• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.165-168
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• 2006

The major cause of deterioration for the bare concrete bridge decks exposed to de-icing chemicals would be chloride-induced reinforcement corrosion. Thus, in this paper, in order to predict time to corrode for concrete bridge decks on highways, the chloride concentration was measured with depth from the surface. Then, the surface chloride concentration and apparent diffusion coefficient were calculated by regression. The premature failure of bare concrete decks were mostly related with thin cover depth and poor concrete property(high permeability). The good protection of deck surface might contribute to the prolongation of the service life of bare concrete bridge decks.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.663-666
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• 2005

Chloride attach is one of the main factors which cause the deterioration of structures. In the case highway bridges, de-icer salts very significantly increase the surface scaling due to frost action. The deteriorated concrete is subject to experience degrading of durability under chloride attach environment. In this study, diagnosis report of 147 bridges is investigated and core sample of 21 bridge decks is examined and analyzed. The results show that the cover of decks concrete is required more than 8cm for retaining bridge lifetime over 30 years.

• Journal of the Korea Institute of Building Construction
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• v.13 no.2
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• pp.139-147
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• 2013

The purpose of this study was to investigate the durability performance of concrete that includes rice husk ash. Chloride diffusion coefficient obtained through a rapid chloride penetration test and depth of $CO_2$ penetration obtained through a rapid carbonation test were used to evaluate latent durability. Durability characteristics for rice husk ash replacement and age were determined. Through the experiment, it was found that when the replacement ratio of rice husk ash was increased from 0% to 10%, the compressive strength of concrete containing rice husk ash was similar to that of concrete containing silica fume. This shows that the durability performance of concrete containing rice husk is excellent compared to other concretes containing admixtures.

• Journal of the Korea Concrete Institute
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• v.19 no.6
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• pp.707-715
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• 2007

The vulnerability of concrete to its environment is significantly dependent on the fact that concrete is a porous material. For well-consolidated and well-cured concrete, its service life is a very long and an entrance of aggressive substance might be only pores. However, for cracked concrete, cracks should be preferential channel for the penetration of aggressive substance such as chloride ions. The effect of crack on chloride penetration depends on its size for example, crack width and crack depth. The purpose of this study is examining the effect of crack width and crack depth on chloride penetration. In order to visualize chloride penetration via cracks, RCM (rapid chloride migration) testing is accomplished. Crack width is examined using an optical microscope and CMOD value is used to estimate average crack width. From the examination on the trend of chloride diffusion coefficients of concrete specimens with various crack widths, a critical crack width and a critical crack depth are found out.

• Journal of the Korean Society for Advanced Composite Structures
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• v.6 no.2
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• pp.63-69
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• 2015

It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

• Computers and Concrete
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• v.2 no.4
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• pp.325-343
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• 2005

Chloride ingress is a common cause of deterioration of reinforced concrete located in coastal zone. Modeling the chloride ingress is an important basis for designing reinforced concrete structures and for assessing the reliability of an existing structure. The modeling is also needed for predicting the deterioration of a reinforced structure. The existing deterministic solution for prediction model of corrosion initiation cannot reflect uncertainties which input variables have. This paper presents an approach to the fuzzy arithmetic based modeling of the chloride-induced corrosion of reinforcement in concrete structures that takes into account the uncertainties in the physical models of chloride penetration into concrete and corrosion of steel reinforcement, as well as the uncertainties in the governing parameters, including concrete diffusivity, concrete cover depth, surface chloride concentration and critical chloride level for corrosion initiation. There are a lot of prediction model for predicting the time of reinforcement corrosion of structures exposed to chloride-induced corrosion environment. In this work, RILEM model formula and Crank's solution of Fick's second law of diffusion is used. The parameters of the models are regarded as fuzzy numbers with proper membership function adapted to statistical data of the governing parameters instead of random variables of probabilistic modeling of Monte Carlo Simulation and the fuzziness of the time to corrosion initiation is determined by the fuzzy arithmetic of interval arithmetic and extension principle. An analysis is implemented by comparing deterministic calculation with fuzzy arithmetic for above two prediction models.

• Journal of the Korea Institute of Building Construction
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• v.20 no.1
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• pp.1-9
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• 2020

Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.199-200
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• 2010

This paper was estimated the diffusion coefficient through the chlorine ion diffusion coefficient of the high fluidity concrete using the limestone powder. Also, the micro void of high fluidity concrete examined according to the mixing ratio of the limestone powder by the mercury intrusion porosimetry.

• Analytical Science and Technology
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• v.8 no.4
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• pp.663-668
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• 1995

Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.

• International Journal of Concrete Structures and Materials
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• v.9 no.3
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• pp.295-306
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• 2015

Simulating natural leaching process for cementitious materials is essential to perform long-term safety assessments of repositories for nuclear waste. However, the current test methods in literature are time consuming, limited to crushed material and often produce small size samples which are not suitable for further testing. This paper presents the results from the study of the physical (gas permeability as well as chloride diffusion coefficient) and mechanical properties (tensile and compressive strength and elastic modulus) of solid cementitious specimens which have been depleted in calcium by the use of a newly developed method for accelerated calcium leaching of solid specimens of flexible size. The results show that up to 4 times increase in capillary water absorption, 10 times higher gas permeability and at least 3 times higher chloride diffusion rate, is expected due to complete leaching of the Portlandite. This coincides with a 70 % decrease in mechanical strength and more than 40 % decrease in elastic modulus.