• Title/Summary/Keyword: Chloride diffusion

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Effect of Time-dependent Diffusion and Exterior Conditions on Service Life Considering Deterministic and Probabilistic Method (결정론 및 확률론적 방법에 따라 시간의존성 염화물 확산계수 및 외부 영향인자가 내구수명에 미치는 영향)

  • Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.6
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    • pp.65-72
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    • 2016
  • Service life evaluation for RC Structures exposed to chloride attack is very important, however the previous two methods(deterministic and probabilistic method) show a big difference. The paper presents a service life simulation using deterministic and probabilistic method with time-dependent diffusion coefficient. Three different cases are considered for diffusion coefficient, concrete cover depth, and surface chloride content respectively, and then the PDF(probability of durability failure) and the related service life are obtained. Through adopting time-dependent diffusion, the discrepancy between the two methods can be reduced, which yields reasonable service life. When diffusion coefficient increases from $2.5{\times}10^{-12}m^2/sec$ to $7.5{\times}10^{-12}m^2/sec$, the service life decreases to 25.5~35.6% level, and cover depth does from 75 mm to 125 mm, it increases to 267~311% level as well. In the case of surface chloride content from $5.0kg/m^3$ to $15.0kg/m^3$, it changes to 40.9~54.5%. The effect of cover depth is higher than the others by 8~10 times and also implies it is a key parameter to service life extension.

Chloride Diffusion Coefficient Evaluation in 1 Year-Cured OPC Concrete under Loading Conditions and Cold Joint (하중조건과 콜드조인트를 고려한 1년 양생된 OPC 콘크리트의 염화물 확산계수 평가)

  • Oh, Kyeong-Seok;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.21-29
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    • 2017
  • Cold joint caused by construction delay is vulnerable to shear stress and it allows more rapid chloride penetration and diffusion. In the paper, investigation of chloride diffusion coefficient is performed for 1-year cured concrete considering compressive and tensile loading level and cold joint. The results are compared with the previous results in 91-day cured concrete. In the 1-year cured concrete without loading, 10.7% and 10.5% of diffusion reduction are evaluated for those in 91-day cured concrete, respectively. The reduction ratios are almost similar however the result in cold joint concrete shows much higher values. The results in 1-year cured concrete under 30% and 60% of compressive loading show reduction of chloride diffusion by 10.9% and 5.8% compared with 91-day cured results, which is caused by steady hydration of cement particles, so called, time effect. In the case of tensile loading, the differences in results are not significant regardless of time effect and cold joint since micro cracks which is weak point of concrete is much dominant despite of long term curing.

Prediction of chloride penetration into hardening concrete (경화중 콘크리트의 염해 침투성능에 관한 연구)

  • Fan, Wei-Jie;Wang, Xiao-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.50-51
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    • 2015
  • In marine and coastal environments, penetration of chloride ions is one of the main mechanisms causing concrete reinforcement corrosion. Currently, most of experimental investigations about submerged penetration of chloride ions are started after the four weeks standard curing of concrete. The further hydration of cement and reduction of chloride diffusivity during submerged penetration period are ignored. To overcome this weak point, this paper presents a numerical procedure to analyze simultaneously cement hydration reaction and chloride ion penetration process. First, using a cement hydration model, degree of hydration and phase volume fractions of hardening concrete are determined. Second, the dependences of chloride diffusivity and chloride binding capacity on age of concrete are clarified. Third, chloride profiles in hardening concrete are calculated. The proposed numerical procedure is verified by using chloride penetration test results of concrete with different mixing proportions.

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Probabilistic evaluation of chloride ingress process in concrete structures considering environmental characteristics

  • Taisen, Zhao;Yi, Zhang;Kefei, Li;Junjie, Wang
    • Structural Engineering and Mechanics
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    • v.84 no.6
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    • pp.831-849
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    • 2022
  • One of the most prevalent causes of reinforced concrete (RC) structural deterioration is chloride-induced corrosion. This paper aims to provide a comprehensive insight into the environmental effect of RC's chloride ingress process. The first step is to investigate how relative humidity, temperature, and wind influence chloride ingress into concrete. The probability of initiation time of chloride-induced corrosion is predicted using a probabilistic model that considers these aspects. Parametric analysis is conducted on several factors impacting the corrosion process, including the depth of concrete cover, surface chloride concentration, relative humidity, and temperature to expose environmental features. According to the findings, environmental factors such as surface chloride concentration, relative humidity and temperature substantially impact on the time to corrosion initiation. The long- and short-distance impacts are also examined. The meteorological data from the National Meteorological Center of China are collected and used to analyze the environmental characteristics of the chloride ingress issue for structures along China's coastline. Finally, various recommendations are made for improving durability design against chloride attacks.

