• Title/Summary/Keyword: Chloride attack

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Evaluation on Resistance of Chloride Attack and Freezing and Thawing of Concrete with Surface Penetration Sealer (표면 침투제에 따른 콘크리트의 염화물 침투와 동결융해 저항성 평가)

  • Kim Myung Yu;Yang Eun Ik;Lho Byeong Cheol;Kim Jeong Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.505-508
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    • 2005
  • Concrete has a void, which exists as one of defect in concrete. If the porosity of concrete increases, durability of concrete decreases. In this paper, to improve surface void of concrete, surface penetration sealers are applied to specimen. And it were investigated that the resistances of chloride penetration and freezing and thawing for concrete with surface penetration sealer of two types. According to the results, surface penetration sealer has not show a harmful influence on strength and resistance of freezing and thawing. Also, B type surface penetration sealer was more superior in resistance of chloride penetration.

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Durability of Hydrophilic Alkali Silicate Impregnant of Concrete Structure (알칼리 실리케이트계 침투성 콘크리트 표면보호재의 내구특성)

  • Song, Hun;Lee, Jong-Kyu;Chu, Yong-Sik;Kim, Young-Yup
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.91-94
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    • 2007
  • It is essential every concrete structure should continue to perform its intended functions, that is maintain its required strength and durability, during the service life. However, deterioration occurs more progressively from the outside of concrete exposed to severe conditions. Deterioration in the concrete structure is due to carbonation and chloride ion attack. Therefore, concrete structure is needed to surface protection for increase durability using impregnant. Impregnant classify into two large groups in polymeric and silicate materials. Silicate impregnant is included silane and alkali silicate(sodium and lithium silicate). Thus, this study is concerned with carbonation and chloride ion resistance of self cleaning hydrophilic impregnant of concrete structure using lithium and potassium silicate. From the experimental test result, lithium and potassium silicate have a good properties as a carbonation and chloride ion resistance. Lithium and potassium silicate make good use of hydrophilic impregnant.

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Chloride Ion Diffusion Coefficient and Compressive Strength of the Concrete Produced by Ready Mixed Concrete Company in Busan (부산지역 레미콘사의 콘크리트의 압축강도와 염소이온 확산계수)

  • Park, Dong-Cheon;Bang, Jung-Suk;Kim, Yong-Ro;Lee, Tae-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.11-12
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    • 2017
  • The properties of concrete produced by ready mixed concrete company in Busan were tested. Because the concrete was mixed with blast furnace slag and fly ash, the compressive strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design.

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A Study on the Combined Deterioration of Concrete subjected to Freezing-Thawing and Chloride Attack (동해와 염해를 동시에 받는 콘크리트의 복합열화에 관한 연구)

  • Kim Eun-Kyum;Choi Sang-Deok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.225-228
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    • 2005
  • This paper was accomplished for analyzing the reason of the above deterioration happened on the deck of concrete bridge. The bridge was constructed at 660m above the sea level having more freezing and snowing days. Therefore, it is placed on the particular condition sprinkling $CaCl_2$ enough for keeping up with moderate traffic condition. When it is considered to the former condition, the bridge can be assumed to potentialities for combined deterioration with freezing-thawing under sprinkling deicing chemical. Core specimens were gathered from the concrete deck for clearing the reason of the above deterioration exactly, and it is used for various tests for measuring the compressive strength, elastic modulus, content of $Cl^-$, freezing-thawing at the fresh and salt water. As a result of freezing-thawing test, the specimen at the fresh water has over 90$\%$ of durability factor, but another specimen at 1$\%$ of salt water has 0$\%$ of durability factor at 140 cycles of the freezing-thawing. The result means that frost damage is sccelerated at the salt water. Therefore, the deterioration of the concrete deck is estimated to be occured by combined effects of freezing-thawing and chloride ion attack.

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The effect of attack of chloride and sulphate on ground granulated blast furnace slag concrete

  • Ashish, Deepankar K.;Singh, Bhupinder;Verma, Surender K.
    • Advances in concrete construction
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    • v.4 no.2
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    • pp.107-121
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    • 2016
  • This concrete is one of the most versatile construction material widely used for almost a century now. It was considered to be very durable material and required a little or no maintenance since long time. The assumption is very true, except when it is subjected to highly aggressive environments. The deterioration of concrete structures day by day due to aggressive environment is compelling engineers to assess the loss in advance so that proper preventive measure can be taken to achieve required durability to concrete structures. The compounds present in cement concrete are attacked by many salt solutions and acids. These chemicals are encountered by almost all concrete structures. The present study has been undertaken to investigate the effect of attack of chlorides and sulphates with varying severity on compressive strength of ground granulated blast furnace slag (GGBFS) concrete after immersion in salt solution for 28 days. The results indicate that the durability of GGBFS concrete increases with the increase in percentage replacement of cement by GGBFS for 20% and then gradually decreases with increases in percentage of GGBFS with cement (as in the study for 40% and 60%). Also there is increase in strength of GGBFS concrete with increase in age. Thus the durability of concrete improves when GGBFS is added as partial replacement of cement. In this study the strength of GGBFS concrete is less affected by chemicals as compared to conventional concrete when exposed to aggressive environment.

