years ago. From surface examination results, the tunnel had been repaired and reinforced in several times. It has many cracks, water-leakage, efflorescence and exploitation. Compressive strengths obtained from nondestructive inspection and uniaxial compressive strength test have measured $17.5{\sim}34.7MPa$, and $12.8{\sim}40.3MPa$, respectively. Carbonation depth specimen cored from concrete lining has ranged from 3mm to 27mm. From chloride diffusion test, most specimens have low permeability. And the XRD analysis was able to detect ettringite and thaumasite, which were confirmed by SEM and EDS results to be the causes for the deterioration of lining concrete.

Ground-based model study for spaceflight experiments under microgravity environments on thermo-solutal convection during physical vapor transport of mercurous chloride

  • Choi, Jeong-Gil;Lee, Kyong-Hwan;Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.6
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    • pp.256-263
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    • 2007
  • For $P_B=50Torr,\;P_T=5401Torr,\;T_S=450^{\circ}C,\;{\Delta}T=20K$, Ar=5, Pr=3.34, Le=0.01, Pe=4.16, Cv=1.05, adiabatic and linear thermal profiles at walls, the intensity of solutal convection (solutal Grashof number $Grs=7.86{\times}10^6$) is greater than that of thermal convection (thermal Grashof number $Grt=4.83{\times}10^5$) by one order of magnitude, which is based on the solutally buoyancy-driven convection due to the disparity in the molecular weights of the component A ($Hg_2Cl_2$) and B (He). With increasing the partial pressure of component B from 20 up to 800 Torr, the rate is decreased exponentially. It is also interesting that as the partial pressure of component B is increased by a factor of 2, the rate is approximately reduced by a half. For systems under consideration, the rate increases linearly and directly with the dimensionless Peclet number which reflects the intensity of condensation and sublimation at the crystal and source region. The convective transport decreases with lower g level and is changed to the diffusive mode at $0.1g_0$. In other words, for regions in which the g level is $0.1g_0$ or less, the diffusion-driven convection results in a parabolic velocity profile and a recirculating cell is not likely to occur. Therefore a gravitational acceleration level of less than $0.1g_0$ can be adequate to ensure purely diffusive transport.

Evaluation of Durability Characteristics of High Performance Shotcrete Using Fly Ash (폐석탄회를 이용한 고성능 숏크리트의 내구특성 평가)

  • Park, Cheol-Woo;Lee, Hyeon-Gi;Kang, Tae-Sung
    • Journal of the Korea Concrete Institute
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    • v.22 no.3
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    • pp.305-311
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    • 2010
  • The industrial by-product market has increased at a geometric rate worldwide with the rapid economic growth. At present time, conventional disposal methods of industrial by-products in Korea including landfill, incineration and storage already have reached their limits. In this study, the industrial by-products such as fly ash and silicafume were used as mineral admixtures, which are commonly added to concrete mix to inhance the economic efficiency, long-term strength and durability of concrete, to determine the optimized mix proportion of high performance shotcrete. Through the series of tests (compressive strength test, accelerated chloride ion penetration test, measurement of chloride diffusion coefficient). The results of the study showed that the proposed mix proportions satisfied the requirements of domestic as well as international guidelines for shotcrete, with a higher durability than the existing shotcrete.

Screening of an Antagonistic Bacterium for Control of Red-pepper Anthracnose, Colletotrichum gloeosporioides (고추탄저병균 Colletotrichum gloeosporioides의 방제를 위한 길항 미생물의 분리 및 항진균 활성)

  • Park Sung-Min;Jung Hyuck-Jun;Yu Tae-Shick
    • Journal of Life Science
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    • v.16 no.3 s.76
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    • pp.420-426
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    • 2006
  • Bacillus sp. KMU-991 was isolated from Oslo city soils at Norway and shown a strong antifungal activity on red-pepper anthracnose, Colletotrichum gloeosporioides. Bacillus sp. KMU-991 produced a maximum level of antifungal substrate under aerobic incubation at $30^{\circ}C$, 180 rpm for 48 hours in TSB medium(initial pH 7.0) containing 1.0% mannitol and 1.0% ammonium chloride. Precipitate of culture broth by $30{\sim}60%$ ammonium sulfate precipitation exhibited strong antifungal activity against C. gloeosporioides KACC 40804. Butanol extract of cultured broth also shown fungal growth inhibitory activity against Fusarium oxysporum f. sp. radicus-lycopersici KACC 40537, Rhizoctonia solani AG-4 KACC 40142, Botrytis cinerea KACC 40573, Colletotrichum orbiculare KACC 40808, and Phytophthora cambivora KACC 40160 by agar diffusion method.

Durability Performance Evaluation On Early-Aged Concrete with Rice Husk Ash and Silica Fume (Rice Husk Ash와 실리카퓸을 혼입한 초기재령 콘크리트의 내구성능 평가)

  • Saraswathy, Velu;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.343-351
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    • 2015
  • Currently, lots of researches have been performed for reducing cement usages due to increasing social/engineering problems caused by $CO_2$ emission. Supplementary cement materials like fly ash, slag, and silca fume are usually employed for cement replacement, and nowadays rice husk ash (RHA) is widely studied for enhancement of concrete performance as mineral admixture. In this paper, concrete samples with RHA and SF which is known for its engineering advantages are prepared and a resistance to chloride attack is evaluated in early-aged concrete. For the work, replacement ratios of 10~30% for RHA concrete and 2~8% for SF concrete are considered, and various durability tests such as density, void, sorptivity, current measurement, and chloride diffusion coefficient are performed including mechanical test like compressive and tensile strength. Replacement of RHA 10~15% shows better improvement of corrosion resistance and strength than that of SF 2~4% and normal concrete, which shows a strong applicability for utilization as construction materials.

Durability Properties of High Volume Blast Furnace Slag Concrete for Application in Nuclear Power Plants (고로슬래그 다량치환 콘크리트의 원전 콘크리트 적용을 위한 내구성능 평가)

  • Seo, Eun-A;Lee, Jang-Hwa;Lee, Ho-Jea;Kim, Do-Gyeum
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.45-52
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    • 2017
  • This study evaluated the durability of nuclear power plant concrete. The main parameters were the water-to-binder ratio and admixture type. The results revealed that high-volume ground granulated blast-furnace slag(GGBS) concrete had lower initial strength, while the strength reached higher after 28 days. On the other hand, the initial strength of fly ash blended concrete was high, but the long-term strength of the robbery was low. The measured durability of GGBS blended concrete was found to be better than that of the existing concrete mix for use in the construction of nuclear power plants. Especially, the GGBS blended concrete was more durable than the fly ash blended concrete in terms of chloride attack, carbonation resistivity and freezing-thawing durability in low compressive strength. The effects of concrete compressive strength according to gamma rays were minor.