• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1233-1237
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• 2000

In this study, we measured and assay the analysis of chloride ion in cement hydration by the standard method of JCI and understand the mutual relation between added contents and result. The purpose of this research is to provide fundamental information for the deterioration of the reinforcing concrete on account of steel of reinforced steel to repress.

• Bulletin of the Korean Chemical Society
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• v.19 no.5
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• pp.575-579
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• 1998

The 77 K luminescence and excitation spectra, and 298 K infrared and absorption spectra of $cis-{\Alpha}-[Cr(trien)Cl_2]Cl{\cdot}H_2O$ (trien=triethylenetetramine) have been measured. Ligand field electronic transitions due to spin-allowed and spin-forbidden are assigned. The zero-phonon line in the excitation spectrum splits into two components by $198\; cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the trien ligand have a strong σ-donor character, but chloride ligand has weak σ- and π -donor properties toward chromium(III) ion.

• Journal of Construction Engineering and Project Management
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• v.7 no.1
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• pp.26-29
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• 2017

This paper represents the experimental investigation of chloride penetration into plain concretes and reinforced concretes. The main objective of this work is to study the main influencing parameters affecting corrosion of steel in concrete. Plain cement concrete and reinforced cement concrete with different water-cement ratios and different cover depth were subjected to ponding test. Ponding of specimens were done for different periods into 10% NaCl solution. Depth of penetration of chloride solution into specimens was measured after ponding. Specimens were crushed and reinforcements were washed using $HNO_3$ solution and weight loss due to corrosion was calculated accordingly. There was a linear relationship between depth of penetration and water-cement ratio. It was also observed that, corrosion of reinforcing steel increases with chloride ponding period and with water-cement ratio. Corrosion of steel in concrete can be minimized by providing good quality concrete and sufficient concrete cover over the reinforcing bars. Water-cement ratio has to be low enough to slow down the penetration of chloride salts into concrete.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.345-351
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• 2003

The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

• Journal of the Korea institute for structural maintenance and inspection
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• v.3 no.4
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• pp.163-171
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• 1999

In this study, we executed fundamental experiment to investigate properties of accelerated carbonation with changing chloride content of concrete used sea sand in order to examine durability. So we obtained the results of following properties of mechanics, durability, concrete with sea sand, determined concrete w/C 30%, 40%, 50%, and fine aggregate 40% and changing containing chloride 0, 0.3, 0.6, $0.9kg/m^3$ by the experiment of accelerated neutralization. The results of this study as follows: 1) As result of changing chloride content of concrete used sea sand augmented in stages $0.3kg/m^3$, accelerated carbonation was increased as increment chloride content. The increment depth was decreased as it went long term age. It was shown the chloride content effected increment of carbonation depth in concrete 2) As a result of changing W/C of concrete used sea sand augmented in stages 10% at a time from 30% to 50%, accelerated carbonation depth of concrete was increased as W/C ratio. 3) As the carbonation concrete used sea sand, compressive strength between 8 weeks and accelerated carbonation depth of 1 weeks, 2 weeks, 4 weeks, 8 weeks was inversion proportion.

• Journal of the Korea Concrete Institute
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• v.25 no.2
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• pp.145-153
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• 2013

Recently, accelerated chloride diffusion coefficients are used for an evaluation of chloride behavior. Similar as apparent diffusion coefficients, accelerated diffusion coefficients decrease with time. In this study, decrease in diffusion coefficient with time is simulated with porosity. Utilizing DUCOM-program, porosities from 15 mix proportions are obtained and diffusion coefficients are modelled with regression analysis of porosity for 270 days. Considering non-linear binding capacity which means the relation between free and bound chloride ion, chloride behavior in high performance concrete is evaluated. Through utilizing the previous test results for concrete under chlorides for 180 days, the applicability of the proposed technique is verified. The proposed technique is evaluated to reasonably predict the chloride behavior in concrete with various w/c (water to cement) ratios and mineral admixtures (GGBFS and FA). It is also shown that decrease in chloride diffusion should be considered for chloride prediction in concrete with mineral admixture since it has very clear decrease in diffusivity with time.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.2
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• pp.173-180
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• 2005

Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the mechanical and durability test such as compressive/tensile/flexural strength test, chloride ion diffusion, chemical attack and repeated freezing and thawing, carbonation test. In the mechanical tests, 10~15% for binder is optimum substitute rate. And, in the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient was more reduced. In the chemical attack test, by the filler effect of fine powder such metakaolin and silica-fume, the resistance is more excellent than normal concrete. In the other durability test, the concrete using metakaolin also compared with those of silica-fume substitute concrete. Through these tests, we recognized that metakaolin can be used as a substitute for silica-fume.

• Journal of the Korean GEO-environmental Society
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• v.8 no.2
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• pp.57-63
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• 2007

Coal combustion by-product (CCB) bottom ash, obtained from burning of pulverized coal, has physical properties which are similar to that of natural sand with particle sizes ranging from fine gravel to fine sand. Several studies have been completed to utilize pulverized coal combustion (PCC) bottom ash as a partial or full replacement of fine aggregate in cement concrete products. The objectives of this study were to develop air-entrained concrete composites using PCC bottom ash from burning of Illinois coal and to demonstrate the use of these composites on real-world projects. The results obtained show that the compressive, splitting-tensile, and flexural strengths of concrete composites is slightly lower than that of conventional concrete are early curing ages. However, after 60 days of curing, the strength of concrete composites is either equal to or slightly higher than that of an equivalent conventional concrete. The concrete composites showed lower resistance to chloride ion penetrability than that of an equivalent conventional concrete at early curing ages. However, after 28 days of curing, concrete composites showed better resistance to chloride ion penetrability compared to that of an equivalent conventional concrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2002.11a
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• pp.87-91
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• 2002

This paper investigates the corrosion inhibition and the reduction of hydration heat properties of Ground Granulated Blast-Furnace Slag (GGBFS) added concrete. Since the massive civil structure is vulnerable to the thermal crack by hydration. adiabatic temperature rising tests were performed for water-binder ratios from 43.2% to 47.3%, while replacing 15% to 50% of cement with GGBFS of equal weight. Then, the corrosion protection performance was evaluated using cylindrical specimens embedded with steel reinforcement according to the combination of 3 W/B ratios and 2 levels of chloride ion quantity. The corrosion area of the embedded steel ban was determined using the high pressure steam curing method specified in KS F 2561. The test results showed that the replacement of GGBFS was effective in reducing the hydration heat. The corrosion area of the embedded steel ban decreased as the replacement of GGBFS increased. However, the corrosion area of the steel bar was proportional to the autoclave cycle and the chloride ion quantity. Among the tested specimens, compressive strength, reduction of hydration heat, and corrosion inhibition performance were excellent when 50% of cement was replaced with GGBFS of equal weight.

• Resources Recycling
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• v.15 no.3 s.71
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• pp.74-80
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• 2006

In this article, we would like to investigate a durability characterization of cement mortar with inert filler, which is ground calcium carbonate(GCC). The kinds of techniques to evaluate cement mortar are chloride ion ingress, carbonation and sulfate attack. For the experimental result of the resistance of chloride ion ingress, carbonation and sulfate attack, as the addition of GCC makes decreasing the permeability by micro-filler effect, the specimens of $5{\sim}15%$ ratio of replacement are superior to the GCC0 mortar specimen with respect to durability of cement matrix in this scope.