Durability and mechanical performance in activated hwangtoh-based composite for NOx reduction

  • Kim, Hyeok-Jung;Park, Jang-Hyun;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Advances in concrete construction
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    • v.11 no.4
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    • pp.307-314
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    • 2021
  • Activated hwangtoh (ACT) is a natural resource abundant in South Korea, approximately 15.0% of soil. It is an efficient mineral admixture that has activated pozzolanic properties through high-temperature heating and rapid cooling. The purpose of this study is to improve a curb mixture that can reduce NOx outside and investigate durability performance. To this end, mortar curb specimens were manufactured by replacing OPC with ACT. The ACT substitution ratios of 0.0, 10.0, and 25.0% were considered, and mechanical and durability tests on the curb specimens were conducted at 28 and 91 days of age. Steam curing was carried out for three days for the production of curbs, which was very effective to strength development at early ages. The reduction in strength at early ages could be compensated through this process, and no significant performance degradation was evaluated in the tests on chloride attack, carbonation, and freezing and thawing. The mortar curb with an ACT of 10.0~25.0% replacement ratio exhibited clear NOx reduction through photocatalytic (TiO2) treatment. This is due to the increase in physical absorption through surface absorption and the photocatalyst-containing TiO2 coating. In this study, the reasonable range of the ACT replacement ratio for NOx reduction was quantitatively evaluated through a comprehensive analysis of each test.

Influence of supplementary cementitious materials on strength and durability characteristics of concrete

  • Praveen Kumar, V.V.;Ravi Prasad, D.
    • Advances in concrete construction
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    • v.7 no.2
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    • pp.75-85
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    • 2019
  • The present study is focused on the mechanical and durability properties of ternary blended cement concrete mix of different grades 30 MPa, 50 MPa and 70 MPa. Three mineral admixtures (fly ash, silica fume and lime sludge) were used as a partial replacement of cement in the preparation of blended concrete mix. The durability of ternary blended cement concrete mix was studied by exposing it to acids HCl and $H_2SO_4$ at 5% concentration. Acid mass loss factors (AMLF), acid strength loss factor (ASLF) and acid durability factor (ADF) were determined, and the results were compared with the control mix. Chloride ions penetration was investigated by conducting rapid chlorination penetration test and accelerated corrosion penetration test on control mix and ternary blended cement concrete. From the results, it was evident that the usage of these mineral admixtures is having a beneficiary role on the strength as well as durability properties. The results inferred that the utilization of these materials as a partial replacement of cement have significantly enhanced the compressive strength of blended concrete mix in 30 MPa, 50 MPa and 70 MPa by 42.95%, 32.48% and 22.79%. The blended concrete mix shown greater resistance to acid attack compared to control mix concrete. Chloride ion ingress of the blended cement concrete mix was low compared to control mix implying the beneficiary role of mineral admixtures.

Resistance of Cementitious Binders to Chloride Induced Corrosion of Embedded Steel by Electrochemical and Microstructural Studies

  • Song, Ha-Won;Ann, Ki-Yong;Kim, Tae-Sang
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.74-80
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    • 2009
  • The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

Service Life Prediction and Cost Estimation of Repaired Concrete Structures Under Marine Environment (염해 환경 하 보수된 콘크리트 구조물의 사용수명 예측 및 보수 비용 평가)

  • Shim, Hyun Bo;Ann, Ki Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.226-234
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    • 2011
  • The service life of concrete structures exposed to a marine environment can be extended by controlling the amount of chloride in cover concrete. Patching is one of the appropriate maintenance techniques for chloride contamination. Chloride-contaminated cover concrete is removed and replaced with sound one. It can provide less risk of corrosion of steel, so that the structure can be maintained for required service life. In this study, a quantitative assessment of the service life subjected to the chloride attack is proposed to determine the effective repair options such as repair depth, repair material and timing of repair. The Crank-Nicolson based finite difference formulation from Fick's second law is proposed to predict the profiles of chloride ion in a repaired concrete structure, considering ingress of chloride from outer and redistribution of residual chloride from the substrate concrete. Therefore, the repair application times and maintenance cost for the target service life can be estimated. Finally, the numerical examples are presented to ensure its applicability.

Evaluation of Chloride Behavior and Service Life in Long-Term Aged FA Concrete through Probabilistic Analysis (장기재령 FA 콘크리트에 대한 염화물 거동 및 확률론적 염해 내구수명 평가)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.276-285
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    • 2020
  • In this study, accelerated chloride diffusion tests were performed on OPC(Ordinary Portland Cement) and FA(Fly Ash) concrete considering three levels o f W/B(Water to Binder) ratio o n 1,095 curing days. The accelerated chloride diffusion coefficient and the passed charge were evaluated in accordance with Tang's method and ASTM C 1202, and the resistance performance to chloride attack improved over time. FA concrete showed excellent resistance performance against chloride penetration with help of pozzolanic reaction. As the result of the passed charge, FA concrete showed durability improvement, "low" grade to "very low" grade, but OPC concrete changed "moderate" grade to "low" grade at 1,095 curing days. After assuming the design variables used for durability design as normal distribution functions, the service life of each case was evaluated by the probabilistic analysis method based on MCS(Monte Carlo Simulation). In FA concrete, the increase of probability of durability failure was lower than that of OPC concrete with increasing time, because the time-dependent coefficient of FA concrete was up to 3.2 times higher than OPC concrete. In addition, the service life by probabilistic analysis was evaluated lower than the service life by deterministic analysis, since the target probability of durability failure was set to 10%. It is considered that more economical durability design will be possible if the mo re suitable target probability of durability failure is set for various structures through researches on actual conditions and indoor tests under various circumstances.