A Study on the Service Life Prediction of Reinforced Concrete Structures with Chloride Penetration (철근콘크리트 구조물의 염해에 의한 사용수명 예측에 관한 연구)

  • Kim Dong-Baek;Kwon Ki-Jun;Park Byung-Wook
    • Journal of the Korean Society of Safety
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    • v.20 no.2 s.70
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    • pp.113-118
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    • 2005
  • Recently, the corrosion of reinforced concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. The purpose of the present study is to explore the influences of chloride attack parameters to service life of reinforced concrete structures and to propose the rational program for the guarantee of service life. for this purpose, several codes for durability design have been examined and the diffusion analysis based on Fick's second law has been performed with various parameter value. The present study indicates that durability design code of Japan Society of Civil Engineers is more rational than other codes but the application of durability design code of JSCE to domestic durability design needs more studies to the various parameter values related with chloride penetration.

Pore Size Distribution and Chloride Diffusivity of Concrete Containing Ground Granulated Blast Furnace Slag

  • Moon Han-Young;Kim Hong-Sam;Choi Doo-Sun
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.277-282
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    • 2004
  • In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

An Experimental Study on the Corrosion Characteristics of Reinforcement Concrete According to Types of Surface Covering Material (표면피복재 종류에 따른 철근콘크리트의 철근 부식특성에 관한 실험적 연구)

  • 김갑수;장종호;김재환;김용로;오시덕;김무한
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.39-43
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    • 2003
  • Chloride ions are considered to be the major cause of steel corrosion in concrete structures exposed to seashore environments and also permeation of chloride is controlled by chloride diffusion. Therefore, the study on chloride diffusion of concrete have been done so far by many researchers. It is reported that coating material as surface covering material is effect about deterioration of salt damage and carbonation, therefore these materials are important in durability of concrete structure. In this study, corrosion characteristics of reinforcement concrete according to types of surface covering material were evaluated by water-cement ratio, chloride penetration by age on the corrosion area rate and mass decrement of reinforcement. And it is considered that the result of this study on application of the corrosion characteristics of reinforcements under salt damage environmental will be suggested as fundamental data of control performance of salt damage. It is performed that comparison and examination of control performance of salt damage by the corrosion characteristics under salt damage environmental.

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A Probability-Based Durability Analysis of Concrete Structures in Chloride Containing Environments (염해환경 콘크리트 구조물의 확률론적 내구성 해석)

  • Kwon, Ki-Jun;Kim, Dong-Baek;Jung, Sang-Hwa;Chae, Seong-Tae
    • Journal of the Korean Society of Safety
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    • v.22 no.3 s.81
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    • pp.51-56
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    • 2007
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures in chloride containing environments. In particular, the development of new procedures for probability-based durability analysis/design has proved to be very valuable. Although there is still a lack of relevant data, this approach has been successfully applied to some new concrete structures. In this paper, the equation used for modelling of the chloride penetration was based on Fick's Second Law of Diffusion in combination with a time dependent diffusion coefficient. The probability analysis of the durability performance was performed by use of a Monte Carlo Simulation. The procedure was applied to an example based on limited data gathered in this country. The influences of each parameter on the durability of concrete structures are studied and some comments for durability design are given. The new procedure may be very useful in designing an important concrete structures in chloride containing environments. Also it may help to predict the service life of concrete structures under a given probability of failure.

Development of Chloride Ingress Model in Reinforced Concrete Structures (철근콘크리트 구조물의 염소이온 침투 모델 개발)

  • 구현본;이광명
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.731-736
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    • 2002
  • The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures due to chloride attack followed by reinforcement corrosion is one of the serious problems. The objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a mathematical model of chloride ingress into concrete consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water was proposed. Moreover, the variability of diffusivity of chloride ion due to degree of hydration of concrete, relative humidity in pore, exposure condition, and variation of chloride binding was considered in the chloride ingress model.

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Characteristics for Reinforcement Corrosion and Chloride Ion Diffusion of High Volume Fly Ash Concrete (하이볼륨 플라이애시 콘크리트의 철근부식 및 염소이온 확산 특성)

  • Kwon, Soon-Oh;Bae, Su-Ho;Lee, Hyun-Jin;Jung, Sang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.34-39
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    • 2014
  • The purpose of this experimental research is to evaluate the resistance of reinforcement corrosion and chloride ion penetration of high volume fly ash (HVFA) concrete. For this purpose, concrete test specimens were made for various strength level and replacement ratio of fly ash, and then compressive strength and diffusion coefficient for chloride ion of them were measured for 28, 91 and 182 days, respectively. Also, corrosion monitoring by half cell potential method was carried out for the made lollypop concrete test specimens to detect the time of corrosion initiation for reinforcement in concrete. As a result, it was observed from the test results that compressive strength of HVFA concrete was decreased with increasing replacement ratio of fly ash but long-term resistance against reinforcement corrosion and chloride ion penetration of that was increased.